Manufacturing method of electrode material
A method of manufacturing a composite materials in which a carbon material and a metal compound can maintain a nanosized form as a final product is realized, and a method for manufacturing a superior electrode material is provided. A metal compound precursor is formed from a metal compound material source, and a mixture of the metal compound precursor and a carbon material is calcinated. In the treatment to form the precursor, a treatment of absorbing one of the metal compound material sources to the functional group of the carbon material and a treatment of producing on the carbon material a treatment of reacting the remaining material source of the adsorbed metal compound material source on the carbon material to produce a metal compound precursor are performed in separate steps.
1. A method for manufacturing an electrode material including a composite material of a metal compound which occludes and releases lithium supported on a carbon material, comprising:
a first mechanochemical treatment of dispersing a starting material for a metal compound which occludes and releases lithium and a carbon material by applying shear stress and centrifugal force in a rotating reactor,
a second mechanochemical treatment of further applying shear stress and centrifugal force in the reactor after the first mechanochemical treatment to allow production of a metal compound precursor of the metal compound which occludes and releases lithium from the starting material, and
a calcination treatment of heating a mixture obtained by the second mechanochemical treatment,
wherein
one of a hydrolysis reaction and a complex formation reaction is used for producing the metal compound precursor,
wherein when a hydrolysis reaction is used for producing the metal compound precursor, an alcohol is used as a solvent in the first mechanochemical treatment, and water is added in the second mechanochemical treatment, and
wherein when a complex formation reaction is used for producing the metal compound precursor, a pH adjustment treatment is added between the first and the second mechanochemical treatments.
2. A method for manufacturing an electrode material according to claim 1 , wherein
the first mechanochemical treatment includes adsorbing one of the starting materials of the metal compound onto the carbon material, and
the second mechanochemical treatment includes reacting the remaining starting materials of the adsorbed starting materials of the metal compound on the carbon material to produce the metal compound precursor on the carbon material.
3. A method for manufacturing an electrode material according to claim 1 , wherein
the electrode material is a sheet composite of the composite material molded in a paper machine using a fibrous carbon binder, and
the fibrous carbon binder of the composite material comprises any of carbon nanotubes, carbon nanofibers, and carbon fibers having a specific surface area of less than 600 m 2 /g.
4. A method for manufacturing an electrode material according to claim 2 , wherein
the complex formation reaction is used for producing the metal compound precursor.
5. A method for manufacturing an electrode material according to claim 2 , wherein
the electrode material is a sheet composite of the composite material molded in a paper machine using a fibrous carbon binder, and
the fibrous carbon binder of the composite material comprises any of carbon nanotubes, carbon nanofibers, and carbon fibers having a specific surface area of less than 600 m 2 /g.
6. A method for manufacturing an electrode material according to claim 4 , wherein
the electrode material is a sheet composite of the composite material molded in a paper machine using a fibrous carbon binder, and
the fibrous carbon binder of the composite material comprises any of carbon nanotubes, carbon nanofibers, and carbon fibers having a specific surface area of less than 600 m 2 /g.
7. The method of claim 1 , wherein the hydrolysis reaction is used for producing the metal compound precursor.