Aqueous carbon filler dispersion coating liquid, conductivity-imparting material, electrode plate for an electrical storage device, manufacturing method therefore, and electrical storage device
A water-based, carbon filler-dispersed coating formulation for forming a conductive coating film contains (1) a hydroxyalkyl chitosan as a resin binder, (2) a conductive carbon filler, and (3) a polybasic acid or its derivative in a water-based medium containing at least water as a polar solvent. In 100 parts by mass of the coating formulation, the hydroxyalkyl chitosan (1) is contained in a range of from 0.1 to 20 parts by mass, and the conductive carbon filler (2) is contained in a range of from 1 to 30 parts by mass. An electricity-imparting material, an electrode plate for an electricity storage device, a process for producing the electrode plate, and the electricity storage device are also disclosed.
1. A water-based, carbon filler-dispersed coating formulation for forming a conductive coating film, comprising:
(1) a hydroxyalkyl chitosan as a resin binder;
(2) a conductive carbon filler; and
(3) a polybasic acid or a derivative thereof,
in a water-based medium, which is water or a mixed dispersion medium that is a mixture of water and an organic solvent miscible with water, the organic solvent being at least one solvent selected from the group consisting of alcohols, esters, ketones, amides, sulfoxides, and mixtures thereof,
wherein in 100 parts by mass of the coating formulation, the hydroxyalkyl chitosan (1) is contained in an amount from 0.1 to 20 parts by mass, and the conductive carbon filler (2) is contained in an amount from 1 to 30 parts by mass,
the coating formulation contains the water-based medium at least 68% by mass, and
an amount ratio of the organic solvent relative to the water in the water-based medium by mass is in a range from 0/100 to 70/30, and
the hydroxyalkyl chitosan has a weight average molecular weight in a range from 2,000 to 350,000.
2. The water-based, carbon filler-dispersed coating formulation according to claim 1 ,
wherein the hydroxyalkyl chitosan comprises at least one hydroxyalkyl chitosan selected from the group consisting of glycerylated chitosan, hydroxyethyl chitosan, hydroxypropyl chitosan, hydroxybutyl chitosan, and hydroxybutyl hydroxypropyl chitosan.
3. The water-based, carbon filler-dispersed coating formulation according to claim 1 , wherein the hydroxyalkyl chitosan has a hydroxyalkylation degree of 0.5 or higher but 4 or lower.
4. The water-based, carbon filler-dispersed coating formulation according to claim 1 , wherein the polybasic acid or the derivative thereof is contained in an amount from 20 to 300 parts by mass per 100 parts by mass of the hydroxyalkyl chitosan.
5. The water-based, carbon filler-dispersed coating formulation according to claim 1 ,
wherein the conductive carbon filler is at least one conductive carbon filler selected from the group consisting of carbon black, acetylene black, Ketjenblack, furnace black, natural graphite, artificial graphite, carbon nanofibers and carbon nanotubes.
6. The water-based, carbon filler-dispersed coating formulation according to claim 1 ,
wherein the polybasic acid is at least one polybasic acid selected from the group consisting of 1,2,3,4-butanetetracarboxylic acid, pyromellitic acid, citric acid, 1,2,3-propanetricarboxylic acid, 1,2,4-cyclohexanetricarboxylic acid, 1,2,4,5-cyclohexanetetracarboxylic acid, trimellitic acid, 1,4,5,8-naphthalenetetracarboxylic acid, and 1,2,3,4,5,6-cyclohexanehexacarboxylic acid.
7. The water-based, carbon filler-dispersed coating formulation according to claim 1 , further comprising at least one resin component, which is selected from the group consisting of polyvinyl alcohol, polyvinyl acetal, polyacrylic acid, fluorine-containing macromolecules, cellulose-based macromolecules, starch-based macromolecules, styrene-based polymers, acrylic polymers, styrene-acrylate ester copolymers, polyamides, polyimides, and polyamide-imides, as a binder in an amount from 10 to 2,000 parts by mass per 100 parts by mass of the hydroxyalkyl chitosan.
8. The water-based, carbon filler-dispersed coating formulation according to claim 1 ,
wherein the alcohols in the group are methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, s-butyl alcohol, isobutyl alcohol, and t-butyl alcohol,
the esters in the group are methyl acetate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, methoxybutyl acetate, cellosolve acetate, amyl acetate, methyl lactate, ethyl lactate, and butyl lactate,
the ketones in the group are acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, and cyclohexanone,
the amides in the group are N-methyl-2-pyrrolidone, N,N-dimethylacetamide, and N,N-dimethylformamide, and
the sulfoxides in the group is dimethyl sulfoxide.