IP Library Granted Patent US 9,522,388
Granted Patent B2
US 9,522,388 · App. 14/154,089 · Granted Dec 20, 2016

Pinning and affixing nano-active material

Inventors: Qinghua Yin (Tempe, AZ); Xiwang Qi (Scottsdale, AZ); Eliseo Ruiz (Queen Creek, AZ)
Assignee: SDCmaterials, Inc.
B01J23/8926B01J23/42B01J35/0013B01J37/00B01J37/009B01J37/0211B01J37/32B01J37/349B28B23/0087B32B7/12B32B37/14B82Y30/00B82Y40/00C23C4/134
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Quick Facts
Patent No.
US 9,522,388
App. No.
14/154,089
Granted
Dec 20, 2016
Kind
B2
Abstract

A nanoparticle comprises a nano-active material and a nano-support. In some embodiments, the nano-active material is platinum and the nano-support is alumina. Pinning and affixing the nano-active material to the nano-support is achieved by using a high temperature condensation technology. In some embodiments, the high temperature condensation technology is plasma. Typically, a quantity of platinum and a quantity of alumina are loaded into a plasma gun. When the nano-active material bonds with the nano-support, an interface between the nano-active material and the nano-support forms. The interface is a platinum alumina metallic compound, which dramatically changes an ability for the nano-active material to move around on the surface of the nano-support, providing a better bond than that of a wet catalyst. Alternatively, a quantity of carbon is also loaded into the plasma gun. When the nano-active material bonds with the nano-support, the interface formed comprises a platinum copper intermetallic compound, which provides an even stronger bond.

Claims (20)

1. A catalyst comprising:

a nano-support material, wherein the nano-support has a partially reduced surface; and

a nano-catalytic material bonded to the partially reduced surface of the nano-support,

wherein the catalyst is prepared by vaporizing a support material and a catalytic material in a plasma stream under reducing conditions and condensing the vaporized support material and catalytic material to form nano-catalytic material on the nano-support material, said nano-support material having a partially reduced surface,

wherein the partially reduced surface of the nano-support material limits the movement of the nano-catalytic material on the surface of the nano-support, and

wherein the vaporizing under reducing conditions and condensing results in a more metallic surface of the nano-support by reducing the nano-support material.

2. The catalyst of claim 1 , wherein the nano-support comprises alumina.

3. The catalyst of claim 1 , wherein the nano-catalytic material comprises platinum.

4. The catalyst of claim 1 , wherein the plasma stream comprises hydrogen gas.

5. The catalyst of claim 1 , wherein the vaporized support material and catalytic material are condensed in a highly turbulent quench chamber.

6. A catalyst comprising:

a nano-support, wherein the nano-supports have a partially reduced surface; and

a nano-catalytic copper intermetallic compound bonded to the partially reduced surfaces of the nano-support,

wherein the catalyst is prepared by vaporizing a support material, a catalytic material, and copper in a plasma stream under reducing conditions and condensing the vaporized support material, catalytic material, and copper to form nano-catalytic copper intermetallic material on the nano-support material, said nano-support material having a partially reduced surface,

wherein the partially reduced surface of the nano-support material limits the movement of the nano-catalytic material on the surface of the nano-support, and

wherein the vaporizing under reducing conditions and condensing results in a more metallic surface of the nano-support by reducing the nano-support material.

7. The catalyst of claim 6 , wherein the nano-support comprises alumina.

8. The catalyst of claim 6 , wherein the nano-catalytic copper intermetallic material comprises platinum and copper.

9. The catalyst of claim 6 , wherein the plasma stream comprises hydrogen gas.

10. The catalyst of claim 6 , wherein the vaporized support material, catalytic material, and copper are condensed in a highly turbulent quench chamber.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 16, 2018
From: SM (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
To: UMICORE AG & CO. KG
Reel/Frame 045350/0280 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 19, 2014
From: YIN, QINGHUA; QI, XIWANG; RUIZ, ELISEO
To: SDCMATERIALS, INC.
Reel/Frame 032249/0634 →
Continuity (3)
Continuation 12962473 · Dec 7, 2010
Provisional Application 61284329 · Dec 15, 2009
Related Publication 20140128245A1 · May 8, 2014