Polyisocyanate-based adhesive
Adhesive prepared by reacting an organic polyisocyanate with a compound containing isocyanate-reactive hydrogen atoms in the presence of a trimerization catalyst. The softblock content of the adhesive is between 20 and 70 wt %.
1. A polyisocyanate based adhesive obtained by reacting, in the presence of a trimerisation catalyst, (i) a polymeric polyisocyanate or a prepolymeric polyisocyanate having an isocyanate content of 6 to 30 wt. % with (ii) a polyol selected from a polyether polyol, a polyester polyol and a combination thereof; wherein component (i) is the reaction product of an organic polyisocyanate and a compound containing isocyanate-reactive hydrogen atoms selected from a monohydric alcohol, polypropylene glycol, tetramethylene glycol, polytetramethylene glycol, polyhexamethylene glycol, polyheptamethylene glycol, polydecamethylene glycol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, 1,9-nonane diol, 2-methyl-1,8-octanediol, a polyester polyol, a mercaptan, a carboxylic acid, an amine, urea, an amide and a mixture thereof; wherein the trimerisation catalyst is selected from the group consisting of alkali metal salts of carboxylic acids; wherein the adhesive has a softblock content between 40 and 60 wt %; and wherein component (ii) does not comprise an amine compound and wherein component (i) and component (ii) are miscible with each other.
2. The adhesive according to claim 1 , wherein at least 50% of the softblock content is provided by the compound containing isocyanate-reactive hydrogen atoms present in the adhesive.
3. The adhesive according to claim 1 , wherein the trimerisation catalyst is used in an amount of 0.01 to 1% by weight based on the total formulation.
4. A laminated structure comprising a support structure, a second substrate layer and an adhesive binding the supporting layer to the second substrate layer wherein the adhesive layer comprises an adhesive as defined in claim 1 .
5. A laminated structure according to claim 4 , wherein the supporting structure is a film.
6. A reaction mixture for preparing a polyisocyanate based adhesive, the reaction mixture consisting of a trimerisation catalyst and (i) a polymeric polyisocyanate or a prepolymeric polyisocyanate having an isocyanate content of 6 to 30 wt. % and (ii) a polyol selected from the group consisting of polyester polyols, polyether polyols, and combinations thereof; wherein component (i) is the reaction product of an organic polyisocyanate and a compound containing isocyanate-reactive hydrogen atoms selected from a monohydric alcohol, polypropylene glycol, tetramethylene glycol, polytetramethylene glycol, polyhexamethylene glycol, polyheptamethylene glycol, polydecamethylene glycol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, 1,9-nonane diol, 2-methyl-1,8-octanediol, a polyester polyol, a mercaptan, a carboxylic acid, an amine, urea, an amide and a mixture thereof; wherein the trimerisation catalyst is selected from the group consisting of alkali metal salts of carboxylic acids; wherein the adhesive has a softblock content between 40 and 60 wt %; wherein component (ii) does not comprise an amine compound; and wherein component (i) and component (ii) are miscible with each other and do not separate into two or more phases.
7. The reaction mixture according to claim 6 , wherein at least 50% of the softblock content is provided by the compound containing isocyanate-reactive hydrogen atoms present in the adhesive.