Separator for non-aqueous secondary battery, method for producing the same, and non-aqueous secondary battery
The present invention provides a separator for a non-aqueous secondary battery including a porous substrate and an adhesive layer that is formed on at least one side of the porous substrate and is an aggregate layer of particles that contain a polyvinylidene fluoride resin and have an average particle diameter of from 0.01 μm to 1 μm, in which a content of the particles per one adhesive layer is from 0.1 g/m 2 to 6.0 g/m 2 .
1. A separator for a non-aqueous secondary battery, the separator comprising:
a porous substrate; and
an adhesive layer that is formed on at least one side of the porous substrate and is an aggregate layer of particles that contain a polyvinylidene fluoride resin and have an average particle diameter of from 0.01 μm to 1 μm, in which a content of the particles per one adhesive layer is from 0.1 g/m 2 to 6.0 g/m 2 ;
wherein the particles retain their particle shapes in the adhesive layer.
2. The separator for a non-aqueous secondary battery according to claim 1 , wherein a smoothness of a surface of the adhesive layer is 1.30 or less, wherein the smoothness of the surface is evaluated based on surface area ratio (smoothness) in a 2×2 μm 2 visual field in AFM observation, using an atomic force microscope (AFM).
3. The separator for a non-aqueous secondary battery according to claim 1 , wherein the polyvinylidene fluoride resin is a copolymer that contains structural units derived from vinylidene fluoride in an amount of 50 mol % or more, with respect to a total amount of structural units of the copolymer.
4. The separator for a non-aqueous secondary battery according to claim 1 , wherein the adhesive layer is formed on both sides of the porous substrate.
5. The separator for a non-aqueous secondary battery according to claim 4 , wherein
a total amount of the particles in the two adhesive layers formed on the porous substrate is from 0.2 g/m 2 to 12.0 g/m 2 , and
of the two adhesive layers formed on the porous substrate, a difference between an amount of the particles in one adhesive layer and an amount of the particles in the other adhesive layer is 20% by mass or less, with respect to the total amount of the particles in the two adhesive layers.
6. The separator for a non-aqueous secondary battery according to claim 1 , wherein the porous substrate is a polyolefin microporous membrane containing polyethylene.
7. The separator for a non-aqueous secondary battery according to claim 6 , wherein the polyolefin microporous membrane comprises polyethylene and polypropylene.
8. The separator for a non-aqueous secondary battery according to claim 6 , wherein the polyolefin microporous membrane has a multilayer structure having two or more layers, in which at least one layer of the multilayer structure includes polyethylene, and at least one other layer includes polypropylene.
9. A method for producing a separator for a non-aqueous secondary battery, the method including coating a water-based dispersion including particles containing a polyvinylidene fluoride resin, on at least one side of a porous substrate, followed by drying, to form an adhesive layer that is an aggregate layer of the particles, thereby producing the separator for a non-aqueous secondary battery according to claim 1 .
10. A non-aqueous secondary battery comprising a positive electrode, a negative electrode, and the separator for a non-aqueous secondary battery according to claim 1 , the separator being disposed between the positive electrode and the negative electrode, wherein in the non-aqueous secondary battery, electromotive force is obtained by lithium doping/dedoping.