Pressure-sensitive adhesive composition, polarization plate, and liquid crystal display
Provided are a pressure-sensitive adhesive (PSA) composition including an interpenetrating polymer network structure in a cured state, and including an acrylic resin and a crosslinking agent component that consists of a bifunctional crosslinking agent, a polarizer and a liquid crystal display. Provided are the PSA composition, the polarizer including a cured product of the PSA composition, and the liquid crystal display, which have excellent workability and optical properties, durability and reliability, at high temperature or humidity condition, and significantly increase productivity of optical members such as a polarizer, since the time-dependent change of the pressure-sensitive adhesive strength is rapidly ended after fabrication.
1. A polarizer, comprising:
a polarizing film or element; and
a pressure-sensitive adhesive layer formed on one or both sides of the polarizing film or element, and including a cured product of a pressure-sensitive adhesive composition,
wherein the pressure-sensitive adhesive composition includes an interpenetrating polymer network structure and has re-movability in a cured state,
wherein the composition comprises an acrylic resin; a crosslinking agent component consisting of a bifunctional crosslinking agent; a multi-functional acrylate; and a polymerization initiator, and satisfies Formula 1 and Formula 2:
X 1 ≦638 g/25 mm [Formula 1]
where X 1 represents peel strength measured after a pressure-sensitive adhesive formed from the pressure-sensitive adhesive composition adheres to a non-alkaline glass adherent and is then stored at room temperature for 168 hours,
X 2 ≦1162 g/25 mm [Formula 2]
where X 2 represents peel strength measured after the pressure-sensitive adhesive formed from the pressure-sensitive adhesive composition adheres to the adherent, and is then stored at 50° C. for about 4 hours, and is then stored at room temperature for 168 hours,
wherein the composition includes the interpenetrating polymer network structure in a cured state which is a condition which comprises a first crosslinked structure formed by the reaction of the acrylic resin and the crosslinking agent, and a second crosslinked structure formed by the multi-functional acrylate and the polymerization initiator, the first crosslinked structure and the second crosslinked structure existing simultaneously in the composition,
wherein the acrylic resin is a polymer of a monomer mixture including 80 to 99.9 parts by weight of a (meth)acrylic acid ester monomer and 0.1 to 20 parts by weight of a crosslinkable monomer, relative to 100 parts by weight of the acrylic resin
wherein the crosslinking agent component is included in an amount of 0.01 to 10 parts by weight, relative to 100 parts by weight of the acrylic resin, and
wherein the multi-functional acrylate is at least one trifunctional acrylate selected from the group consisting of trimethylolpropane tri(meth)acrylate, dipentaerythritol tri(meth)acrylate, propionic acid-modified dipentaerythritol tri(meth)acrylate, pentaerythritol tri(meth)acrylate, propyleneoxide-modified trimethylolpropane tri(meth)acrylate, trifunctional urethane (meth)acrylate and tris(meth)acryloxyethyl isocyanurate.
2. The polarizer according to claim 1 , wherein the acrylic resin has a weight average molecular weight of 300,000 or more.
3. The polarizer according to claim 1 , further comprising a surfactant or a plasticizer.
4. The polarizer according to claim 3 , wherein the surfactant is polyalkyleneoxide-modified polydimethylsiloxane.
5. The polarizer according to claim 3 , wherein the surfactant is represented by Formula 4:
where Me is methyl, x is an integer of 0 or more, y is an integer of 1 or more, A is —CH 2 CH 2 CH 2 O(EO) m Z, EO is ethylene oxide, PO is propylene oxide, Z is hydrogen, amine or alkyl, and m+n is 1 or more (but n is not 0).
6. The polarizer according to claim 3 , wherein the plasticizer is an ester compound having at least one ether linkage.
7. The polarizer according to claim 3 , wherein the plasticizer is represented by Formula 3:
where R 6 and R 7 are independently hydrogen, alkyl, allyl or aryl, R 8 is hydrogen or alkyl, and n is an integer of 2 to 20.
8. The polarizer according to claim 3 , wherein the surfactant or plasticizer is included in an amount of 0.0001 to 10 parts by weight relative to 100 parts by weight of the acrylic resin.
9. The polarizer according to claim 1 , wherein the multi-functional acrylate is included in an amount of 5 to 40 parts by weight relative to 100 parts by weight of the acrylic resin.
10. The polarizer according to claim 1 , wherein the polymerization initiator includes at least one selected from the group consisting of a thermal initiator and a photoinitiator.
11. The polarizer according to claim 1 , wherein the polymerization initiator is included in an amount of 0.2 to 20 parts by weight relative to 100 parts by weight of the acrylic resin.
12. A liquid crystal display comprising a liquid crystal panel in which the polarizer according to claim 1 is attached to one or both surfaces of a liquid crystal cell.