Nitrogen-containing porous carbon material and method of producing the same, and electric double-layer capacitor using the nitrogen-containing porous carbon material
A nitrogen-containing carbon porous material, which has a nitrogen content of 0.5 to 30 mass %, and which has a specific surface area of 200 to 3,000 m 2 /g.
1. A nitrogen-containing carbon porous material, comprising nitrogen at a content of 0.5 to 30 mass %, wherein the nitrogen-containing porous material has a specific surface area of 1,015 to 2,200 m 2 /g and contains oxygen at a content of 8.7 to 11.4 mass %,
wherein the nitrogen-containing carbon porous material is obtained by mixing and heating a melamine and magnesium citrate to form a carbon film containing the nitrogen on a carbon skeleton at a circumference of a particle of MgO formed by oxidation of Mg in the magnesium citrate upon heating, and then removing the MgO.
2. The nitrogen-containing carbon porous material according to claim 1 , wherein the mixing and heating a melamine and magnesium citrate comprises mixing the melamine and magnesium citrate, and heating a resultant mixture to 700° C. or more under an inert atmosphere, followed by cooling and washing with an acid.
3. An electrode material for an electric double-layer capacitor, which is formed by binding the nitrogen-containing carbon porous material according to claim 1 with a binder resin.
4. An electric double-layer capacitor, which is formed with the electrode material for an electric double-layer capacitor according to claim 3 in an electrode.
5. An electrode material for an electric double-layer capacitor, which is formed by binding the nitrogen-containing carbon porous material according to claim 2 with a binder resin.
6. An electric double-layer capacitor, which is formed with the electrode material for an electric double-layer capacitor according to claim 5 in an electrode.
7. A method of producing the nitrogen-containing carbon porous material according to claim 1 , comprising the steps of: mixing a melamine and magnesium citrate; heating the resultant mixture to 700° C. or more under an inert atmosphere; cooling; and washing with an acid.
8. The method of producing a nitrogen-containing carbon porous material according to claim 7 , wherein a retention time period at 700° C. or more is from 1 to 5,000 min.
9. The method of producing a nitrogen-containing carbon porous material according to claim 7 , wherein a temperature rising speed to a retention temperature of 700° C. or more is from 1 to 100° C./min.
10. The method of producing a nitrogen-containing carbon porous material according to claim 9 , wherein a retention time period at 700° C. or more is from 1 to 5,000 min.