Ammonia gas generator and use of the same for reducing nitrogen oxides in exhaust gases
Ammonia gas generator for producing ammonia from a solution of an ammonia precursor substance comprising a catalyst unit, which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber arranged upstream of the catalyst, an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber, and an outlet for the ammonia gas formed, wherein the injection device comprises a nozzle which produces droplets having a Sauter mean diameter D 32 of 26 to 100 μm.
1. An ammonia gas generator for producing ammonia gas from a solution of an ammonia precursor substance comprising:
i) a catalyst unit, which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber arranged upstream of the catalyst, wherein the catalyst has a catalyst volume V Cat and the mixing chamber has a mixing chamber volume V Mix ;
ii) an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;
iii) an inlet for a carrier gas for forming a plurality of parallel jets of carrier gas; and
iv) an outlet for the ammonia gas formed,
wherein the injection device comprises a nozzle which produces droplets with a Sauter mean diameter D 32 of 26 to 100 μm, wherein the ratio of the volume of the mixing chamber V Mix to the volume of the catalyst V Cat corresponds to the ratio of from 1:1 to 5:1, and wherein the opening of the nozzle is arranged such that the solution of ammonia precursor substance is introduced as an aerosol into the plurality of parallel jets of carrier gas.
2. The ammonia gas generator of claim 1 , wherein the injection device comprises a nozzle which produces droplets with a Sauter mean diameter D 32 of 26 to 40 μm.
3. The ammonia gas generator of claim 1 , wherein the injection device is a dual substance nozzle in which the solution of the ammonia precursor substance to be introduced into the mixing chamber is charged with the carrier gas.
4. The ammonia gas generator of claim 1 , wherein the nozzle has a first number of openings for inserting the solution into the mixing chamber, which is surrounded annularly by a second number of nozzle openings for introducing compressed air into the mixing chamber.
5. The ammonia gas generator of claim 1 , wherein the nozzle is a single substance nozzle or an injector.
6. The ammonia gas generator of claim 1 , wherein the ammonia gas generator comprises a perforated disc and the opening of the nozzle is arranged centrally in the perforated disc.
7. The ammonia gas generator of claim 1 , wherein the ammonia gas generator comprises a perforated disc having a plurality of openings therethrough.
8. The ammonia gas generator of claim 1 , wherein the catalyst is a hydrolysis catalyst.
9. The ammonia gas generator of claim 1 , wherein the ammonia gas generator comprises a metering unit for metering the solution of ammonia precursor substance, the metering unit being arranged upstream of the injection device.
10. A method for producing ammonia from a solution of an ammonia precursor substance using an ammonia gas generator comprising:
i) a catalyst unit, which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber arranged upstream of the catalyst, wherein the catalyst has a catalyst volume V Cat and the mixing chamber has a mixing chamber volume V Mix ;
ii) an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber; and,
iii) an outlet for the ammonia gas formed;
the method comprising:
introducing the solution of ammonia precursor substance into the mixing chamber by injecting droplets with a Sauter mean diameter D 32 of 26 to 100 wherein the ratio of the volume of the mixing chamber V Mix to the volume of the catalyst V Cat corresponds to the ratio of from 1:1 to 5:1; and wherein the solution of the ammonia precursor substance is introduced as an aerosol into a plurality of parallel jets of carrier gas.
11. The method of claim 10 , further comprising introducing into the mixing chamber a carrier gas or a carrier gas flow, at a temperature T (K) in the range of 10 to 200° C.
12. The method of claim 10 , further comprising introducing into the mixing chamber a carrier gas or a carrier gas flow, at a temperature T (K) in the range of 250 to 550° C.
13. An exhaust gas post-processing system for exhaust gas pipes of vehicles, the system comprising the ammonia gas generator of claim 1 .
14. The system of claim 13 , further comprising a Venturi mixer, wherein the outlet for the ammonia gas formed and the Venturi mixer are connected by a pipe.
15. The system of claim 14 , wherein the Venturi mixer is a component of the exhaust gas pipe of a motor vehicle.
16. A method for of reducing nitrogen oxides in exhaust gases, the method comprising treating an exhaust gas from an internal combustion engine, a gas engine, a diesel engine, or a petrol engine with the ammonia gas formed by the ammonia gas generator of claim 1 .
17. The ammonia gas generator of claim 3 , wherein the carrier gas is compressed air.
18. The ammonia gas generator of claim 1 , wherein the inlet for the carrier gas produces a carrier gas flow aligned perpendicularly to a catalyst end face of the catalyst.
19. The ammonia gas generator of claim 7 , wherein the plurality of openings of the perforated disc split the carrier gas into a plurality of gas streams parallel to a flow direction of the catalyst unit.
20. The method of claim 10 , wherein the solution of ammonia precursor substance is injected into the mixing chamber in the form of droplets with a Sauter mean diameter D 32 of 26 to 40 μm.
21. The method of claim 11 , wherein the carrier gas flow is guided perpendicularly to a catalyst end face of the catalyst.
22. The method of claim 11 , wherein the carrier gas or carrier gas flow is injected into the mixing chamber at a temperature T (K) in the range of 10 to 200° C.
23. The method of claim 12 , wherein the carrier gas flow is guided perpendicularly to a catalyst end face of the catalyst.
24. The method of claim 12 , wherein the carrier gas or carrier gas flow is injected into the mixing chamber at a temperature T (K) in the range of 10 to 200° C.
25. The method of claim 14 , wherein the outlet for the ammonia gas formed and the Venturi mixer are connected through a direct connection.
26. An ammonia gas generator for producing ammonia gas from a solution of an ammonia precursor substance comprising:
i) a catalyst unit, which comprises a catalyst for the decomposition and/or hydrolysis of ammonia precursor substances into ammonia and a mixing chamber arranged upstream of the catalyst, wherein the catalyst has a catalyst volume V Cat and the mixing chamber has a mixing chamber volume V Mix ;
ii) an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber;
iii) an inlet for a carrier gas;
iv) a perforated disc which has a plurality of openings by means of which the carrier gas is separated into a plurality of parallel jets; and
v) an outlet for the ammonia gas formed,
wherein the injection device comprises a nozzle which produces droplets with a Sauter mean diameter D 32 of 26 to 100 μm, wherein the ratio of the volume of the mixing chamber V Mix to the volume of the catalyst V Cat corresponds to the ratio of from 1:1 to 5:1, and wherein the opening of the nozzle is arranged centrally with respect to the perforated disc such that the solution of the ammonia precursor substance is introduced as an aerosol into the plurality of parallel jets of the carrier gas.