IP Library Granted Patent US 9,728,811
Granted Patent B2
US 9,728,811 · App. 15/082,128 · Granted Aug 8, 2017

Nonaqueous electrolyte for lithium secondary battery and lithium secondary battery employing the same

Inventors: Jinah Seo (Suwon-si, KR); Dongyoung Kim (Yongin-si, KR); Hosang Park (Seoul, KR); Yoonsok Kang (Seongnam-si, KR); Insun Park (Suwon-si, KR)
Assignees: SAMSUNG ELECTRONICS CO., LTD.; SAMSUNG SDI CO., LTD.
H01M10/0567H01M10/0525H01M10/0568H01M10/0569H01M2220/30H01M2300/0025
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Quick Facts
Patent No.
US 9,728,811
App. No.
15/082,128
Granted
Aug 8, 2017
Kind
B2
Abstract

A nonaqueous electrolyte for a lithium secondary battery, the nonaqueous electrolyte including: a fluorine-containing lithium salt, an organic solvent, and an organosilicon compound represented by Formula 1: wherein, in Formula 1, R 1 to R 6 are each independently a C 1 -C 10 alkyl group or a C 1 -C 10 alkoxy group. Also a lithium secondary battery including the nonaqueous electrolyte.

Claims (11)

1. A nonaqueous electrolyte for a lithium secondary battery, the nonaqueous electrolyte comprising:

a fluorine-containing lithium salt;

an organic solvent; and

an organosilicon compound represented by Formula 1:

wherein, in Formula 1, R 1 to R 6 are each independently a C 1 -C 10 alkyl group or a C 1 -C 10 alkoxy group.

2. The nonaqueous electrolyte of claim 1 , wherein an amount of the organosilicon compound is in a range of about 0.05 percent by weight to about 10 percent by weight, based on a total weight of the nonaqueous.

3. The nonaqueous electrolyte of claim 1 , wherein an anion of the fluorine-containing lithium salt comprises F − , BF 4 − , PF 6 − , (CF 3 ) 2 PF 4 − , (CF 3 ) 3 PF 3 − , (CF 3 ) 4 PF 2 − , (CF 3 ) 5 PF − , (CF 3 ) 6 P − , CF 3 SO 3 − , CF 3 CF 2 SO 3 − , (CF 3 SO 2 ) 2 N − , (FSO 2 ) 2 N − , CF 3 CF 2 (CF 3 ) 2 CO − , (CF 3 SO 2 ) 2 CH − , (SF 5 ) 3 C − , (CF 3 SO 2 ) 3 C − , CF 3 (CF 2 ) 7 SO 3 − , CF 3 CO 2 − , (CF 3 CF 2 SO 2 ) 2 N − , or a combination thereof.

4. The nonaqueous electrolyte of claim 1 , further comprising an additional lithium salt, wherein an anion of the additional lithium salt comprises Cl − , Br − , I − , NO 3 − , N(CN) 2 − , ClO 4 − , CH 3 CO 2 − , SCN − , or a combination thereof.

5. The nonaqueous electrolyte of claim 1 , wherein the organic solvent comprises an ether, an ester, an amide, a linear carbonate, a cyclic carbonate, or a combination thereof.

6. The nonaqueous electrolyte of claim 1 , further comprising vinylene carbonate, vinyl ethylene carbonate, fluoroethylene carbonate, cyclic sulfite, saturated sultone, unsaturated sultone, an acyclic sulfone, or a combination thereof.

7. A lithium secondary battery comprising the nonaqueous electrolyte according to claim 1 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 18, 2019
From: SAMSUNG ELECTRONICS CO., LTD.; SAMSUNG SDI CO., LTD.
To: SAMSUNG ELECTRONICS CO., LTD.; SAMSUNG SDI CO., LTD.
Reel/Frame 051366/0480 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 28, 2016
From: SEO, JINAH; KIM, DONGYOUNG; PARK, HOSANG; KANG, YOONSOK; PARK, INSUN
To: SAMSUNG ELECTRONICS CO., LTD.; SAMSUNG SDI CO., LTD.
Reel/Frame 038113/0537 →
Priority Claims (1)
KR 10-2015-0148027 · Oct 23, 2015 · national
Continuity (1)
Related Publication 20170117579A1 · Apr 27, 2017