IP Library Granted Patent US 9,493,013
Granted Patent B2
US 9,493,013 · App. 13/982,174 · Granted Nov 15, 2016

Inkjet ink set

Inventors: Xiaohe Chen (San Diego, CA); Pradeep Kumar Koyadan Kizhakkedath (Kerala, IN); Dennis P. Parazak (Oceanside, CA); Keshava A. Prasad (San Marcos, CA); Savka Ilieva Stoeva (San Diego, CA); Yi-Hua Tsao (San Diego, CA); Tze Hwei Tseeng (San Diego, CA); Ervin Mubarekyan (Sugar Land, TX)
Assignee: Hewlett-Packard Development Company, L.P.
B41J2/2107B41J2/2114C09D11/322C09D11/40C09D11/54
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Quick Facts
Patent No.
US 9,493,013
App. No.
13/982,174
Granted
Nov 15, 2016
Kind
B2
Abstract

An inkjet ink set includes a black ink, a yellow ink, a cyan ink, and a magenta ink. The magenta ink includes an ink vehicle including a polyurethane binder, and a dispersed magenta pigment in the ink vehicle. The magenta pigment is chosen from Pigment Red 282.

Claims (31)

1. An inkjet ink set, consisting of:

an aqueous black ink;

an aqueous yellow ink;

an aqueous cyan ink;

an aqueous magenta ink, including:

a first ink vehicle; and

a dispersed magenta pigment in the first ink vehicle, wherein the magenta pigment is Pigment Red 282;

a fixer vehicle including water; and

a fixing agent dispersed in the fixer vehicle, wherein the fixing agent is calcium propionate or calcium butyrate;

wherein the aqueous black ink includes a second ink vehicle, the aqueous yellow ink includes a third ink vehicle, and the aqueous cyan ink includes a fourth ink vehicle, wherein each of the aqueous black, aqueous yellow, and aqueous cyan inks individually includes a respective dispersed black, yellow and cyan pigment, and wherein each of the first, second, third and fourth ink vehicles includes a water-soluble polyurethane binder;

wherein, each of the first, second, third, and fourth ink vehicles individually further includes:

a solvent system of about 8 wt % 1,3-bis(2-hydroxyethyl)-5 5,-dimethylhydantoin, about 1.5 wt % 1,2-hydroxyethyl-2-pyrrolidinone, and from 0 wt % to 1.5 wt % of a glycerol polyoxyethyl ether;

optionally an additive chosen from any of a biocide, an anti-kogation agent, a surfactant, or a pH buffering agent; and

water as a balance.

2. The inkjet ink set as defined in claim 1 wherein the polyurethane binder has a weight average molecular weight ranging from about 20,000 to about 100,000.

3. The inkjet ink set as defined in claim 1 wherein the polyurethane binder has an acid number ranging from about 40 to about 60.

4. The inkjet ink set as defined in claim 1 wherein the yellow pigment is chosen from Pigment Yellow 74, Pigment Yellow 155, Pigment Yellow 213, or Pigment Yellow 128.

5. The inkjet ink set as defined in claim 1 wherein the cyan pigment is chosen from Pigment Blue 15:3 or Pigment Blue 15:4.

6. The inkjet ink set as defined in claim 1 wherein each of the dispersed black, yellow, cyan and magenta pigments includes a dispersant chosen from a styrene acrylic polymer containing a carboxylate group.

7. The inkjet ink set as defined in claim 6 wherein the styrene acrylic polymer containing the carboxylate group has a weight average molecular weight ranging from about 5000 to about 20,000, and an acid number ranging from about 120 to about 200.

8. The inkjet ink set as defined in claim 6 wherein the styrene acrylic polymer anionically disperses the respective black, yellow, cyan and magenta pigments.

9. The inkjet ink set as defined in claim 1 wherein the cyan pigment is Pigment Blue 15:4.

10. The inkjet ink set as defined in claim 1 wherein the water-soluble polyurethane binder has an acid number of about 40, and a weight average molecular weight ranging from 36,000 to 90,000.

11. An inkjet printing system, consisting of:

a first ink chamber including an aqueous black ink;

a second ink chamber including an aqueous yellow ink;

a third ink chamber including an aqueous cyan ink;

a fourth ink chamber including an aqueous magenta ink, the aqueous magenta ink including a dispersed magenta pigment in an ink vehicle, wherein the magenta pigment is Pigment Red 282; and

a fifth ink chamber including a fixer, the fixer including a fixing agent selected from the group consisting of calcium propionate and calcium butyrate;

wherein each of the black ink, yellow ink, cyan ink, and the magenta ink includes an ink vehicle including at least a solvent system of about 8 wt % 1,3-bis(2-hydroxyethyl)-5,5-dimethylhydantoin, about 1.5 wt % 1,(2-hydroxyethyl)-2-pyrrolidinone, and from 0 wt % to 1.5 wt % of a glycerol polyoxyethyl ether, a water-soluble polyurethane binder, and a balance of water, the water-soluble polyurethane binder having a weight average molecular weight ranging from about 20,000 to about 100,000, and an acid number ranging from about 40 to about 60.

12. The inkjet printing system as defined in claim 11 wherein the acid number of the water-soluble polyurethane binder ranges from about 40 to less than 55.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 21, 2013
From: CHEN, XIAOHE; KIZHAKKEDATH, PRADEEP KUMAR KOYADAN; PARAZAK, DENNIS P.; PRASAD, KESHAVA A.; STOEVA, SAVKA ILIEVA; TSAO, YI-HUA; TSEENG, TZE HWEI; MUBAREKYAN, ERVIN
To: HEWLETT-PACKARD DEVELOPMENT COMPANY, L.P.
Reel/Frame 031051/0138 →
Continuity (1)
Related Publication 20130307914A1 · Nov 21, 2013