Organice electroluminescent materials and devices

1. A first device comprising a first organic light emitting device, further comprising: an anode, a cathode and an emissive layer disposed between the anode and the cathode, said emissive layer comprising a phosphorescent emissive dopant and a host material, the host material comprising nanocrystals, wherein said phosphorescent emissive dopant is bonded to said host material by a bridge moiety, wherein at least 50% of ligands bonded to said nanocrystals are compact ligands with fewer than 10 total atoms.

2. The first device according to claim 1 , wherein said bridge moiety is selected from the group consisting of a carboxylate, a phosphonate, a thiol, a sulfonic group and an amine group.

3. The first device according to claim 1 , wherein said nanocrystals comprise an inorganic material.

4. The first device according to claim 3 , wherein the inorganic material comprises one or more inorganic materials selected from the group consisting of a sulfide, a selenide, a telluride, an arsenide, a phosphide, a nitride, a carbide, an oxide, a fluoride, an oxysulfide, and combinations thereof.

5. The first device according to claim 3 , wherein said inorganic material comprises one or more inorganic materials selected from the group consisting of ZnO, In 2 O 3 , NiO, MnO, MoS 2 , TiO 2 , SiC, CdS, CdSe, GaAs, InP, ZnSe, ZnTe, GeS 2 , InAs, CdTe, ZnS, CdSe x S 1-x , ZnSe x Te 1-x , Al x Zn 1-x O, In 2-x Sn x O 3 , AlGaAs, CuInS 2 , CuInSe 2 , NaYF 4 , BaTiO 3 , SnO 2 , SnO 2-x F x , SnS 2 , Gd 2 O 2 S, and combinations thereof.

6. The first device according to claim 1 , wherein the host material has an energy band gap of less than 4 eV.

7. The first device according to claim 1 , wherein said nanocrystals have a size ranging from 1 to 20 nm.

8. The first device according to claim 1 , wherein less than 50% of the ligands bonded to said nanocrystals are long-chain organic ligands.

9. The first device according to claim 1 , wherein the phosphorescent emissive dopant comprises a transition metal complex having at least one ligand or part of the ligand if the ligand is more than bidentate selected from the group consisting of:

wherein R a , R b , R c , and R d may represent mono, di, tri, or tetra substitution, or no substitution;

wherein R a , R b , R c , and R d are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, a bridge moiety, and combinations thereof; and

wherein two adjacent substituents of R a , R b , R c , and R d are optionally joined to form a fused ring or form a multidentate ligand.

10. The first device according to claim 1 , wherein the concentration of the host material in the emissive layer is 10-90 wt-%.

11. The first device according to claim 1 , wherein the host material consists essentially of a substance containing at least 70 wt-% inorganic material.

12. The first device according to claim 1 , wherein the phosphorescent emissive dopant is an iridium complex, a platinum complex or a combination of both.

13. The first device according to claim 1 , wherein the material host has an energy band gap value larger than the triplet energy of the phosphorescent emissive dopant.

14. The first device according to claim 1 , wherein the emissive layer further comprises a second host material, a second phosphorescent emissive dopant, or both.

15. The first device according to claim 14 , wherein the concentration of the second host material in the emissive layer is at least 10 wt-%.

16. The first device according to claim 1 , wherein the emissive layer further comprises a second host material comprising an organic compound selected from the group consisting of triphenylene, dibenzothiophene, aza-dibenzothiophene, dibenzofuran, aza-dibenzofuran, carbazole, aza-carbazole, and combinations thereof.

17. The first device according to claim 16 , wherein the second host material comprising the compound selected from the group consisting of:

and combinations thereof.

18. The first device according to claim 1 , wherein the first device is a consumer product.

19. The first device according to claim 1 , wherein the first device is an organic light-emitting device.

20. The first device according to claim 1 , wherein the first device comprises a lighting panel.

21. A method of making a first organic light emitting device, comprising:

depositing a first electrode layer over a substrate;

forming an emissive layer over said first electrode layer, said emissive layer comprising a phosphorescent emissive dopant and a nanocrystal host material, wherein said phosphorescent emissive dopant is bonded to said nanocrystal host material by a bridge moiety, wherein said forming step comprises:

depositing a solid film of said nanocrystal host material over said first electrode layer, and

immersing said solid film in a solution containing said prepared phosphorescent emissive dopant, thereby replacing surface ligands coupled to said nanocrystal host material with said prepared phosphorescent emissive dopant to convert said solid film to a film of modified nanocrystal-phosphorescent dopant complex in which the phosphorescent emissive dopant is bonded to the nanocrystal host material; and

depositing a second electrode layer over said emissive layer, wherein said emissive layer is disposed between said first electrode and said second electrode, wherein said forming an emissive layer comprising preparing said phosphorescent emissive dopant to include said bridge moiety.

22. The first device according to claim 1 , wherein the compact ligand is a short-chain organic ligand comprising a functional group selected from the group consisting of carboxylates, amines, thiols, phosphonates, and combinations thereof.

23. The first device according to claim 1 , wherein the compact ligand is a short-chain organic ligand selected from the group consisting of formic acid, 1,2-ethanedithiol, 1,4-benzene dithiol, ethylenediamine, and combinations thereof.

24. The first device according to claim 1 , wherein the compact ligand is an inorganic ligand selected from the group consisting of chalcogenide complexes, simple chalcogenide ions, chalcogenocyanates, halides, tetrafluoroborate, hexafluorophosphate and combinations thereof.

25. The first device according to claim 9 , wherein at least one of R a , R b , R c , and R d is a bridge moiety.

26. A composition comprising a phosphorescent emissive dopant and a host material, the host material comprising nanocrystals, wherein said phosphorescent emissive dopant is bonded to said nanocrystals by a bridge moiety to form a plurality of nanocrystal-phosphorescent dopant complexes, wherein at least 50% of ligands bonded to said nanocrystals are compact ligands with fewer than 10 total atoms.

27. The composition of claim 26 , wherein said composition is provided as a solution, wherein said nanocrystal-phosphorescent dopant complexes are dispersed in a solvent.

28. The composition of claim 26 , wherein said composition is provided as a layer of film comprising said nanocrystal-phosphorescent dopant complexes.

29. The composition of claim 26 , wherein said host material has an energy band gap of less than 4 eV.

30. The method according to claim 21 , wherein said host material has an energy band gap of less than 4 eV.