Palladium-based catalyst and support systems
Described are catalyst compositions, oxidizable-gas burner systems, methods of oxidizing oxidizable gas, and methods of preparing catalyst compositions and oxidizable-gas burner systems.
1. An oxidizable-gas burner system comprising:
an oxidizable gas source,
a heat source, and
a catalyst system comprising:
(i) an activating nanoporous support medium selected from the group consisting of an oxide of zirconium, an oxide of titanium, an oxide of manganese, an oxide of cerium optionally further comprising a mixture with aluminum oxide, and an oxide of a mixture of titanium, zirconium and manganese; and
(ii) a palladium metal physically vapor deposited on the support medium;
wherein the oxidizable gas source is in fluid communication with the heat source and the catalyst system is situated proximate to the heat source, wherein the palladium metal is present at from 0.001 to 5 weight percent palladium based on the total weight of the palladium and the support medium.
2. The system according to claim 1 , wherein the palladium metal is present from 0.04 to 0.5 weight percent palladium based on the total weight of the palladium and the support medium.
3. The system according to claim 1 , wherein at least 95 percent by weight of the palladium based on the total weight of the palladium and the support medium is deposited on the surface of the support medium.
4. The system according to claim 3 , wherein at least 99.5 percent by weight of the palladium based on the total weight of the palladium and the support medium is deposited on the surface of the support medium.
5. The system according to claim 1 , wherein the palladium metal has an oxidation state selected from +2 and +4.
6. A method comprising:
providing a system according to claim 1 , and
contacting the catalyst system with an oxidizable gas, wherein the T50 is below 400° C. and the palladium is present in an amount of from 0.001 to 5 weight percent palladium based on the total weight of the palladium and the support medium.
7. The method of claim 6 , wherein the palladium is present in an amount of from 0.04 to 0.5 weight percent palladium based on the total weight of the palladium and the support medium.