Electrode mix, electrode mix paste, electrode, and non-aqueous electrolyte secondary battery
An electrode mixture containing a particulate electrode active material, an electrically conductive material and a binder, wherein the electrode active material comprises a particulate core material and a coating material adhering in the form of particles or a layer to the surface of the core material, the core material is obtained by a method comprising a step of coprecipitating two or more transition metal elements, and the binder comprises a water-soluble macromolecule or a water-dispersible macromolecule or both. An electrode comprising the electrode mixture and an electrode collector. An electrode mixture paste containing the electrode mixture and water. A nonaqueous electrolyte secondary battery comprising a positive electrode, a negative electrode and an electrolyte, wherein the positive electrode is the electrode.
1. An electrode mixture containing a particulate electrode active material, an electrically conductive material and a binder, wherein the electrode active material includes a particulate core material and a coating material adhering in the form of particles or a layer to the surface of the core material, the core material is obtained by a method comprising a step of coprecipitating two or more transition metal elements, and the binder consists essentially of a water-soluble macromolecule and a water-dispersible macromolecule where the water-soluble macromolecule and water-dispersible macromolecule are provided in a weight ratio of 9:1 to 1:9,
wherein the water-dispersible macromolecule is at least one selected from the group consisting of an ethylene-vinyl acetate copolymer and ethylene-vinyl acetate-alkyl acrylate copolymer, and the water-soluble macromolecule includes one or more macromolecules selected from the group consisting of carboxymethyl cellulose, polyvinyl alcohol and polyvinyl pyrrolidone.
2. The electrode mixture according to claim 1 , wherein the core material is a lithium nickel composite metal oxide.
3. The electrode mixture according to claim 1 , wherein the core material is represented by the following formula (A):
Li x (Ni 1-y M y )O 2 (A)
wherein M is one or more elements selected from the group consisting of Co, Mn and Fe; x is 0.9 or more and 1.3 or less; and y is 0 or more and 0.7 or less.
4. The electrode mixture according to claim 1 , wherein the coating material is an oxide containing Al.
5. The electrode mixture according to claim 1 , wherein the electrically conductive material is a carbonaceous material.
6. An electrode comprising the electrode mixture according to claim 1 and an electrode collector.
7. A nonaqueous electrolyte secondary battery comprising a positive electrode, a negative electrode and an electrolyte, wherein the positive electrode is the electrode according to claim 6 .
8. The nonaqueous electrolyte secondary battery according to claim 7 , further comprising a separator.
9. The nonaqueous electrolyte secondary battery according to claim 8 , wherein the separator is composed of a laminated film comprising a porous film and a heat resistant porous layer laminated thereon.
10. An electrode mixture paste containing the electrode mixture according to claim 1 and water.