Multi-layer microprismatic retroreflective sheeting and method of manufacturing the same
A multi-layer microprismatic retroreflective film and a method of manufacturing the same. In one embodiment, the film includes: (1) a prism layer including an acrylic polymeric material and containing microprisms, (2) a strengthening layer including a polymeric material different from the acrylic polymeric material and (3) a buffer section including acrylic polymeric material located between the microprisms of the prism layer and the strengthening layer.
1. A multi-layer microprismatic retroreflective film, comprising:
a prism layer including an acrylic polymeric material and containing microprisms;
a strengthening layer made from a polymeric material selected from the group consisting of polycarbonate, polyester, copolyester polymeric materials, and blends thereof;
an upper body layer including an acrylic polymeric material; and
a buffer section including acrylic polymeric material located between said microprisms of said prism layer and said strengthening layer, wherein:
said buffer section includes a separately provided acrylic lower body layer;
said acrylic polymeric materials of said prism layer, said upper body layer, and said lower body layer have a Vicat softening point greater than about 150° F.; and
said strengthening layer is located between said upper body layer and said lower body layer.
2. The film as recited in claim 1 wherein said buffer section includes a land section.
3. The film as recited in claim 1 wherein said lower body layer has a thickness of less than about 140 microns.
4. The film as recited in claim 1 wherein an Izod notched impact strength of said polymeric material of said strengthening layer is at least 100 J/m greater than that of said acrylic polymeric material of said prism layer.
5. The film as recited in claim 1 wherein an Izod notched impact strength of said polymeric material of said strengthening layer is at least 400 J/m greater than that of said acrylic polymeric material of said prism layer.
6. The film as recited in claim 1 wherein a tensile strength at break of said polymeric material of said strengthening layer is at least 2,000 psi greater than that of said acrylic polymeric material of said prism layer.
7. The film as recited in claim 1 wherein a tensile strength at break of said polymeric material of said strengthening layer is at least 3,500 psi greater than that of said acrylic polymeric material of said prism layer.
8. The film as recited in claim 1 wherein a Vicat softening point of said strengthening layer is at least 20° F. greater than a Vicat softening point of said acrylic polymeric material in said lower body layer.
9. The film as recited in claim 1 wherein a Vicat softening point of said strengthening layer is at least 50° F. greater than a Vicat softening point of said acrylic polymeric material in said lower body layer.
10. The film as recited in claim 1 wherein said strengthening layer comprises a polycarbonate polymeric material.
11. The film as recited in claim 1 wherein a thickness of said buffer section is at least 50% of a height of said microprisms of said prism layer.
12. The film as recited in claim 1 wherein a thickness of said buffer section ranges from about 20 microns to about 400 microns.
13. The film as recited in claim 1 further comprising a cap layer.
14. The film as recited in claim 13 wherein said cap layer comprises an acrylic polymeric material.
15. The film as recited in claim 1 wherein said lower body layer has a thickness of less than about 100 microns.
16. The film as recited in claim 1 wherein said lower body layer has a thickness of less than about 50 microns.
17. The film as recited in claim 1 wherein said microprisms have a reflective coating on lateral faces thereof, said reflective coating selected from the group consisting of aluminum, nickel, and silver.
18. The film as recited in claim 1 wherein said film has a force required to tear greater than about 1.5 LBf.
19. The film as recited in claim 1 wherein said film has a force required to tear greater than about 3.0 LBf.
20. The film as recited in claim 1 wherein said film has a force required to tear greater than about 13.0 LBf.
21. The film as recited in claim 1 wherein said film has a force required to tear greater than about 15.0 LBf.
22. A method of manufacturing a multi-layer microprismatic retroreflective film, comprising:
forming a prism layer containing microprisms from an acrylic polymeric material;
separately forming a first laminating film including a strengthening layer having a polymeric material different from said acrylic polymeric material and including an acrylic lower body layer; and
bonding said first laminating film to said prism layer, said bonding forming a buffer section having acrylic polymeric material between said microprisms and said strengthening layer.
23. The method as recited in claim 22 wherein said buffer section includes a land section.
24. The method as recited in claim 22 wherein lower body layer has a thickness of less than about 140 microns.
25. The method as recited in claim 22 wherein said first laminating film includes an upper body layer wherein said strengthening layer is located between said upper body layer and said lower body layer.
26. The method as recited in claim 22 wherein said forming said first laminating film is carried out by coextruding said strengthening layer and said lower body layer.
27. The method as recited in claim 22 wherein said lower body layer has a thickness of less than about 100 microns.
28. The method as recited in claim 22 wherein said lower body layer has a thickness of less than about 50 microns.
29. The method as recited in claim 22 wherein said microprisms have a reflective coating on lateral faces thereof, said reflective coating selected from the group consisting of aluminum, nickel, and silver.