Solidification matrix comprising a carboxylic acid terpolymer
Stability enhancement agents for use in a solidification matrices and solid detergent compositions are described. Stability enhancement is provided by a hydratable salt, water and a carboxylic acid terpolymer forming a dimensionally stable solid compositions. Preferred carboxylic acid terpolymers include from about 40 to 90% by weight of a carboxylic acid monomer, anhydride or salt thereof, from about 4 to 40% by weight of a monomer comprising sulfo groups, and from about 4 to 40% by weight of a nonionic monomer set forth in formula (I). The stability enhancement composition for use in solid detergent compositions are preferably biodegradable and may be substantially free of phosphate and/or NTA-free and provide beneficial hard water scale control.
1. A solid detergent composition comprising:
between about 1 wt-% and about 15 wt-% of a terpolymer (A), said terpolymer (A) comprising in copolymerized form of about 75% by weight of acrylic acid, of about 20% by weight of 2-acrylamido-2-methylpropanesulfonic acid, and of about 5% by weight of a nonionic monomer of the formula (I)
H 2 C═CH—CH 2 —O[EO] 17 —H (I)
in which EO is ethylene oxide units;
between about 0.1 wt-% and about 50 wt-% water;
between 65 wt-% and about 95 wt-% alkali metal carbonate; and
between about 0.5 wt-% and about 10 wt-% surfactant;
wherein the solid detergent composition is dimensionally stable and has a growth exponent of less than 3% if heated at a temperature of 122° F. for two weeks.
2. The composition of claim 1 , wherein the terpolymer (A) further comprises in copolymerized form up to about 30% by weight of one or more further ethylenically unsaturated monomers.
3. The composition of claim 1 , further comprising a phosphonate detergent builder.
4. The composition of claim 3 , wherein the phosphonate detergent builder is in an amount less than about 5 wt-%.
5. The composition of claim 1 , wherein the surfactant is a nonionic surfactant.
6. The composition of claim 5 , wherein the nonionic surfactant comprises an alkoxylated surfactant.
7. The composition of claim 6 , wherein the alkoxylated surfactant is in an amount between about 1 wt. % and about 10 wt. %.
8. The composition of claim 5 , wherein the nonionic surfactant is an EO/PO copolymer.
9. The composition of claim 1 , wherein the terpolymer (A) is in an amount between about 1 wt-% and about 10 wt-%.
10. The composition of claim 1 , wherein the ratio of sodium carbonate to water is about 9.8.
11. The composition of claim 1 , wherein the surfactant is a nonionic surfactant and/or the composition further comprises at least one functional ingredient selected from the group consisting of: chelating agents, sequestering agents, inorganic detergents, organic detergents, alkaline sources, builders, water conditioners, rinse aids, hardening agents, bleaching agents, sanitizers, activators, fillers, defoaming agents, anti-redeposition agents, optical brighteners, dyes, odorants, stabilizing agents, dispersants, enzymes, corrosion inhibitors, thickeners and solubility modifiers.
12. A method of forming a solid detergent composition according to claim 1 comprising:
combining said alkali metal carbonate, water surfactant and terpolymer (A); and forming a cast, pressed, or extruded solid.
13. The method of claim 12 , wherein the surfactant is a nonionic surfactant and/or the solid detergent composition further comprises at least one functional ingredient selected from the group consisting of: chelating agents, sequestering agents, inorganic detergents, organic detergents, alkaline sources, builders, water conditioners, rinse aids, hardening agents, bleaching agents, sanitizers, activators, fillers, defoaming agents, anti-redeposition agents, optical brighteners, dyes, odorants, stabilizing agents, dispersants, enzymes, corrosion inhibitors, thickeners and solubility modifiers.
14. A method of forming the solid detergent composition of claim 1 comprising the steps of:
combining the alkali metal carbonate, the surfactant and at least one functional component to form a powder pre-mix;
mixing the powder pre-mix with a liquid pre-mix, the liquid pre-mix comprising the water and the
casting, pressing, and/or extruding the mixture obtained from mixing the power pre-mix with the liquid pre-mix.
15. The method of claim 14 , wherein the functional component is selected from the group consisting of: chelating agents, sequestering agents, inorganic detergents, organic detergents, alkaline sources, builders, water conditioners, rinse aids, hardening agents, bleaching agents, sanitizers, activators, fillers, defoaming agents, anti-redeposition agents, optical brighteners, dyes, odorants, stabilizing agents, dispersants, enzymes, corrosion inhibitors, thickeners and solubility modifiers.