Partial oxidation of methane (POM) assisted solid oxide co-electrolysis
Methods for simultaneous syngas generation by opposite sides of a solid oxide co-electrolysis cell are provided. The method can comprise exposing a cathode side of the solid oxide co-electrolysis cell to a cathode-side feed stream; supplying electricity to the solid oxide co-electrolysis cell such that the cathode side produces a product stream comprising hydrogen gas and carbon monoxide gas while supplying oxygen ions to an anode side of the solid oxide co-electrolysis cell; and exposing the anode side of the solid oxide co-electrolysis cell to an anode-side feed stream. The cathode-side feed stream comprises water and carbon dioxide, and the anode-side feed stream comprises methane gas such that the methane gas reacts with the oxygen ions to produce hydrogen and carbon monoxide. The cathode-side feed stream can further comprise nitrogen, hydrogen, or a mixture thereof.
1. A method for simultaneous syngas generation by opposite sides of a solid oxide co-electrolysis cell, comprising:
exposing a cathode side of the solid oxide co-electrolysis cell to a cathode-side feed stream, wherein the cathode-side feed stream comprises water and carbon dioxide;
supplying electricity to the solid oxide co-electrolysis cell such that the cathode side produces a product stream comprising hydrogen gas and carbon monoxide gas while supplying oxygen ions to an anode side of the solid oxide co-electrolysis cell; and
exposing the anode side of the solid oxide co-electrolysis cell to an anode-side feed stream, wherein the anode-side feed stream comprises methane gas such that the methane gas reacts with the oxygen ions to produce hydrogen and carbon monoxide.
2. The method of claim 1 , wherein the cathode-side feed stream further comprises nitrogen.
3. The method of claim 1 , wherein the cathode-side feed stream further comprises hydrogen.
4. The method of claim 1 , wherein the cathode-side feed stream further comprises hydrogen and nitrogen.
5. The method of claim 1 , further comprising:
exposing the cathode-side feed stream to heat such that the cathode-side feed stream has a temperature of about 650° C. and about 1000° C. when exposed to the cathode side of the solid oxide co-electrolysis cell.
6. The method of claim 1 , wherein the cathode-side feed stream has a flow ratio of carbon dioxide to water such that the product stream produced by has a ratio of hydrogen to carbon monoxide from about 1:1 to about 4:1.
7. The method of claim 1 , wherein the cathode-side feed stream has a flow ratio of carbon dioxide to water such that the product stream produced by has a ratio of hydrogen to carbon monoxide that is about 2 to 1.
8. The method of claim 1 , wherein the methane gas and the electrolysis current in the anode produce a ratio of hydrogen and carbon monoxide of about 1:1 to about 4:1.
9. The method of claim 1 , wherein the methane gas and the electrolysis current in the anode produce a ratio of hydrogen and carbon monoxide of about 2 to 1.
10. The method of claim 1 , further comprising:
operating the cathode as an anode.
11. The method of claim 1 , further comprising:
operating the anode as a cathode.