Electrode assembly having safety separator and secondary battery including the same
Disclosed herein is an electrode assembly configured to have a structure in which two or more unit cells are sequentially stacked or a structure in which two or more unit cells are folded using a long sheet type separation film, wherein the unit cells include bi-cells, each of which includes a positive electrode, a negative electrode, and a separator, at least one of the bi-cells includes a safety electrode configured such that an electrode active material is applied only to one major surface of an electrode current collector, the safety electrode includes a first surface, to which no electrode active material is applied, and a second surface, to which the electrode active material is applied, and the at least one of the bi-cells including the safety electrode is configured such that a safety separator, having a thickness equivalent to 110% to 220% of a thickness of a separator disposed between a positive electrode and a negative electrode or between a negative electrode and a positive electrode excluding the safety electrode, is added to the first surface and/or the second surface of the safety electrode.
1. An electrode assembly configured to have a structure in which two or more unit cells are sequentially stacked or a structure in which two or more unit cells are folded using a long sheet type separation film, wherein
the unit cells comprise bi-cells, each of which comprises a positive electrode, a negative electrode, and a separator, at least one of the bi-cells comprises a safety electrode configured such that an electrode active material is applied only to one major surface of an electrode current collector, the safety electrode comprises a first surface, to which no electrode active material is applied, and a second surface, to which the electrode active material is applied, and the at least one of the bi-cells comprising the safety electrode is configured such that a safety separator, having a thickness equivalent to 110% to 220% of a thickness of a separator disposed between a positive electrode and a negative electrode or between a negative electrode and a positive electrode excluding the safety electrode, is added to the first surface and/or the second surface of the safety electrode.
2. The electrode assembly according to claim 1 , wherein the bi-cells comprise first bi-cells disposed at outermost sides of the electrode assembly and second bi-cells disposed between the first bi-cells.
3. The electrode assembly according to claim 2 , wherein each of the first bi-cells is configured to have a structure in which a safety separator, a safety electrode, a separator, a double-sided electrode, a separator, and a double-sided electrode are sequentially stacked.
4. The electrode assembly according to claim 3 , wherein the double-sided electrode is configured such that an electrode active material is applied to opposite major surfaces of a current collector.
5. The electrode assembly according to claim 2 , wherein each of the first bi-cells is configured to have a structure in which a safety separator, a safety electrode, a safety separator, a double-sided electrode, a separator, and a double-sided electrode are sequentially stacked.
6. The electrode assembly according to claim 2 , wherein each of the first bi-cells is configured to have a structure in which a safety electrode, a safety separator, a double-sided electrode, a separator, and a double-sided electrode are sequentially stacked.
7. The electrode assembly according to claim 2 , wherein each of the second bi-cell is configured to have the same structure as each of the first bi-cells and/or a structure in which a double-sided electrode, a separator, a double-sided electrode, a separator, and a double-sided electrode are sequentially stacked.
8. The electrode assembly according to claim 1 , wherein the safety electrode is disposed on at least one outermost side of the electrode assembly.
9. The electrode assembly according to claim 1 , wherein the separator and the safety separator each are an organic/inorganic composite porous safety-reinforcing separator (SRS).
10. The electrode assembly according to claim 9 , wherein the SRS separator is configured such that an active layer, comprising inorganic particles and a binder polymer, is coated on a polyolefin-based separator substrate.
11. The electrode assembly according to claim 10 , wherein a thickness ratio of the separator substrate to the active layer is 9:1 to 1:9.
12. The electrode assembly according to claim 11 , wherein the thickness ratio of the separator substrate to the active layer is 5:5.
13. The electrode assembly according to claim 10 , wherein the inorganic particles are one or more kinds of inorganic particles selected from a group consisting of (a) inorganic particles having piezoelectricity and (b) inorganic particles having lithium ion transfer ability.
14. The electrode assembly according to claim 13 , wherein the inorganic particles having piezoelectricity are one or more kinds of inorganic particles selected from a group consisting of BaTiO 3 , Pb(Zr,Ti)O 3 (PZT), Pb 1-x La x Zr 1-y Ti y O 3 (PLZT), Pb(Mg 3 Nb 2/3 )O 3 —PbTiO 3 (PMN-PT), and hafnia (HfO 2 ).
15. The electrode assembly according to claim 13 , wherein the inorganic particles having lithium ion transfer ability are one or more kinds of inorganic particles selected from a group consisting of lithium phosphate (Li 3 PO 4 ), lithium titanium phosphate (Li x Ti y (PO 4 ) 3 , where 0<x<2 and 0<y<3), lithium aluminum titanium phosphate (Li x Al y Ti z (PO 4 ) 3 , where 0<x<2, 0<y<1, and 0<z<3), (LiAlTiP) x O y -based glass (where 0<x<4 and 0<y<13), lithium lanthanum titanate (Li x La y TiO 3 , where 0<x<2 and 0<y<3), lithium germanium thio phosphate (Li x Ge y P z S w , where 0<x<4, 0<y<1, 0<z<1, and 0<w<5), lithium nitride (Li x N y , where 0<x<4 and 0<y<2), SiS 2 -based glass (Li x Si y S z , where 0<x<3, 0<y<2, and 0<z<4), and P 2 S 5 -based glass (Li x P y S z , where 0<x<3, 0<y<3, and 0<z<7).
16. The electrode assembly according to claim 1 , wherein the separator has a thickness of 10 to 14 micrometers.
17. The electrode assembly according to claim 1 , wherein the safety separator added to the second surface has a thickness of 15 to 30 micrometers.
18. The electrode assembly according to claim 17 , wherein the safety separator added to the second surface has a thickness of 20 micrometers.
19. The electrode assembly according to claim 1 , wherein the safety separator added to the first surface has a thickness equivalent to 80 to 95% of a thickness of the safety separator added to the second surface.
20. A secondary battery having an electrode assembly according to claim 1 mounted in a battery case.
21. The secondary battery according to claim 20 , wherein the battery case is a pouch-shaped case made of an aluminum laminate sheet or a metal can-shaped case.
22. A battery pack comprising a secondary battery according to claim 20 as a unit battery.
23. A device comprising a battery pack according to claim 22 as a power source.
24. The device according to claim 23 , wherein the device is selected from among a mobile phone, a portable computer, a smartphone, a smart pad, a tablet PC, and a netbook computer.