Polyamide composite resin composition for fuel filler pipe
View Patent ↗A polyamide composite resin composition for a fuel filler pipe, the polyamide composite resin includes 41 to 77% by weight of polyamide 6, 5 to 15% by weight of m-xylenediamine (MXD)-based modified nylon, 14 to 30% by weight of a maleic anhydride-grafted ethylene-octene copolymer, a maleic anhydride-grafted ethylene-propylene-diene monomer or a thermoplastic elastic body rubber as a mixture thereof, and 3 to 10% by weight of mixed clay.
1. A polyamide composite resin composition for a fuel filler pipe, the polyamide composite resin comprising:
41 to 77% by weight of polyamide 6;
5 to 15% by weight of m-xylenediamine (MXD)-based modified nylon;
14 to 30% by weight of a maleic anhydride-grafted ethylene-octene copolymer, a maleic anhydride-grafted ethylene-propylene-diene monomer or a thermoplastic elastic body rubber as a mixture thereof; and
3 to 10% by weight of mixed clay.
2. The polyamide composite resin composition according to claim 1 , wherein the m-xylenediamine (MXD)-based modified nylon is one or more selected from the group consisting of m-xylenediamine 6 nylon, aromatic nylon and amorphous nylon.
3. The polyamide composite resin composition according to claim 1 , wherein the mixed clay is immobilization-pretreated through mixing two or more selected from the group consisting of tabular montmorillonite, hectorite, saponite and vermiculite.
4. The polyamide composite resin composition according to claim 3 , wherein, in the immobilization pretreatment, pre-treatment into an organic material comprising one or more functional groups selected from the group consisting of tertiary and quaternary ammonium, phosphonium, maleate, succinate, acrylate, benzylic hydrogen, dimethyl distearyl ammonium and oxazoline is performed.
5. The polyamide composite resin composition according to claim 1 , further comprising 0.3 to 1.0% by weight of a heat stabilizer, 0.3 to 1.0% by weight of a lubricant, 0.3 to 1.0% by weight of a thickener and 0.1 to 1.0% by weight of a filler.