Heat curable silicone rubber composition
View Patent ↗The present invention provides a heat-curable silicone rubber composition capable of giving a stable and high antistatic property for a long time without degrading inherent properties of a silicone rubber, such as thermal stability. The heat-curable silicone rubber composition includes: (A) 100 parts by mass of a mixture of a polyorganosiloxane obtained by polymerization by using an alkali metal hydroxide as a polymerization catalyst and by neutralization, and a curing agent, and (B) 50 to 1000 ppm of an ionic substance containing an anion and a cation, and being a bis(trifluoromethanesulfonyl)imide as the anion.
1. A heat-curable silicone rubber composition comprising:
(A) 100 parts by mass of a mixture of a polyorganosiloxane obtained by polymerization by using an alkali metal hydroxide as a polymerization catalyst and by neutralization, and adding a curing agent, and
(B) 100 to 1000 ppm of an ionic substance containing an anion and a cation, and being a bis(trifluoromethanesulfonyl)-imide anion as the anion.
2. The heat-curable silicone rubber composition according to claim 1 , wherein the alkali metal polymerization catalyst used in polymerization of the component (A) is an alkali metal hydroxide catalyst selected from cesium hydroxide, rubidium hydroxide, potassium hydroxide, and sodium hydroxide.
3. The heat-curable silicone rubber composition according to claim 1 , wherein the cation of the component (B) is an imidazolium-based cation, a pyrrolidinium-based cation, a pyridinium-based cation, an ammonium-based cation, or a lithium cation.
4. The heat curable silicone rubber composition according to claim 1 , wherein the component (B) is selected from 1-butyl-1-methylpyrrolidinium.bis-(trifluoromethanesulfonyl)imide, 1-methyl-1-propylpyrrolidinium.bis(trifluoromethanesulfonyl)imide, 3-methyl-1-propylpyridinium.bis(trifluoromethanesulfonyl)imide, N-butyl-e-methylpyridinium.bis(trifluoromethanesulfonyl)imide, 1-methyl-1-propylpyridinium.bis(trifluoromethanesulfonyl)imide, diallyldimethylammonium.bis(trifluoromethanesulfonyl)imide, methyltrioctylammonium.bis(trifluoromethanesulfonyl)imide, 1-butyl-3-methylimidazolium.bis(trifluoromethanesulfonyl)imide, 1,2-dimethyl-3-propylimidazolium.bis(trifluoromethanesulfonyl)-imide, 1-ethyl-3-methylimidazolium.bis(trifluoromethane-sulfonyl)imide, 1-vinylimidazolium.bis(trifluoromethane-sulfonyl)imide, 1-allylimidazolium.bis(trifluoromethane-sulfonyl)imide, 1-allyl-3-methylimidazolium.bis(trifluoro-methanesulfonyl)imide, and lithium.bis(trifluoromethane-sulfonyl)imide.
5. A method for manufacturing the heat-curable silicone rubber composition according to claim 1 , the method comprising the steps of:
mixing the ionic substance of the component (B) and a filler containing a reinforcing silica to thereby carry the ionic substance on the filler, and then
mixing the resultant mixture with the component (A).
6. An antistatic silicone rubber cured product obtained by curing the silicone rubber composition according to claim 1 .
7. A heat-curable silicone rubber composition comprising:
(A) 100 parts by mass of a mixture of a polyorganosiloxane obtained by polymerization by using an alkali metal hydroxide as a polymerization catalyst and by neutralization, and adding a curing agent, and
(B) 100 to 1000 ppm of an ionic substance containing an anion and a cation, and being a bis(trifluoromethanesulfonyl)-imide anion as the anion,
wherein the component (A) further contains a reinforcing silica.
8. The heat-curable silicone rubber composition according to claim 7 , wherein the alkali metal polymerization catalyst used in polymerization of the component (A) is an alkali metal hydroxide catalyst selected from cesium hydroxide, rubidium hydroxide, potassium hydroxide, and sodium hydroxide.
9. The heat-curable silicone rubber composition according to claim 7 , wherein the cation of the component (B) is an imidazolium-based cation, a pyrrolidinium-based cation, a pyridinium-based cation, an ammonium-based cation, or a lithium cation.
10. The heat-curable silicone rubber composition according to claim 7 , wherein the component (B) is selected from 1-butyl-1-methylpyrrolidinium.bis(trifluoromethylsulfonyl)imide, 1-methyl-1-propylpyrrolidinium.bis(trifluoromethanesulfonyl)-imide, 3-methyl-1-propylpyridinium.bis(trifluoromethane-sulfonyl)imide, N-butyl-3-methylpyridinium.bis(trifluoromethane-sulfonyl)imide, 1-methyl-1-propylpyridnium bis(trifluoromethane-sulfonyl)imide, diallyldimethylammonium.bis(trifluoromethane-sulfonyl)imide, methyltrioctylammonium.bis(trifluoromethane-sulfonyl)imide, 1-butyl-3-methylimidazolium.bis(trifluoro-methanesulfonyl)imide, 1,2-dimethyl-3-propylimiadzolium.bis-(trifluoromethanesulfonyl)imide, 1-ethyl-3-methylimidazolium.bis(trifluoromethanesulfonyl)imide, 1-vinylimidazolium.bis(trifluoromethanesulfonyl)imide, 1-allylimidazolium.bis(trifluoromethanesulfonyl)imide, 1-allyl-3-methylimidazolium.bis(trifluoromethanesulfonyl)imide, and lithium.bis(trifluoromethanesulfonyl)imide.
11. A method for manufacturing the heat-curable silicone rubber composition according to claim 7 , the method comprising the steps of:
mixing the ionic substance of the component (B) and a filler containing a reinforcing silica to thereby carry the ionic substance on the filler, and then
mixing the resultant mixture with the component (A).
12. An antistatic silicone rubber cured product obtained by curing the silicone rubber composition according to claim 7 .