Integrated circuit carrier coating
View Patent ↗A device includes an integrated circuit (IC) carrier for a semiconductor device, and a coating on the IC carrier. In the presence of an electrical field or a magnetic field, the coating includes a first functional group that attracts anions and a second functional group that attracts cations.
1. A device comprising:
an integrated circuit (IC) carrier for a semiconductor device; and
a coating on the IC carrier, wherein, in the presence of an electrical field or a magnetic field, the coating includes a functionalized self-assembled monolayer (SAM) material that comprises:
an anchoring element that has an affinity for attachment to a metal surface,
a first functional group that carries a positive charge to attract and immobilize anions, and
a second functional group that carries a negative charge to attract and immobilize cations, and
the anions and the cations are ionic contaminants.
2. The device of claim 1 wherein the first functional group includes amino alkane thiols.
3. The device of claim 1 wherein the first functional group includes hydroxyl alkane thiols.
4. The device of claim 1 wherein the second functional group includes carboxy alkane thiols.
5. The device of claim 1 wherein the IC carrier is either a printed circuit board or a package substrate including one of a group consisting of:
a leadframe, a quad flat no lead (QFN), a power QFN, a ball grid array, micro leadframe, small outline leadframe, thin small outline, zig-zag inline, single inline package, dual inline package, flatpack, land grid array, pin grid array, plastic leaded chip carrier, chip scale package, flip chip, package on package, and quilt packaging.
6. The device of claim 1 wherein the anchoring element is sulfur.
7. The device of claim 1 wherein the coating covers a majority of a surface of leads on the IC carrier.
8. A packaged semiconductor device comprising:
an integrated circuit (IC) carrier;
an integrated circuit (IC) mounted on the IC carrier;
a mold compound encapsulating at least a portion of the IC carrier and the IC;
a protective coating on the IC carrier, wherein the protective coating is applied in regions that are subject to electrical or magnetic fields generated by the IC, and the protective coating includes a functionalized self-assembled monolayer (SAM) material that comprises an anchoring element that has an affinity for attachment to a metal surface and at least two functional groups, wherein a first functional group of the at least two functional groups carries a positive charge to attract and immobilize anions from the mold compound, and a second functional group of the at least two functional groups carries a negative charge to attract and immobilize cations from the mold compound, and wherein the anions and the cations are ionic contaminants from the mold compound.
9. The device of claim 8 wherein the first functional group includes at least one of a group consisting of: amino alkane thiols and hydroxyl alkane thiols.
10. The device of claim 8 wherein the second functional group includes carboxy alkane thiols.
11. The device of claim 8 wherein the IC carrier is either a printed circuit board or a package substrate including one of a group consisting of:
a leadframe, a quad flat no lead (QFN), a power QFN, a ball grid array, micro leadframe, small outline leadframe, thin small outline, zig-zag inline, single inline package, dual inline package, flatpack, land grid array, pin grid array, plastic leaded chip carrier, chip scale package, flip chip, package on package, and quilt packaging.
12. The device of claim 8 wherein the anchoring element includes sulfur.
13. The device of claim 1 wherein the first functional group immobilizes the anions by formation of a chemical bond with the anions, and the second functional group immobilizes the cations by formation of a chemical bond with the cations.
14. The device of claim 1 wherein
the first functional group carries the positive charge when the first functional group oxidizes in the presence of the electrical field or the magnetic field to change from a neutral chemical state to a positively charged chemical state,
the first functional group immobilizes the anions by formation of a chemical bond with the anions in the presence of the electrical field or the magnetic field, and
the first functional group is chemically bonded with the anions after removal of the electrical field or the magnetic field.
15. The device of claim 1 wherein
the second functional group carries the negative charge when the second functional group oxidizes in the presence of the electrical field or the magnetic field to change from a neutral chemical state to a negatively charged chemical state,
the second functional group immobilizes the cations by formation of a chemical bond with the cations in the presence of the electrical field of the magnetic field, and
the second functional group is chemically bonded with the cations after removal of the electrical field or the magnetic field.
16. The device of claim 1 wherein the coating includes a functionalized SAM molecule comprising the anchoring element, the first functional group, the second functional group, and a carbon chain that links the first functional group and the second functional group to the anchoring element.
17. The device of claim 1 wherein the coating includes a first functionalized SAM molecule comprising the anchoring element, the first functional group, and a first carbon chain that links the first functional group to the anchoring element, and wherein the coating includes a second functionalized SAM molecule comprising the anchoring element, the second functional group, and a second carbon chain that links the second functional group to the anchoring element.
18. The device of claim 1 wherein the coating comprises a first set of functionalized SAM molecules and a second set of functionalized SAM molecules, wherein the first set of functionalized SAM molecules includes the first functional group that carries the positive charge, and the second set of functionalized SAM molecules includes the first functional group that is chemically bonded to at least one anion.
19. The device of claim 1 wherein the coating comprises a first set of functionalized SAM molecules and a second set of functionalized SAM molecules, wherein the first set of functionalized SAM molecules includes the second functional group that carries the negative charge, and the second set of functionalized SAM molecules includes the second functional group that is chemically bonded to at least one cation.
20. The device of claim 8 wherein
the IC carrier comprises a plurality of metal contacts,
a surface of the mold compound and the plurality of metal contacts are exposed to an ambient environment,
the cations and the anions migrate along the surface of the mold compound toward the metal contacts in the presence of moisture in the ambient environment, and
the cations and the anions are immobilized by the protective coating on a surface of the metal contacts adjacent to the surface of the mold compound.