Composite porous separation membrane having shut-down function, method of manufacturing same, and secondary batteries using same
A composite porous separator includes: a porous substrate acting as a support and having a first melting point and a first porosity; a first porous polymer web layer that is laminated on one side of the porous substrate, and acts as an adhesive layer when being in close contact with an opposing electrode; and a second porous polymer web layer that is laminated on the other surface of the porous substrate, and is formed of nanofibers of a heat-resistant polymer, in which the first porous polymer web layer and the second porous polymer web layer have a melting point higher than the first melting point of the porous substrate and a porosity that is the same as or similar to the first porosity of the porous substrate, respectively.
1. A composite porous separator having a shutdown function, the composite porous separator comprising:
(1) a porous substrate acting as a support and having a first melting point and a first porosity;
(2) a first porous polymer web layer that is formed on one side of the porous substrate, and acts as an adhesive layer when in close contact with an opposing electrode; and
(3) a second porous polymer web layer that is formed on the other surface of the porous substrate, and is formed of nanofibers of a heat-resistant polymer,
wherein the first porous polymer web layer and the second porous polymer web layer have a melting point higher than the first melting point of the porous substrate and a porosity that is the same as or similar to the first porosity of the porous substrate, respectively,
wherein the porous substrate has a thickness set in the range of 5-9 μm, the first porous polymer web layer has a thickness set in the range of 2-3 μm, and the second porous polymer web layer has a thickness set in the range of 4-14 μm.
2. The composite porous separator having a shutdown function according to claim 1 , wherein the porosity of the porous substrate is set to 60 to 80%, the porosities of the first porous polymer web layer and the second porous polymer web layer are respectively set to 50˜80%.
3. The composite porous separator having a shutdown function according to claim 1 , wherein the porous substrate is a polyethylene (PE) porous membrane.
4. The composite porous separator having a shutdown function according to claim 3 , wherein the porous substrate is set to have a mechanical tensile strength of 700 kg/cm 2 or less, and a transverse tensile strength of 150 kg/cm 2 or less.
5. The composite porous separator having a shutdown function according to claim 1 , wherein the first porous polymer web layer is made of a polymer that is swellable in an electrolytic solution and enables electrolytic ions to conduct.
6. The composite porous separator having a shutdown function according to claim 1 , wherein the nanofibers of the second porous polymer web layer further comprise a swellable polymer and inorganic particles.
7. The composite porous separator having a shutdown function according to claim 6 , wherein contents of the inorganic particles are in the range from 10˜25% by weight on the whole content of the nanofibers, and size of the inorganic particles is in the range of 10˜100 nm.
8. The composite porous separator having a shutdown function according to claim 6 , wherein the heat-resistant polymer and the swellable polymer are mixed at a weight ratio ranging from 5:5 to 7:3.
9. A secondary battery comprising:
a cathode;
an anode;
a separator separating the cathode and the anode; and
an electrolyte solution,
wherein the separator is made of a composite porous separator having a shutdown function according to claim 1 .