Synergistic fungicidal composition and methods of use
Described is a broad spectrum, synergistic fungicidal composition when used for the preservation of a glued wood product comprising as active ingredients: (A) triadimefon, and (B) cyproconazole characterized in that the weight ratio of (A):(B) is from about 20:1 to about 1:1, the composition being further characterized in that the application rate for the composition is from about 10 gai/m 3 to about 6,000 gai/m 3 .
1. A method for the preservation of a glued wood product against a broad spectrum of fungi selected from the group of fungi causing brown rot, white rot, dry rot and soft rot, the method comprising the steps of:
(i) providing at least one of wood flakes, strands, particles, fibres and veneers;
(ii) providing a glue additive comprising a fungicidally effective amount of:
(A) a first active ingredient comprising triadimefon, and
(B) a second active ingredient comprising cyproconazole
at synergistic weight ratios of (A) to (B) from 20:1 to 6:1,
wherein the glue additive is to be applied at application rates which vary within the range from 100 gai/m 3 to 4,490 gai/m 3 for triadimefon (A) and within the range from 10 gai/m 3 to 2,000 gai/m 3 for cyproconazole (B), provided that the total application rate does not exceed 4,500 gai/m 3 ;
(iii) providing a glue to bond the at least one of wood flakes, strands, particles, fibres and veneers;
(iv) configuring the at least one of wood flakes, strands, particles, fibres and veneers, the glue additive, and the glue; and
(v) forming the glued wood product.
2. The method of claim 1 comprising an additional step (vi), wherein the glue additive is applied as a surface treatment for the formed glued wood product.
3. The method of claim 1 wherein the application rate for triadimefon (A) is from 100 gai/m 3 to 2,700 gai/m 3 and the application rate for cyproconazole (B) is from 100 gai/m 3 to about 300 gai/m 3 .
4. The method according to claim 1 wherein the glue additive is applied during manufacture of a glued wood product by direct application to at least one of wood flakes, strands, particles, fibres and veneers at any stage prior to the addition of the glue component; or by mixing into the glue prior to a veneer layup operation; or by mixing the glue additive with at least one of wood flakes, strands, particles, and fibres by injection into a refiner, blow line, or tumbler prior to, at the same time or after injection of the glue mixture.
5. The method according to claim 1 wherein the glued wood product is selected from:
(i) an engineered wood product comprising glued wood veneers, such products including laminated veneer lumber and plywood;
(ii) a reconstituted wood product selected from the group comprising at least one of glued wood flakes, strands, particles and fibres, such products including strand board, oriented strand board, parallel strand lumber, flake board, particle board, medium density fibreboard, high density fibreboard, hardboard, wood plastic composites, and mixtures thereof; and
(iii) a product comprising engineered and reconstituted wood products.
6. The method according to claim 1 wherein the glue component of the glued wood product is selected from an amino resin including urea-formaldehyde, melamineformaldehyde, melamine-urea-formaldehyde, and hydroxymethyl or alkoxymethyl derivatives of urea, melamine, benzoguanamine, or glycoluril, a phenolic resin including phenol-formaldehyde, resorcinol-formaldehyde or phenol-resorcinol-formaldehyde, an isocyanate resin, a PYA adhesive, a polyurethane adhesive, a protein based adhesive, and/or a derivative or combination thereof.
7. A preserved glued wood product treated by the method of claim 1 .
8. The method according to claim 1 , wherein the synergistic weight ratios of (A) to (B) from 20:1 to about 10:1.
9. The method according to claim 2 , wherein the glue additive has a synergy factor of 1.96 or greater based on an ED 90 for the triadimefon and the cyproconazole.