IP Library Granted Patent US 9,735,430
Granted Patent B2
US 9,735,430 · App. 14/598,344 · Granted Aug 15, 2017

Electrode, power storage device, and electronic device

Inventors: Kai Kimura (Kanagawa, JP); Kazutaka Kuriki (Kanagawa, JP); Teppei Oguni (Kanagawa, JP); Aya Uchida (Kanagawa, JP)
Assignee: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
H01M4/622H01G11/24H01G11/26H01G11/28H01G11/38H01M4/13H01M4/133H01M4/62H01M10/0525H01M10/0566H01M10/446H01M2004/021H01M2010/4292H01M2220/20H01M2220/30Y02E60/122Y02E60/13Y02T10/7011Y02T10/7022
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Quick Facts
Patent No.
US 9,735,430
App. No.
14/598,344
Granted
Aug 15, 2017
Kind
B2
Abstract

A power storage device with high capacity or high energy density is provided. A highly reliable power storage device is provided. A long-life power storage device is provided. An electrode includes an active material, a first binder, and a second binder. The specific surface area of the active material is S [m 2 /g]. The weight of the active material, the weight of the first binder, and the weight of the second binder are a, b, and c, respectively. The solution of {(b+c)/(a+b+c)}×100÷S is 0.3 or more. The electrode includes a first film in contact with the active material. The first film preferably includes a region in contact with the active material. The first film preferably includes a region with a thickness of 2 nm or more and 20 nm or less. The first film contains a water-soluble polymer.

Claims (114)

1. An electrode comprising:

a current collector;

an active material;

a first film in contact with the active material, the first film containing a first binder and a second binder, and

a second film overlapping the active material with the first film interposed therebetween at a first portion of the second film and in contact with the active material at a second portion of the second film,

wherein a thickness of the second film at the first portion of the second film is thinner than a thickness of the second film at the second portion of the second film,

wherein the first binder is a water-soluble polymer,

wherein the second film contains lithium, fluorine, oxygen, and carbon,

wherein a specific surface area of the active material is S [m 2 /g],

wherein a weight of the active material, a weight of the first binder, and a weight of the second binder are a, b, and c, respectively, and

wherein A defined by Mathematical Formula 1 is 0.3 or more.

A

=

b

+

c

a

+

b

+

c

×

100

÷

S

[

Mathematical

Formula

1

]

2. The electrode according to claim 1 ,

wherein the first film includes a region with a thickness of 2 nm or more and 20 nm or less.

3. The electrode according to claim 1 ,

wherein the active material is in a form of particles, and

wherein the specific surface area S of the active material is greater than or equal to 0.2 m 2 /g and less than or equal to 7.0 m 2 /g.

4. The electrode according to claim 1 , wherein the first binder contains carboxymethyl cellulose, methyl cellulose, ethyl cellulose, hydroxypropyl cellulose, or diacetyl cellulose.

5. The electrode according to claim 1 , wherein the second binder contains a styrene monomer or a butadiene monomer.

6. The electrode according to claim 1 , wherein the active material contains graphite.

7. A power storage device comprising:

the electrode according to claim 1 ; and

a second electrode,

wherein the electrode has a function of operating as one of a positive electrode and a negative electrode, and

wherein the second electrode has a function of operating as the other of the positive electrode and the negative electrode.

8. An electronic device comprising the power storage device according to claim 7 and a display device.

9. An electrode comprising:

a current collector;

an active material;

a first film in contact with the active material, the first film containing a first binder and a second binder, and

a second film overlapping the active material with the first film interposed therebetween at a first portion of the second film and in contact with the active material at a second portion of the second film,

wherein a thickness of the second film at the first portion of the second film is thinner than a thickness of the second film at the second portion of the second film,

wherein the first binder is a water-soluble polymer,

wherein the second film contains lithium, fluorine, oxygen, and carbon,

wherein a specific surface area of the active material is S [m 2 /g],

wherein a weight of the active material, a weight of the first binder, and a weight of the second binder are a, b, and c, respectively, and

wherein B defined by Mathematical Formula 2 is 0.3 or more.

A

=

b

+

c

a

+

b

+

c

×

100

÷

S

[

Mathematical

Formula

1

]

10. The electrode according to claim 9 , further comprising:

wherein the first film includes a region with a thickness of 2 nm or more and 20 nm or less.

11. The electrode according to claim 9 ,

wherein the active material is in a form of particles, and

wherein the specific surface area S of the active material is greater than or equal to 0.2 m 2 /g and less than or equal to 7.0 m 2 /g.

12. The electrode according to claim 9 , wherein the first binder contains carboxymethyl cellulose, methyl cellulose, ethyl cellulose, hydroxypropyl cellulose, or diacetyl cellulose.

13. The electrode according to claim 9 , wherein the second binder contains a styrene monomer or a butadiene monomer.

14. The electrode according to claim 9 , wherein the active material contains graphite.

15. A power storage device comprising:

the electrode according to claim 9 ; and

a second electrode,

wherein the electrode has a function of operating as one of a positive electrode and a negative electrode, and

wherein the second electrode has a function of operating as the other of the positive electrode and the negative electrode.

16. An electronic device comprising the power storage device according to claim 15 and a display device.

17. An electrode comprising:

an active material;

a first film in contact with the active material, the first film containing a first binder and a second binder, and

a second film overlapping the active material with the first film interposed therebetween at a first portion of the second film and in contact with the active material at a second portion of the second film,

wherein a thickness of the second film at the first portion of the second film is thinner than a thickness of the second film at the second portion of the second film,

wherein the first binder is a water-soluble polymer, and

wherein the second film contains lithium, fluorine, oxygen, and carbon.

18. The electrode according to claim 17 ,

wherein the first film includes a region with a thickness of 2 nm or more and 20 nm or less.

19. The electrode according to claim 17 , wherein the first binder contains carboxymethyl cellulose, methyl cellulose, ethyl cellulose, hydroxypropyl cellulose, or diacetyl cellulose.

20. The electrode according to claim 17 , wherein the second binder contains a styrene monomer or a butadiene monomer.

21. The electrode according to claim 17 , wherein the active material contains graphite.

22. A power storage device comprising:

the electrode according to claim 17 ; and

a second electrode,

wherein the electrode has a function of operating as one of a positive electrode and a negative electrode, and

wherein the second electrode has a function of operating as the other of the positive electrode and the negative electrode.

23. An electronic device comprising the power storage device according to claim 22 and a display device.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 16, 2015
From: KIMURA, KAI; KURIKI, KAZUTAKA; OGUNI, TEPPEI; UCHIDA, AYA
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 034735/0537 →
Priority Claims (1)
JP 2014-010689 · Jan 23, 2014 · national
Continuity (1)
Related Publication 20150207148A1 · Jul 23, 2015