Conductive composition and conductive film
Provided is a conductive film having a high conductivity in which electric resistance is less likely to increase, and a conductive composition for forming the same. The conductive composition includes an elastomer component, a fibrous carbon material having a fiber diameter of less than 30 nm, and a flake-like carbon material having a graphite structure, having an intensity ratio (G/D ratio) of a peak (G band) appearing in the vicinity of 1580 cm −1 to a peak (D band) appearing in the vicinity of 1330 cm −1 of Raman spectrum of not less than 1.8, and having a maximum length of not less than 150 nm and a thickness of not more than 100 nm. The conductive film is formed from the conductive composition.
1. A conductive composition comprising:
an elastomer component;
a fibrous carbon material having a fiber diameter of less than 30 nm; and
a flake-like carbon material having a graphite structure, having an intensity ratio (G/D ratio) of a peak (G band) appearing in the vicinity of 1580 cm −1 to a peak (D band) appearing in the vicinity of 1330 cm −1 of Raman spectrum of not less than 1.8, and having a maximum length of not less than 150 nm and a thickness of not more than 100 nm, wherein,
the flake-like carbon material is produced from a carbon material having a graphite structure, a G/D ratio of Raman spectrum of not less than 1.8, and a ratio of the minimum length to the maximum length (minimum length/maximum length) of not more than ⅕,
the content of the fibrous carbon material is not less than 5% by mass and not more than 30% by mass with respect to 100% by mass of the solid content of the conductive composition,
the content of the flake-like carbon material is not less than 3% by mass and not more than 30% by mass with respect to 100% by mass of the solid content of the conductive composition, and
a blend ratio of the fibrous carbon material to the flake-like carbon material is set in a range of 5:1 to 1:4 by mass.
2. The conductive composition according to claim 1 , wherein the carbon material is one or more kinds selected from carbon nanotubes having a fiber diameter of 30 nm or more, cup-stacked carbon nanotubes, graphite, and expanded graphite.
3. The conductive composition according to claim 1 , wherein the fibrous carbon material is carbon nanotubes.
4. A conductive film formed from the conductive composition according to claim 1 .
5. The conductive film according to claim 4 formed by screen printing or metal mask printing.
6. The conductive film according to claim 4 formed on a surface of a substrate that is expandable and contractible, or bendable.
7. The conductive film according to claim 6 , wherein
the elastomer component in the conductive composition has a cross-linkable functional group;
the substrate is made of a polymer having a functional group; and
the conductive film is bonded to the substrate through chemical bonding between the cross-linkable functional group and the functional group.
8. An electromagnetic shield formed of the conductive film according to claim 4 .
9. A transducer comprising:
a dielectric layer made of a polymer;
a plurality of electrodes arranged with the dielectric layer interposed therebetween; and
a wire connected to each of the electrodes, wherein
either or both of the electrodes and the wire are formed of the conductive film according to claim 4 .
10. A flexible wiring board comprising:
a substrate; and
a wire arranged on a surface of the substrate, wherein
at least part of the wire is formed of the conductive film according to claim 4 .