Method for recovering scandium from intermediate products formed in the hydrometallurgical processing of laterite ores
The invention provides a method for recovering scandium from scandium-containing intermediate products, formed during hydrometallurgical processing of scandium-containing feed materials, including: (a) leaching of the scandium-containing intermediate products with a suitable acid at a controlled pH selected to maximize scandium extraction and minimize the co-extraction of impurities, (b) solid/liquid separation, to obtain a scandium-containing leach solution; (c) selective precipitation of the scandium at a controlled pH from the scandium-containing leach solution using a suitable base, (d) solid/liquid separation, to obtain an upgraded scandium concentrate and a barren solution for return to the hydrometallurgical process. A further upgraded scandium concentrate can be obtained by (e) alkaline leaching of the upgraded scandium concentrate for additional removal of impurities, and (f) solid/liquid separation to obtain a further upgraded scandium concentrate and impurities-containing base solution.
1. A method for recovering scandium from a precipitate formed in a hydrometallurgical process, comprising:
(a) obtaining a scandium-containing precipitate formed in a hydrometallurgical process for recovering nickel and cobalt from laterite ores;
(b) leaching the scandium-containing precipitate formed in said hydrometallurgical process with an acid at a controlled pH;
(c) performing a solid-liquid separation to obtain a scandium-containing leach solution;
(d) selective precipitation of scandium at a controlled pH from the scandium-containing leach solution using a base; and
(e) performing a solid-liquid separation to obtain an purified scandium concentrate and a barren solution for return to the hydrometallurgical process.
2. The method according to claim 1 , wherein the scandium-containing precipitate is collected from a thickener underflow slurry that has been filtered and washed.
3. The method according to claim 1 , wherein the acid in step (b) comprises a mineral acid.
4. The method according to claim 3 , wherein the acid is selected from the group consisting of hydrochloric acid and sulfuric acid.
5. The method according to claim 4 , wherein the acid is sulfuric acid.
6. The method according to claim 1 , wherein the controlled pH in step (b) ensures scandium dissolution while limiting dissolution of other metals in the intermediate products.
7. The method according to claim 6 , wherein the controlled pH is about 2.0 to about 4.0.
8. The method according to claim 7 , wherein the controlled pH is about 2.5 to about 3.5.
9. The method according to claim 8 , wherein the controlled pH is about 2.9 to about 3.2.
10. The method according to claim 1 , wherein the base in step (d) is selected from the group consisting of sodium carbonate (soda ash), sodium hydroxide, magnesium oxide, and magnesium hydroxide.
11. The method according to claim 1 , wherein the selective precipitation of step (d) is carried out at a controlled pH about 4.5 to about 6.0.
12. The method according to claim 11 , wherein the controlled pH is about 5.0 to about 5.5.
13. A method for recovering scandium from a precipitate formed in a hydrometallurgical process, comprising:
(a) obtaining a scandium-containing precipitate formed in a hydrometallurgical process for recovering nickel and cobalt from laterite ores;
(b) leaching the scandium-containing precipitate formed in said hydrometallurgical process with an acid at a controlled pH;
(c) performing a solid-liquid separation to obtain a scandium-containing leach solution;
(d) selective precipitation of scandium at a controlled pH from the scandium-containing leach solution using a base;
(e) performing a solid-liquid separation to obtain a first purified scandium concentrate and a barren solution for return to the hydrometallurgical process;
(f) leaching of the first purified scandium concentrate with a base to remove impurities; and
(g) performing a solid-liquid separation to obtain a second purified scandium concentrate and an impurities-containing base solution.
14. The method according to claim 13 , wherein the scandium-containing precipitate is collected from a thickener underflow slurry that has been filtered and washed.
15. The method according to claim 13 , wherein the acid in step (b) comprises a mineral acid.
16. The method of claim 15 , wherein the acid is selected from the group consisting of hydrochloric acid and sulfuric acid.
17. The method of claim 16 , wherein the acid is sulfuric acid.
18. The method according to claim 13 , wherein the controlled pH in step (b) ensures scandium dissolution while limiting dissolution of other metals in the intermediate products.
19. The method of claim 18 , wherein the controlled pH is about 2.0 to about 4.0.
20. The method of claim 19 , wherein the controlled pH is about 2.5 to about 3.5.
21. The method of claim 20 , wherein the controlled pH is about 2.9 to about 3.2.
22. The method according to claim 13 , wherein the base in step (d) is selected from the group consisting of sodium carbonate (soda ash), sodium hydroxide, magnesium oxide, and magnesium hydroxide.
23. The method according to claim 13 , wherein the selective precipitation of step (d) is carried out at a controlled pH of about 4.5 to about 6.0.
24. The method of claim 23 , wherein the controlled pH is about 5.0 to about 5.5.
25. The method according to claim 13 , wherein the suitable base in step (f) comprises an aqueous solution of alkali metal hydroxide.
26. The method of claim 25 , wherein a concentration of the alkali metal hydroxide in the aqueous solution is from about 1 N and to about 8 N.
27. The method of claim 26 , wherein the concentration of the alkali metal hydroxide in the aqueous solution is from about 2.5 N to about 6 N.
28. The method of claim 25 , wherein the alkali metal hydroxide is sodium hydroxide.