Process for preparing aqueous polymer dispersions for adhesives
The present invention relates to aqueous polymer dispersions having a polymer content of at least 55% by weight that are suitable for pressure sensitive adhesives. The invention also relates to a process for preparing these aqueous polymer dispersions and also to the use of the aqueous polymer dispersions in pressure sensitive adhesives and, respectively, pressure sensitive adhesive compositions, especially in pressure sensitive adhesives for transparent substrates, such as plastics labels. The aqueous polymer dispersions have a polymer content of at least 55% by weight, based on the total weight of the dispersion, the polymer being composed of ethylenically unsaturated monomers M and having a glass transition temperature below −10° C., in which the dispersed polymer particles have a polymodal particle size distribution, in which at least 70% by weight have a particle diameter of below 350 nm.
1. A process for preparing an aqueous polymer dispersion,
the process comprising:
performing free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers M by a monomer feed process,
wherein the monomer feed process comprises:
adding at least 95% of the monomers to be polymerized under polymerization conditions to a first particulate seed polymer 1 located in the polymerization reactor, and
adding at least one further seed polymer 2 in the form of an aqueous dispersion to the polymerization reactor in the course of the polymerization to obtain the aqueous polymer dispersion,
wherein the aqueous polymer dispersion has a polymer content of at least 55% by weight, based on the total weight of the dispersion, in which the polymer comprises the ethylenically unsaturated monomer units M and has a glass transition temperature of below −10° C., and in which dispersed polymer particles have a polymodal particle size distribution,
wherein 10% to 60% by weight of the polymer particles have a particle diameter in a range from 70 to 180 nm and 40 to 90% by weight of the polymer particles have a particle diameter in a range from 180 to 350 nm, and
wherein the particle size distribution has a polydispersity index Q of from 0.5 to 1.5:
Q
=
d
90
-
d
10
d
50
in which
d 10 is a particle diameter below which 10% by weight of the polymer particles fall,
d 50 is a particle diameter below which 50% by weight of the polymer particles fall, and which is in the range from 90 to 320 nm,
d 90 is a particle diameter below which 90% by weight of the polymer particles fall, which is not more than 350 nm,
and all particle diameters are determined at 23° C. by centrifuging and discriminating according to mass fractions,
and wherein the monomers M, based on a total amount of the monomers M, comprise at least 65% by weight of at least one C 2 -C 12 alkyl acrylate.
2. The process according to claim 1 , the seed polymer 2 being added when 10% to 60% by weight of the monomers to be polymerized are located in the polymerization reactor.
3. The process according to claim 1 , the seed polymer 1 being used in an amount of 0.1% to 2% by weight, based on the monomers to be polymerized.
4. The process according to claim 1 , the seed polymer 1 having a weight-average particle size in the range from 10 to 150 nm.
5. The process according to claim 1 , the seed polymer 2 being used in an amount of 0.05% to 2% by weight, based on the monomers to be polymerized.
6. The process according to claim 1 , wherein seed polymer 1 and seed polymer 2 comprise vinylaromatic monomer units.
7. The process according to claim 1 , wherein seed polymer 1 and seed polymer 2 comprise styrene.
8. The process according to claim 1 , wherein seed polymer 1 and seed polymer 2 comprise C 1 -C 10 alkyl acrylates and/or C 1 -C 10 alkyl methacrylates.
9. The process according to claim 1 , wherein seed polymer 1 and seed polymer 2 comprise butyl acrylate and methyl methacrylate.
10. The process according to claim 1 , wherein less than 10% by weight of the polymer particles have a particle diameter of below 70 nm.
11. The process according to claim 1 , wherein the polymer comprises at least 99% by weight of monoethylenically unsaturated monomer units M comprising:
a) 65% to 99.8% by weight of at least one monomer a), wherein said monomer a) is a C 2 -C 12 alkyl acrylate;
b) 0.1% to 30% by weight of at least one monomer b) selected from the group consisting of methyl acrylate, a C 1 -C 12 alkyl methacrylate, and a vinylaromatic monomer;
c) 0.1% to 10% by weight of at least one monomer c), wherein said monomer c) is a monoethylenically unsaturated monomer having at least one hydroxyalkyl group; and
d) 0% to 5% by weight of at least one monomer d), wherein said monomer d) is a monoethylenically unsaturated monomer having at least one acid group.
12. The process according to claim 1 , wherein the polymer dispersion has a Brookfield viscosity, determined in accordance with DIN EN ISO 3219, at 20° C., 100 sec −1 , of not more than 1.5 Pa·s.
13. The process according to claim 12 , wherein the Brookfield viscosity is from 0.05 to 1.5 Pa·s, determined in accordance with DIN EN ISO 3219 at 23° C., 100 sec −1 .
14. The process according to claim 1 , wherein 15% to 50% by weight of the polymer particles have a particle diameter in a range from 70 to 180 nm and 50 to 85% by weight of the polymer particles have a particle diameter in a range from 180 to 340 nm.
15. The process according to claim 1 , wherein 15% to 50% by weight of the polymer particles have a particle diameter in a range from 80 to 150 nm and 50 to 85% by weight of the polymer particles have a particle diameter in a range from 200 to 330 nm.
16. The process according to claim 1 , wherein the polydispersity index Q is from 0.6 to 1.2.