Method of making negative electrode
[Problem] To provide a negative electrode collector for lithium ion secondary batteries, having a high strength and a large discharge capacity. [Means for Resolution] A negative electrode collector using a copper-covered steel foil 10 for carrying a negative electrode active material for lithium ion secondary batteries, which has a steel sheet 6 as the core material thereof and has, on both surfaces thereof, a copper covering layer 7 having a mean thickness t Cu of from 0.02 to 5.0 μm on each surface, and of which the total mean thickness, t, including the copper covering layer 7 is from 3 to 100 μm with t Cu /t of at most 0.3. To the steel sheet 6 , for example, applicable is common steel, austenitic stainless steel or ferritic stainless steel. The copper covering layer 7 is, for example, a copper electroplating layer (including one rolled after plating). On the surface of the copper covering layer 7 , for example, a carbon-based active material layer that has been densified through strong roll pressing is formed, and the copper-covered steel foil 10 and the carbon-based active material layer constitute the negative electrode collector.
1. A method for producing a negative electrode for a lithium ion secondary battery, which comprises:
a step of forming a coating film that contains a carbon-based active material for a negative electrode of a lithium ion secondary battery, on the surface of at least one copper covering layer of a copper-covered steel foil, the copper-covered steel foil comprising a steel sheet as a core material thereof and has, on both surfaces thereof, the copper covering layer, the copper covering layer having a mean thickness t Cu of from 0.02 to 5.0 μm on each surface, and of which the total mean thickness, t, including the copper covering layer is from 3 to 100 μm with t Cu /t of at most 0.3, and
a step of roll-pressing the coating film, after drying it, to reduce the coating film thickness by from 30 to 70% thereby densifying the coating film.
2. A method for producing a negative electrode for a lithium ion secondary battery, which comprises:
a step of forming a coating film that contains a carbon-based active material for a negative electrode of a lithium ion secondary battery, on the surface of at least one copper covering layer of a copper-covered steel foil, the copper-covered steel foil comprising a steel sheet as a core material thereof and has, on both surfaces thereof, the copper covering layer, the copper covering layer having a mean thickness t Cu of from 0.02 to 5.0 μm on each surface, and of which the total mean thickness, t, including the copper covering layer is from 3 to 100 μm with t Cu /t of at most 0.3, and
a step of roll-pressing the coating film, after drying it, to increase the density of the coating film to at least 1.80 g/cm 3 thereby densifying the coating film.
3. The method as claimed in claim 1 , wherein the copper covering layer is a copper electroplating layer, including one rolled after plating.
4. The method as claimed in claim 1 , wherein the copper covering layer is a copper foil layer integrated with the steel sheet through cladding.
5. The method as claimed in claim 1 , wherein the steel sheet is formed of a cold-rolled steel plate, including steel strip, as defined in JIS G3141:2009.
6. The method as claimed in claim 1 , wherein the steel sheet has an austenitic or ferritic chemical composition as defined in JIS G4305:2005.
7. The method as claimed in claim 1 , wherein the steel sheet has a composition comprising, in terms of % by mass, C: 0.001 to 0.15%, Si: 0.001 to 0.1%, Mn: 0.005 to 0.6%, P: 0.001 to 0.05%, S: 0.001 to 0.5%, Al: 0.001 to 0.5%, Ni: 0.001 to 1.0%, Cr: 0.001 to 1.0%, Cu: 0 to 0.1%, Ti: 0 to 0.5%, Nb: 0 to 0.5%, N: 0 to 0.05%, with a balance of Fe and an inevitable impurity.
8. The method as claimed in claim 1 , wherein the steel sheet has a composition comprising, in terms of % by mass, C: 0.0001 to 0.15%, Si: 0.001 to 4.0%, Mn: 0.001 to 2.5%, P: 0.001 to 0.045%, S: 0.0005 to 0.03%, Ni: 6.0 to 28.0%, Cr: 15.0 to 26.0%, Mo: 0 to 7.0%, Cu: 0 to 3.5%, Nb: 0 to 1.0%, Ti: 0 to 1.0%, Al: 0 to 0.1%, N: 0 to 0.3%, B: 0 to 0.01%, V: 0 to 0.5%, W: 0 to 0.3%, total of Ca, Mg, Y, REM (rare earth metal): 0 to 0.1%, with a balance of Fe and an inevitable impurity.
9. The method as claimed in claim 1 , wherein the steel sheet has a composition comprising, in terms of % by mass, C: 0.0001 to 0.15%, Si: 0.001 to 1.2%, Mn: 0.001 to 1.2%, P: 0.001 to 0.04%, S: 0.0005 to 0.03%, Ni: 0 to 0.6%, Cr: 11.5 to 32.0%, Mo: 0 to 2.5%, Cu: 0 to 1.0%, Nb: 0 to 1.0%, Ti: 0 to 1.0%, Al: 0 to 0.2%, N: 0 to 0.025%, B: 0 to 0.01%, V: 0 to 0.5%, W: 0 to 0.3%, total of Ca, Mg, Y, REM (rare earth metal): 0 to 0.1%, with a balance of Fe and an inevitable impurity.
10. The method as claimed in claim 1 , wherein the copper-covered steel foil has a tensile strength of from 450 to 900 MPa.
11. The method as claimed in claim 1 , wherein the copper-covered steel foil has a tensile strength of from more than 600 to 900 MPa.
12. The method as claimed in claim 2 , wherein the copper covering layer is a copper electroplating layer, including one rolled after plating.
13. The method as claimed in claim 2 , wherein the copper covering layer is a copper foil layer integrated with the steel sheet through cladding.
14. The method as claimed in claim 2 , wherein the steel sheet is formed of a cold-rolled steel plate, including steel strip, as defined in JIS G3141:2009.
15. The method as claimed in claim 2 , wherein the steel sheet has an austenitic or ferritic chemical composition as defined in JIS G4305:2005.
16. The method as claimed in claim 2 , wherein the steel sheet has a composition comprising, in terms of % by mass, C: 0.001 to 0.15%, Si: 0.001 to 0.1%, Mn: 0.005 to 0.6%, P: 0.001 to 0.05%, S: 0.001 to 0.5%, Al: 0.001 to 0.5%, Ni: 0.001 to 1.0%, Cr: 0.001 to 1.0%, Cu: 0 to 0.1%, Ti: 0 to 0.5%, Nb: 0 to 0.5%, N: 0 to 0.05%, with a balance of Fe and an inevitable impurity.
17. The method as claimed in claim 2 , wherein the steel sheet has a composition comprising, in terms of % by mass, C: 0.0001 to 0.15%, Si: 0.001 to 4.0%, Mn: 0.001 to 2.5%, P: 0.001 to 0.045%, S: 0.0005 to 0.03%, Ni: 6.0 to 28.0%, Cr: 15.0 to 26.0%, Mo: 0 to 7.0%, Cu: 0 to 3.5%, Nb: 0 to 1.0%, Ti: 0 to 1.0%, Al: 0 to 0.1%, N: 0 to 0.3%, B: 0 to 0.01%, V: 0 to 0.5%, W: 0 to 0.3%, total of Ca, Mg, Y, REM (rare earth metal): 0 to 0.1%, with a balance of Fe and an inevitable impurity.
18. The method as claimed in claim 2 , wherein the steel sheet has a composition comprising, in terms of % by mass, C: 0.0001 to 0.15%, Si: 0.001 to 1.2%, Mn: 0.001 to 1.2%, P: 0.001 to 0.04%, S: 0.0005 to 0.03%, Ni: 0 to 0.6%, Cr: 11.5 to 32.0%, Mo: 0 to 2.5%, Cu: 0 to 1.0%, Nb: 0 to 1.0%, Ti: 0 to 1.0%, Al: 0 to 0.2%, N: 0 to 0.025%, B: 0 to 0.01%, V: 0 to 0.5%, W: 0 to 0.3%, total of Ca, Mg, Y, REM (rare earth metal): 0 to 0.1%, with a balance of Fe and an inevitable impurity.
19. The method as claimed in claim 2 , wherein the copper covering layer has a tensile strength of from 450 to 900 MPa.
20. The method as claimed in claim 2 , wherein the copper covering layer has a tensile strength of from more than 600 to 900 MPa.