Method for preparing carbon nano material/polymer composites
Disclosed is a method for preparing a carbon nanomaterial/polymer composite. More particularly, it relates to an improved method for preparing a carbon nanomaterial/polymer composite capable of solving a dust problem of a carbon nanomaterial powder and a layer separation problem due to large density difference between the carbon nanomaterial powder and a polymer pellet and providing superior physical properties of the composite, whereby an additive used to prepare the carbon nanomaterial/polymer composite is mixed with the carbon nanomaterial powder and prepared into a pellet, which is then mixed with the polymer pellet.
1. A method for preparing a carbon nanomaterial/polymer composite, the method comprising:
preparing a mixture powder by mixing a powder that consists of a dispersion aid with a carbon nanomaterial powder;
forming the mixture powder into a pellet using a rotary tablet press; and
preparing the composite by mixing the pellet with a polymer pellet,
wherein 1-100 parts by weight of the dispersion aid is mixed with 100 parts by weight of the carbon nanomaterial powder,
wherein the dispersion aid is at least one selected from the group consisting of low-molecular-weight polyolefin, metal soap, paraffin wax, fatty acid amide, fatty acid ester, polysiloxane resin and polytetrafluoroethylene wax, and
wherein the carbon nanomaterial powder has an apparent density of 0.01-0.20 g/mL and an angle of repose of 10°-70°.
2. The method for preparing the composite according to claim 1 , wherein the carbon nanomaterial is one or more selected from carbon nanotube, carbon nanofiber, graphene and graphite nanoplate.
3. The method for preparing the composite according to claim 1 , wherein the dispersion aid is selected from low-molecular-weight polyolefin, metal soap, paraffin wax, fatty acid amide, fatty acid ester, polysiloxane resin and polytetrafluoroethylene wax.
4. The method for preparing the composite according to claim 1 , wherein the polymer material is one or more selected from polycarbonate, polyethylene terephthalate, amorphous polyethylene terephthalate, glycol-modified polyethylene terephthalate, cyclohexane-modified polyethylene terephthalate, polybutylene terephthalate, polyphenylene oxide, modified polyphenylene oxide, polyphenylene ether, polyether ketone, polyether ketone ketone, polyethylene, polypropylene, polyacryl, polymethyl methacrylate, polysulfone, polyphenylene sulfide, polyethersulfone, sulfonated polybutylene terephthalate, polyetherimide, polyamide, polyamideimide, polyetheramide, polyacetal, acrylonitrile-butadiene-styrene, polystyrene, polyvinyl chloride, polyvinyl fluoride, polychlorotrifluoroethylene, polyurethane, ethylene propylene rubber, ethylene propylene diene monomer, polylactic acid, liquid crystal polymer, polycarbonate/acrylonitrile-butadiene-styrene, polycarbonate/cyclohexane-modified polyethylene terephthalate, acrylonitrile-butadiene-styrene/polyamide, polybutylene terephthalate/polyethylene terephthalate, polybutylene terephthalate/liquid crystal polymer, polysulfone/modified polyphenylene oxide, polypropylene/polyamide and polycarbonate/polylactic acid.
5. A carbon nanomaterial/polymer composite prepared by the method according to claim 1 , wherein the pellet prepared from the mixture of the carbon nanomaterial and the dispersion aid has a diameter of 2-6 millimeters (mm), a thickness of 1-6 mm and an apparent density of 0.05-0.60 g/mL.
6. A method for preparing a carbon nanomaterial/polymer composite, comprising:
preparing a mixture powder by mixing a powder that consists of a dispersion aid with a carbon nanomaterial powder;
forming the mixture powder into a pellet using a rotary tablet press; and
preparing the composite by mixing the pellet with a polymer pellet,
wherein 10-60 parts by weight of the dispersion aid is mixed with 100 parts by weight of the carbon nanomaterial powder,
wherein the dispersion aid is at least one selected from the group consisting of low-molecular-weight polyolefin, metal soap, paraffin wax, fatty acid amide, fatty acid ester, polysiloxane resin and polytetrafluoroethylene wax, and
wherein the carbon nanomaterial powder has an apparent density of 0.01-0.20 g/mL and an angle of repose of 10°-70°.
7. The method for preparing the composite according to claim 6 , wherein the mixture powder is formed into the pellet using a rotary tablet press with a pressure of 100-700 kg/cm 2 .