Carbon structure electrode for redox flow battery, method of preparing carbon structure electrode for redox flow battery, and carbon structure electrode structure for redox flow battery
Disclosed is a carbon structure electrode for redox flow batteries, which includes a plurality of spherical macropores formed on a surface of a polymer-derived carbon structure and inside the polymer-derived carbon structure so as to allow electrolyte migration. The carbon structure electrode for redox flow batteries has excellent electrical conductivity and enables cost reduction through a simplified preparation process.
1. A carbon structure electrode for redox flow batteries, comprising a plurality of spherical, patterned, uniformly dispersed, macropores formed on a surface of a polymer-derived carbon structure and inside the polymer-derived carbon structure so as to allow electrolyte migration,
wherein the macropores are arranged in an opal structure.
2. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the macropores have an average maximum diameter from 0.5 μm to 500 μm.
3. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the macropores are connected to one another to communicate from one side to the other side of the electrode.
4. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the carbon structure comprises a carbide of a polymer resin.
5. The carbon structure electrode for redox flow batteries according to claim 4 , wherein the polymer resin comprises one selected from the group consisting of a polyacrylonitrile, a polymer for photoresist, a rayon-based polymer, and combinations thereof.
6. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the carbon structure comprises a graphitized material of a polymer resin.
7. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the carbon structure has a macropore-related porosity of 70% to 99%.
8. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the carbon structure has a thickness of 0.5 mm to 5.0 mm.
9. The carbon structure electrode for redox flow batteries according to claim 1 , wherein the carbon structure has a resistance of 0.002 Ω·mm to 0.02 Ω·mm.
10. A carbon structure electrode structure for redox flow batteries, comprising:
a bipolar plate; and
the carbon structure electrode for redox flow batteries according to claim 1 coupled to the bipolar plate.
11. A method of preparing a carbon structure electrode for redox flow batteries, comprising:
preparing a polymer sheet;
forming patterned, uniformly dispersed macropores in the polymer sheet; and
carbonizing the polymer sheet having the patterned macropores by heat treatment to form a carbon structure.
12. The method according to claim 11 , wherein the step of forming the patterned macropores is performed by at least one selected from a laser patterning method, a holographic lithography method using a laser, and a laser lithography method.
13. The method according to claim 11 , wherein at least part of the polymer sheet is graphitized upon carbonization through heat treatment of the polymer sheet.
14. The method according to claim 11 , wherein the polymer sheet comprises one selected from a polyacrylonitrile, a polymer for photoresist, a rayon based polymer, and for photoresistcombinations thereof.
15. The method according to claim 11 , wherein the heat treatment is performed at 1000° C. to 2500° C.