IP Library Granted Patent US 9,486,797
Granted Patent B2
US 9,486,797 · App. 14/897,104 · Granted Nov 8, 2016

Method for regenerating COS hydrolysis catalyst

Inventors: Masanao Yonemura (Tokyo, JP); Akihiro Sawata (Tokyo, JP); Yukio Tanaka (Tokyo, JP); Hiroshi Yoshioka (Tokyo, JP); Toshinobu Yasutake (Tokyo, JP)
Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.
B01J38/64B01J21/063B01J21/20B01J23/02B01J23/92B01J38/02B01J38/485B01J2523/00B01J2523/25B01J2523/31B01J2523/47
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Quick Facts
Patent No.
US 9,486,797
App. No.
14/897,104
Granted
Nov 8, 2016
Kind
B2
Abstract

The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to the present invention is a method for regenerating a Ba/TiO 2 based carbonyl sulfide (COS) hydrolysis catalyst by hydrolyzing COS which is contained in a gas obtained by gasifying a carbon raw material, wherein a spent COS hydrolysis catalyst is washed with water, dried, immersed in an aqueous solution of a barium salt for a prescribed amount of time, dried, and calcined so as to re-support the active component on the surface of the COS hydrolysis catalyst, thus enabling the regeneration of the COS hydrolysis catalyst.

Claims (7)

1. A method for regenerating a barium oxide-based carbonyl sulfide (COS) hydrolysis catalyst by hydrolyzing COS which is contained in a gas obtained by gasifying a carbon raw material, wherein a spent COS hydrolysis catalyst is immersed in an aqueous solution of a barium salt for a prescribed amount of time, dried, and then calcined.

2. The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to claim 1 , wherein dust removal is performed prior to immersion.

3. The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to claim 1 , wherein drying is performed after water washing prior to immersion.

4. The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to claim 1 , wherein a temperature of the calcination is at least 200° C.

5. The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to claim 2 , wherein drying is performed after water washing prior to immersion.

6. The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to claim 2 , wherein a temperature of the calcination is at least 200° C.

7. The method for regenerating a carbonyl sulfide (COS) hydrolysis catalyst according to claim 3 , wherein a temperature of the calcination is at least 200° C.

Assignments (4)
CHANGE OF NAME Recorded Dec 14, 2023
From: MITSUBISHI HEAVY INDUSTRIES ENGINEERING, LTD.
To: MHI ENGINEERING, LTD.
Reel/Frame 066014/0774 →
NUNC PRO TUNC ASSIGNMENT Recorded Dec 14, 2023
From: MHI ENGINEERING, LTD.
To: MITSUBISHI HEAVY INDUSTRIES, LTD.
Reel/Frame 066014/0870 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2018
From: MITSUBISHI HEAVY INDUSTRIES, LTD.
To: MITSUBISHI HEAVY INDUSTRIES ENGINEERING LTD.
Reel/Frame 046633/0906 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2015
From: YONEMURA, MASANAO; SAWATA, AKIHIRO; TANAKA, YUKIO; YOSHIOKA, HIROSHI; YASUTAKE, TOSHINOBU
To: MITSUBISHI HEAVY INDUSTRIES, LTD.
Reel/Frame 037252/0102 →
Priority Claims (1)
JP 2013-273465 · Dec 27, 2013 · national
Continuity (1)
Related Publication 20160136636A1 · May 19, 2016