Method for producing thermoplastic molding compounds with a high glass fiber content
The present invention relates to a process for the production of thermoplastic molding compositions, in particular styrene copolymer compositions, to a process for production of these, and also to use thereof. The thermoplastic molding compositions produced by a process of the invention offer improved temperature-resistance and mechanical properties, which have better flow properties than known molding compositions.
1. A thermoplastic molding composition consisting of:
A) from 40 to 50% by weight of a styrene-acrylonitrile copolymer with from 65 to 76% by weight styrene content and with from 35 to 24% by weight acrylonitrile content as component A,
B) from 0 to 15% by weight of a graft polymer as component B comprising:
B1: a graft base composed of an alkyl acrylate, of an allyl (meth)acrylate, of a copolymerizable monomer, and/or of a diene monomer,
B2: at least one graft shell composed of at least one vinylaromatic monomer and/or copolymerizable monomer,
C) from 0.1 to 10% by weight of a compatibilizer as component C, where component C is a styrene-acrylonitrile-maleic anhydride terpolymer, where the proportion of acrylonitrile in the terpolymer, based on the entire terpolymer, is from 20 to 25% by weight,
D) from 40 to 55% by weight of glass fibers as component D,
E) from 0 to 10% by weight of other components,
where the entirety of components A, B, C, D, and E gives 100% by weight.
2. The thermoplastic molding composition as claimed in claim 1 , consisting of:
A) from 40 to 50% by weight of a styrene-acrylonitrile copolymer as component A,
B) from 0 to 15% by weight of a graft polymer as component B comprising:
B1: a graft base composed of an alkyl acrylate, of an allyl (meth)acrylate, of a copolymerizable monomer, and/or of a diene monomer,
B2: at least one graft shell composed of at least one vinylaromatic monomer and/or copolymerizable monomer,
C) from 0.5 to 8% by weight of a compatibilizer as component C,
D) from 40 to 50% by weight of glass fibers as component D,
E) from 0.1 to 4% by weight of stabilizer(s) as component E,
where the entirety of components A, B, C, D, and E gives 100% by weight.
3. The thermoplastic molding composition as claimed in claim 1 , consisting of:
A) from 40 to 50% by weight of a styrene-acrylonitrile copolymer as component A,
B) from 0 to 15% by weight of a graft polymer as component B comprising:
B1: a graft base composed of an alkyl acrylate, and/or butadiene,
B2: at least one graft shell composed of styrene and/or acrylonitrile,
C) from 0.5 to 8% by weight of a compatibilizer as component C,
D) from 40 to 50% by weight of glass fibers as component D,
E) from 0.1 to 4% by weight of stabilizer(s) as component E,
where the entirety of components A, B, C, D, and E gives 100% by weight.
4. The thermoplastic molding composition as claimed in claim 1 , consisting of:
from 40 to 50% by weight of a styrene-acrylonitrile copolymer as component A,
C) from 0.5 to 8% by weight of a compatibilizer as component C,
D) from 40 to 50% by weight of glass fibers as component D,
E) from 0.1 to 4% by weight of stabilizer(s) as component E,
where the entirety of components A, C, D, and E gives 100% by weight.
5. The thermoplastic molding composition as claimed in claim 1 ,
where the length of the glass fibers (component D) is ≦50 mm.
6. The thermoplastic molding composition as claimed in claim 1 ,
where component C is composed of one or more copolymers, and
where component C comprises at least one styrene-acrylonitrile-maleic anhydride copolymer which comprises from 0.5 to 5% by weight of maleic-anhydride-derived units.
7. The thermoplastic molding composition as claimed in claim 1 , comprising, as component E, from 0.05 to 5% by weight of at least two stabilizers.
8. The thermoplastic molding composition as claimed in claim 1 , comprising, as component E, a lubricant and a medicinal white oil.
9. A process for the production of a thermoplastic molding composition, wherein in the thermoplastic molding composition consists of:
A) from 40 to 50% by weight of a styrene-acrylonitrile copolymer with from 65 to 76% by weight styrene content and with from 35 to 24% by weight acrylonitrile content as component A,
B) from 0 to 15% by weight of a graft polymer as component B comprising:
B1: a graft base composed of an alkyl acrylate, of an allyl (meth)acrylate, of a copolymerizable monomer, and/or of a diene monomer,
B2: at least one graft shell composed of at least one vinylaromatic monomer and/or copolymerizable monomer,
C) from 0.1 to 10% by weight of a compatibilizer as component C, where component C is a styrene-acrylonitrile-maleic anhydride terpolymer, where the proportion of acrylonitrile in the terpolymer, based on the entire terpolymer, is from 20 to 25% by weight,
D) from 40 to 55% by weight of glass fibers as component D,
E) from 0 to 10% by weight of other components,
where the entirety of components A, B, C, D, and E gives precisely 100% by weight;
the step of mixing the components in a melt.