Carbon black, method for the production thereof, and use thereof
The invention relates to carbon black having a C-14 content greater than 0.05 Bq/g and a ratio ΔD50/Dmode of the aggregate size distribution of less than 0.7. The carbon black is produced by thermal oxidative pyrolysis or thermal cleavage of the carbon black raw material in that the carbon black raw material contains renewable carbon black raw materials and an oxygen deficiency is present in the pyrolysis/cleavage reaction. The carbon blacks can be used in rubber and rubber mixtures, plastic, printing inks, inks, inkjet inks, toners, lacquers, paints, paper, adhesives, batteries, pastes, bitumens, concrete, and other building materials and as reducing agents in metallurgy.
1. A process for producing furnace carbon black,
the carbon black comprising
a C-14 content greater than 0.05 Bq/g; and
a ΔD50/Dmode ratio of the aggregate size distribution less than 0.7, the process comprising
thermal oxidative pyrolysis or thermal cleavage of a carbon black feedstock in a furnace-black reactor, wherein
the carbon black feedstock comprises a renewable carbon black feedstock and the amount of oxygen present during the pyrolysis/cleavage reaction of the carbon black feedstock is substoichiometric, and
the renewable carbon black feedstock comprises: rapeseed oil; soya oil; palm oil; sunflower oil; oils derived from nuts; olive oil; or a combination thereof.
2. The process of claim 1 , further comprising
terminating the reaction by cooling to temperatures below the pyrolysis temperature or cleavage temperature.
3. The process of claim 1 ,
wherein the furnace-black reactor comprises, along the reactor axis, a combustion zone, a reaction zone and a termination zone, and
wherein carrying out the reaction comprises
producing a stream of hot exhaust gas in the combustion zone through complete combustion of a fuel in a gas comprising oxygen,
passing the exhaust gas from the combustion zone through the reaction zone into the termination zone,
mixing the carbon black feedstock into the hot exhaust gas in the reaction zone, and
terminating carbon black formation in the termination zone by spraying water into the system.
4. A method of producing a product with a carbon black, comprising
producing a furnace carbon black in accord with the process of claim 1 ; and
introducing the furnace carbon black to a composition that is suitable for forming at least one of: a rubber, a rubber mixture, a plastic, a printing ink, an inkjet ink, an ink, a toner, a lacquer, a paint, paper, an adhesive, a battery, a paste, bitumen, concrete, a construction material.
5. A method of producing a product with a rubber mixture, comprising
producing a furnace carbon black in accord with the process of claim 1 ;
producing a rubber mixture by introducing the furnace carbon black to a composition suitable for making a rubber mixture; and
introducing the rubber mixture as, or as a part of, a composition that is suitable for forming at least one of: a tyre, tyre treads, cable sheathing, a hose, a drive belt, a conveyor belt, a roll covering, a shoe sole, a sealing ring, a profile element, and a damping element.
6. The process of claim 2 ,
wherein the furnace-black reactor comprises, along the reactor axis, a combustion zone, a reaction zone and a termination zone, and
wherein carrying out the reaction comprises
producing a stream of hot exhaust gas in the combustion zone through complete combustion of a fuel in a gas comprising oxygen,
passing the exhaust gas from the combustion zone through the reaction zone into the termination zone,
mixing the carbon black feedstock into the hot exhaust gas in the reaction zone, and
terminating carbon black formation in the termination zone by spraying water into the system.
7. A method of producing a product with a carbon black, comprising
producing a furnace carbon black in accord with the process of claim 1 ; and
introducing the furnace carbon black to a composition as a reducing agent in a metallurgy process.
8. The process of claim 1 , wherein
the resulting carbon black comprises a C-14 content greater than 0.10 Bq/g.
9. The process of claim 1 , wherein
the resulting carbon black comprises a C-14 content greater than 0.15 Bq/g.
10. The process of claim 1 , wherein
the resulting carbon black comprises a C-14 content greater than 0.25 Bq/g.
11. The process of claim 1 , wherein
the resulting carbon black comprises a C-14 content from greater than 0.05 Bq/g to 0.26 Bq/g.
12. The process of claim 1 , wherein
the resulting carbon black comprises a ΔD50/Dmode ratio of the aggregate size distribution from less than 0.6 to 0.54.