Metal tin-carbon composites, method for producing said composites, anode active material for non-aqueous lithium secondary batteries which is produced using said composites, anode for non-aqueous lithium secondary batteries which comprises said anode active material, and non-aqueous lithium secondary battery
A metal tin-carbon composite having excellent properties required for various use applications, a method for producing the composite at low cost and in a simple manner, and use applications of a non-aqueous lithium secondary battery produced using the composite are provided. A metal tin-carbon composite comprising metal tin nanoparticles (B) contained in a sheet-like matrix (A) composed of carbon, wherein the metal tin-carbon composite contains the metal tin nanoparticle (B) having a particle size of a range of 0.2 nm to 5 nm and does not contain a coarse metal tin particle having a particle size of 1 μm or more, a preferable method for producing the composite using a specific precursor, an anode active material for a non-aqueous lithium secondary battery comprising the composite, a negative electrode for non-aqueous lithium secondary battery using the anode active material, and a non-aqueous lithium secondary battery.
1. A method for producing a metal tin-carbon composite containing a metal tin nanoparticle (B) in a matrix (A) composed of a carbon characterized in that the metal tin-carbon composite contains the metal tin nanoparticle (B) having a particle size of a range of 0.2 nm to 5 nm and does not contain a coarse metal tin particle having a particle size of 1 μtm or more, wherein a precursor comprising a cationic polymer (X), a tin compound (Y) and sulfuric acid (Z) is calcinated.
2. The method for producing the metal tin-carbon composite according to claim 1 , wherein the precursor further comprises a water soluble polymer (U) which is calcinated with the cationic polymer (X), the tin compound (Y) and the sulfuric acid (Z).
3. The method for producing the metal tin-carbon composite according to claim 1 , wherein the metal tin-carbon composite further contains the metal tin nanoparticle (B) having a particle size of a range of more than 5 nm to 100 nm at the same time.
4. A method for producing the metal tin-carbon composite according to claim 2 , wherein the metal tin-carbon composite further contains the metal tin nanoparticle (B) having a particle size of a range of more than 5 nm to 100 nm at the same time.