Resin composition for optical film and compensation film using the same
Provided are a composition for an optical film comprising 40 wt % to 94 wt % of an acrylic resin; 5 wt % to 40 wt % of a styrene-acrylonitrile copolymer having a weight-average molecular weight less than 1,000,000; and 1 wt % to 20 wt % of an ultra-high molecular weight styrene-acrylonitrile copolymer having a weight-average molecular weight ranging from 1,000,000 to 9,000,000, and an optical film using the composition.
1. An optical film prepared by biaxial stretching of a composition, the composition comprising:
40 wt % to 94 wt % of an acrylic resin;
5 wt % to 40 wt % of a styrene-acrylonitrile copolymer having a weight-average molecular weight less than 1,000,000; and
1 wt % to 20 wt % of an ultra-high molecular weight styrene-acrylonitrile copolymer having a weight-average molecular weight ranging from 1,000,000 to 9,000,000,
wherein a thickness of the optical film is in a range of 20 μm to 150 μm; and
wherein the optical film has an optical transmittance of 90% or more and a haze value of 2.5% or less;
wherein an in-plane retardation value of the optical film is in the range of 50 nm to 200 nm;
wherein a thickness retardation value of the optical film is in the range of 50 nm to 400 nm;
wherein a value of R th /R in of the optical film is in the range of 1.0 to 2.0; and
wherein the in-plane retardation value (R in ) denotes a value defined by the following Equation 1 and the thickness retardation value (R th ) denotes a value defined by the following Equation 2:
R in =( n x −n y )× d [Equation 1]
R th =( n z −n y )× d [Equation 2]
in Equations 1 and 2,
n x is an in-plane refractive index of the film in a direction having the largest refractive index,
n y is an in-plane refractive index of the film in a direction perpendicular to the n x direction,
n z is a thickness refractive index,
d is a thickness of the film, and
the measured reference wave-length of the in-plane retardation value and the thickness retardation value is 550 nm.
2. The optical film of claim 1 , wherein a content of acrylonitrile in the styrene-acrylonitrile copolymer having a weight-average molecular weight less than 1,000,000 is in a range of 15 wt % to 26 wt %.
3. The optical film of claim 1 , wherein a content of acrylonitrile in the ultra-high molecular weight styrene-acrylonitrile copolymer is in a range of 15 wt % to 26 wt %.
4. The optical film of claim 1 , wherein the acrylic resin is a copolymer of a (meth)acryl-based monomer and a cyclic based monomer.
5. The optical film of claim 4 , wherein the cyclic based monomer is maleic anhydride, maleimide, glutaric acid anhydride, glutarimide, lactam, or a derivative thereof.
6. The optical film of claim 1 , wherein the styrene-acrylonitrile copolymer having a weight-average molecular weight less than 1,000,000 comprises an alpha-methyl styrene unit.
7. The optical film of claim 1 , wherein the ultra-high molecular weight styrene-acrylonitrile copolymer having a weight-average molecular weight ranging from 1,000,000 to 9,000,000 comprises an alpha-methyl styrene unit.
8. The optical film of claim 1 , wherein the acrylic resin comprises an alpha-methyl styrene unit.
9. The optical film of claim 1 , wherein the stretching is performed at a temperature ranging from Tg to (Tg+20° C.).
10. The optical film of claim 1 , wherein the biaxial stretching is performed at a machine direction (MD) stretching ratio ranging from 1.5 to 2.0 and at a transverse direction (TD) stretching ratio ranging from 2.0 to 4.0.
11. A polarizing plate for in-plane switching (IPS)-liquid crystal display (LCD) compensation comprising the optical film of claim 1 .