IP Library Granted Patent US 9,592,492
Granted Patent B2
US 9,592,492 · App. 14/745,272 · Granted Mar 14, 2017

Method and system for forming plug and play oxide catalysts

Inventors: Maximilian A. Biberger (Scottsdale, AZ); Stephen Edward Lehman, Jr. (Spartanburg, SC); Robert Matthew Kevwitch (Tempe, AZ); Qinghua Yin (Tempe, AZ)
Assignee: SDCmaterials, Inc.
B01J23/464B01J8/00B01J21/04B01J21/063B01J21/066B01J21/08B01J23/00B01J23/02B01J23/10B01J23/40B01J23/42B01J23/44B01J23/58B01J23/63B01J23/83B01J27/02B01J27/14B01J27/20B01J27/24B01J31/02B01J35/006B01J35/0006B01J35/0013B01J35/0066B01J35/023B01J37/0211B01J37/04B01J37/08B01J37/349C07C5/10B01J37/0203B01J37/0219B82Y40/00C07C2101/14C07C2521/04C07C2523/42Y02P20/52Y10S977/892Y10T428/2982Y10T428/2991
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Quick Facts
Patent No.
US 9,592,492
App. No.
14/745,272
Granted
Mar 14, 2017
Kind
B2
Abstract

An oxide catalyst is formed by vaporizing a quantity of at least one precursor material or catalyst material thereby forming a vapor cloud. The vapor cloud is quenched forming precipitate nanoparticles. The nanoparticles are impregnated onto supports. The supports are able to be used in existing heterogeneous catalysis systems. A system for forming oxide catalysts comprises means for vaporizing a quantity of at least one precursor material or at least one catalyst material, quenching the resulting vapor cloud and forming precipitate nanoparticles. The system further comprises means for supports with the nanoparticles.

Claims (17)

1. A supported catalyst, comprising:

a. support structures, wherein the support structure comprises a porous oxide; and

b. nanoparticles bonded to the support structures, wherein the nanoparticles comprise an oxide catalyst;

wherein the nanoparticles are attached to the support structures by an oxide-oxide bond.

2. The supported catalyst of claim 1 , wherein the oxide catalyst comprises a metal oxide.

3. The supported catalyst of claim 2 , wherein the oxide catalyst comprises lanthanum iron oxide.

4. The supported catalyst of claim 1 , wherein the nanoparticles are prepared using plasma.

5. The supported catalyst of claim 1 , wherein the support structures are macroscopic particles.

6. The supported catalyst of claim 1 , wherein the nanoparticles are about 0.5 nanometers to about 200 nanometers in diameter.

7. The supported catalyst of claim 1 , wherein the nanoparticles are on the surface and in the pores of the support structures.

8. The supported catalyst of claim 7 , wherein the nanoparticles are deposited on the surface and in the pores of the support structures by suspending the nanoparticles in a solution to form a suspension, and mixing the suspension with the support structures.

9. The supported catalyst of claim 8 , wherein the solution further comprises a dispersant.

10. The supported catalyst of claim 8 , wherein the suspension of nanoparticles mixed with the support structures is dried, then exposed to heat, pressure, or a combination of heat and pressure to calcine the nanoparticles onto the support structures.

11. The supported catalyst of claim 7 , wherein the nanoparticles are deposited on the surface and in the pores of the support structures by suspending the nanoparticles in a solution to form a suspension, and mixing the suspension with a slurry having the support structures suspended therein.

12. The supported catalyst of claim 11 , wherein the solution further comprises a dispersant.

13. The supported catalyst of claim 1 , wherein the nanoparticles comprise a metal oxide formed from a precursor material, wherein the precursor material is selected from the group consisting of a metal, a metal oxide, a metal salt, a carbon compound, a chlorine compound, a phosphorous compound, and any combination thereof.

14. The supported catalyst of claim 1 , wherein the oxide-oxide bond is formed by calcination.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 16, 2018
From: SM (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
To: UMICORE AG & CO. KG
Reel/Frame 045350/0280 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 11, 2016
From: BIBERGER, MAXIMILIAN A.; LEHMAN, STEPHEN EDWARD, JR.; KEVWITCH, ROBERT MATTHEW; YIN, QINGHUA
To: SDCMATERIALS, INC.
Reel/Frame 037452/0570 →
Continuity (4)
Continuation 13921066 · Jun 18, 2013
Continuation 12001644 · Dec 11, 2007
Provisional Application 60999057 · Oct 15, 2007
Related Publication 20160144346A1 · May 26, 2016