Optical film, anti-reflection film, polarizing plate and liquid crystal display device
Disclosed is an optical film that has excellent adhesion and surface hardness between the film substrate and a hard coat layer or other functional layer, has improved brittleness, is transparent, and has low moisture absorption and high heat resistance. Additionally disclosed are an antireflective film, a polarizing plate, and a display device using the same. The optical film has at least a hard coat layer or a back coat layer as a functional layer containing a resin on a film substrate, and is characterized in that said film substrate contains a thermoplastic acrylic resin (A) and a cellulose ester resin (B), with the content ratio by mass of said thermoplastic acrylic resin (A) and said cellulose ester resin (B) being in a range thermoplastic acrylic resin (A):cellulose ester resin (B)=95:5 to 50:50.
1. An optical film comprising a film substrate and a hard coat layer containing a resin on the film substrate, wherein
the film substrate contains a mixture of a thermoplastic acrylic resin (A) and a cellulose ester resin (B),
a content ratio by mass of the thermoplastic acrylic resin (A) to the cellulose ester resin (B) in the film substrate is in a range of the thermoplastic acrylic resin (A)/the cellulose ester resin (B)=90/10 to 60/40,
a weight average molecular weight of the thermoplastic acrylic resin (A) contained in the film substrate is in a range of 110,000 to 500,000,
the hard coat layer contains a thermoplastic acrylic resin,
a weight average molecular weight of the thermoplastic acrylic resin contained in the hard coat layer is in a range of 80,000 to 500,000, and
the thermoplastic acrylic resin contained in the hard coat layer exists more in quantity in the vicinity of an interface between the film substrate and the hard coat layer than the hard coat layer surface.
2. The optical film of claim 1 , wherein the film substrate contains acrylic particles, and content ratio by mass of the acrylic particles to total mass of thermoplastic acrylic resin (A) and the cellulose ester resin (B) is in a range of total mass of the acrylic particles/thermoplastic acrylic resin (A) and the cellulose ester resin (B)=0.5/100 to 30/100.
3. The optical film of claim 1 , wherein a weight average molecular weight of the thermoplastic acrylic resin contained in the hard coat layer is in a range of 110,000 to 500,000.
4. The optical film of claim 1 , wherein the hard coat layer comprises the thermoplastic acrylic resin and a radical polymerization compound, wherein content ratio by mass of the thermoplastic acrylic resin to the radical polymerization compound is in a range of thermoplastic acrylic resin/radical polymerization compound=0.50/100 to 20/100.
5. The optical film of claim 1 , wherein the hard coat layer is composed of a multi-layer material, wherein the hard coat layer adjacent to the film substrate comprises the thermoplastic acrylic resin.
6. The optical film of claim 1 , further comprising a back coat layer containing a resin, and wherein
a weight average molecular weight of the cellulose ester resin (B) is in a range of 75,000 to 300,000,
the cellulose ester resin (B) has a total substitution degree of an acyl group in a range of 2.0 to 3.0 and a substitution degree of an acyl group having 3 to 7 carbon atoms in a range of 1.2 to 3.0, and
the back coat layer contains cellulose ester resin (C), wherein a weight average molecular weight of the cellulose ester resin (C) is in a range of 10,000 to 200,000.
7. The optical film of claim 6 , wherein the cellulose ester resin (C) has a total substitution degree of an acyl group in a range of 2.0 to 3.0 and a substitution degree of an acyl group having 3 to 7 carbon atoms in a range of 0 to 2.2.
8. The optical film of claim 6 , wherein the back coat layer comprises the cellulose ester resin (C) and a thermoplastic acrylic resin (D), wherein a weight average molecular weight of the thermoplastic acrylic resin (D) is in a range of 30,000 to 1,000,000, and a content ratio by mass the cellulose ester resin (C) to the thermoplastic acrylic resin (D) is in a range of 95/5 to 50/50.
9. The optical film of claim 1 , further comprising a back coat layer containing a resin and acrylic particles in a range of 0.1 to 50% by mass with respect to total mass of the a back coat layer.
10. The optical film of claim 9 , wherein an average particle diameter of the acrylic particles contained in the back coat layer is in a range of 0.1 to 1 μm.
11. An anti-reflection film produced by employing the optical film described in claim 1 , wherein a low refractive index layer is laminated on the hard coat layer directly or via another layer.
12. The anti-reflection film of claim 11 , wherein the low refractive index layer contains a cationic polymerization compound.
13. A polarizing plate employing the optical film described in claim 1 .
14. A liquid crystal display device employing the optical film described in claim 1 .
15. A polarizing plate employing the anti-reflection film described in claim 11 .
16. A liquid crystal display device employing the anti-reflection film described in claim 11 .
17. The optical film of claim 1 , wherein the film substrate is formed by a solution casting method.