Method for producing electrode/separator laminate, and lithium-ion rechargeable battery
To provide a method for producing an electrode/separator laminate which, when producing the electrode/separator laminate by subjecting the electrode and separator with adhesive layer to thermocompression bonding, the separator and the electrode can be bonded with adequate adhesion, without detriment to ion conductivity. [Solution] This method for producing an electrode/separator laminate includes a step in which a separator with adhesive layer comprising a porous polyolefin film having an adhesive layer at least on one side, and an electrode which has an electrode active substance layer containing an electrode active substance and an electrode binder, are laminated in such a manner that the adhesive layer and the electrode active substance layer touch one another, and are subsequently subjected to thermocompression.
1. A method for producing laminate of electrode and separator comprising,
a step of laminating a separator with adhesive layer which comprises an adhesive layer on at least one side of a porous polyolefin film, and an electrode comprising an electrode active material layer including an electrode active material and an electrode binder, so that said adhesive layer and said electrode active material layer are in contact, then carrying out a thermocompression bonding, wherein
said adhesive layer includes a particulate polymer A having a glass transition temperature of −50 to 5° C. and a particulate polymer B having a glass transition temperature of 50 to 120° C.,
a thickness of said adhesive layer is 0.2 to 1.0 μm, and
said thermocompressing bonding is carried out at 50 to 100° C.
2. The method for producing laminate of electrode and separator as set forth in claim 1 , wherein a number average particle diameter of said particulate polymer A and said particulate polymer B is 0.1 to 1 μm.
3. The method for producing laminate of electrode and separator as set forth in claim 1 , wherein said electrode binder includes a particulate polymer having a glass transition temperature of −50 to 5° C.
4. The method for producing laminate of electrode and separator as set forth in claim 1 comprising a step of coating an aqueous dispersion slurry for the adhesive layer including the particulate polymer A and the particulate polymer B, and having the viscosity of 0.001 to 0.1 Pa·s on said porous polyolefin film, and drying thereof, thereby obtaining the separator with adhesive layer.
5. The method for producing laminate of electrode and separator as set forth in claim 4 , wherein a solid concentration of said aqueous dispersion slurry for the adhesive layer is 1 to 20 wt %.
6. The method for producing laminate of electrode and separator as set forth in claim 1 , wherein a swelling ratio of said particulate polymer A and said particulate polymer B when immersed in a mixed solvent (ethylene carbonate/diethyl carbonate=1/2 (volume ratio)) including lithium salt LiPF 6 (concentration of 1 mol/L) is 1 to 5 times.
7. A lithium ion secondary battery comprising laminate of electrode and separator obtained by the production method as set forth in claim 1 .
8. The method for producing laminate of electrode and separator as set forth in claim 2 , wherein said electrode binder includes a particulate polymer having a glass transition temperature of −50 to 5° C.
9. The method for producing laminate of electrode and separator as set forth in claim 2 comprising a step of coating an aqueous dispersion slurry for the adhesive layer including the particulate polymer A and the particulate polymer B, and having the viscosity of 0.001 to 0.1 Pa·s on said porous polyolefin film, and drying thereof, thereby obtaining the separator with adhesive layer.
10. The method for producing laminate of electrode and separator as set forth in claim 3 comprising a step of coating an aqueous dispersion slurry for the adhesive layer including the particulate polymer A and the particulate polymer B, and having the viscosity of 0.001 to 0.1 Pa·s on said porous polyolefin film, and drying thereof, thereby obtaining the separator with adhesive layer.
11. The method for producing laminate of electrode and separator as set forth in claim 2 , wherein a swelling ratio of said particulate polymer A and said particulate polymer B when immersed in a mixed solvent (ethylene carbonate/diethyl carbonate=1/2 (volume ratio)) including lithium salt LiPF 6 (concentration of 1 mol/L) is 1 to 5 times.
12. The method for producing laminate of electrode and separator as set forth in claim 3 , wherein a swelling ratio of said particulate polymer A and said particulate polymer B when immersed in a mixed solvent (ethylene carbonate/diethyl carbonate=1/2 (volume ratio)) including lithium salt LiPF 6 (concentration of 1 mol/L) is 1 to 5 times.
13. The method for producing laminate of electrode and separator as set forth in claim 4 , wherein a swelling ratio of said particulate polymer A and said particulate polymer B when immersed in a mixed solvent (ethylene carbonate/diethyl carbonate=1/2 (volume ratio)) including lithium salt LiPF 6 (concentration of 1 mol/L) is 1 to 5 times.
14. The method for producing laminate of electrode and separator as set forth in claim 5 , wherein a swelling ratio of said particulate polymer A and said particulate polymer B when immersed in a mixed solvent (ethylene carbonate/diethyl carbonate=1/2 (volume ratio)) including lithium salt LiPF 6 (concentration of 1 mol/L) is 1 to 5 times.
15. A lithium ion secondary battery comprising laminate of electrode and separator obtained by the production method as set forth in claim 2 .
16. A lithium ion secondary battery comprising laminate of electrode and separator obtained by the production method as set forth in claim 3 .
17. A lithium ion secondary battery comprising laminate of electrode and separator obtained by the production method as set forth in claim 4 .
18. A lithium ion secondary battery comprising laminate of electrode and separator obtained by the production method as set forth in claim 5 .
19. A lithium ion secondary battery comprising laminate of electrode and separator obtained by the production method as set forth in claim 6 .
20. The method for producing laminate of electrode and separator as set forth in claim 1 , wherein a weight ratio (A/B) between the particulate polymer A and the particulate polymer B is within the range of 10/90 to 20/80.