Air permeation resistant film and pneumatic tire
Provided is an air permeation resistant film in which flexibility can be imparted to the film without remarkably increasing the proportion of a rubber constituting a dispersed phase. An air permeation resistant film comprising (A) a thermoplastic polyester elastomer which comprises a block copolymer containing a polyester as a hard segment and has a melting point of from 180 to 230° C., and (B) a rubber, in a mass ratio (A)/(B) of from 90/10 to 40/60, wherein the component (A) and the component (B) are melt-kneaded to perform dynamic crosslink, thereby forming a continuous phase composed of the component (A) and a dispersed phase composed of the component (B), and the film has an air permeation coefficient at 80° C. of 5×10 13 fm 2 /Pa·s or less and Young's modulus of 120 MPa or less.
1. An air permeation resistant film consisting essentially of:
(A) a thermoplastic polyester elastomer which is a block copolymer containing a hard segment and a soft segment, and has a melting point of from 180 to 230° C., and (B) at least one rubber, in a mass ratio (A)/(B) of from 90/10 to 40/60,
wherein the component (A) and the component (B) are melt-kneaded to perform dynamic crosslink, thereby forming a continuous phase composed of the component (A) and a dispersed phase composed of the component (B),
wherein the hard segment comprises polybutylene terephthalate,
wherein the soft segment comprises aliphatic polycarbonate,
the film has an air permeation coefficient at 80° C. of 5×10 13 fm 2 /Pa·s or less and Young's modulus of 120 MPa or less,
wherein a number average molecular weight of aliphatic polycarbonate diol, which is a raw material of the aliphatic polycarbonate, is from 3,000 to 60,000.
2. The air permeation resistant film according to claim 1 , wherein the component (B) is at least one rubber selected from butyl rubber, halogenated butyl rubber, nitrile rubber and hydrogenated nitrile rubber.
3. The air permeation resistant film according to claim 1 , wherein the component (A) has an air permeation coefficient at 80° C. of 5×10 13 fm 2 /Pa·s or less and Young's modulus of from 100 to 500 MPa, and the component (B) has Young's modulus of 50 MPa or less.
4. The air permeation resistant film according to claim 1 , which further contains a compatibilizing agent.
5. The air permeation resistant film according to claim 4 , wherein the compatibilizing agent has an ethylene main chain framework and a side chain containing an epoxy group.
6. The air permeation resistant film according to claim 1 , further contains a crosslinking agent for dynamically crosslinking the at least one rubber of component (B), wherein the crosslinking agent is a phenolic resin.
7. The air permeation resistant film according to claim 1 , wherein a mass ratio of the hard segment to the soft segment is from 45/55 to 87/13.
8. The air permeation resistant film according to claim 1 , wherein the mass ratio (A)/(B) is from 90/10 to 50/50.
9. The air permeation resistant film according to claim 1 , wherein the hard segment is polybutylene terephthalate, and the soft segment is aliphatic polycarbonate.
10. The air permeation resistant film according to claim 1 , wherein the aliphatic polycarbonate diol is produced from carbonate ester and aliphatic glycol having from 2 to 12 carbon atoms.
11. A pneumatic tire having the air permeation resistant film according to claim 1 as an inner liner or other air permeation inhibiting layer.
12. A method for producing an air permeation resistant film, which comprises melt-kneading a composition consisting essentially of (A) a thermoplastic polyester elastomer that is a block copolymer containing a hard segment and a soft segment, and has a melting point of from 180 to 230° C., and (B) at least one a rubber, in a mass ratio (A)/(B) of from 90/10 to 40/60 to perform dynamic crosslink, thereby obtaining a polymer composition comprising a continuous phase composed of the component (A) and a dispersed phase composed of the component (B), and forming a film comprising the polymer composition,
wherein the hard segment comprises polybutylene terephthalate,
wherein the soft segment comprises aliphatic polycarbonate, and
wherein a number average molecular weight of aliphatic polycarbonate diol, which is a raw material of the aliphatic polycarbonate, is from 3,000 to 60,000.
13. The production method according to claim 12 , wherein the air permeation resistant film has an air permeation coefficient at 80° C. of 5×10 13 fm 2 /Pa·s or less and Young's modulus of 120 MPa or less.
14. The production method according to claim 12 , wherein the component (A) has an air permeation coefficient at 80° C. of 5×10 13 fm 2 /Pa·s or less and Young's modulus of from 100 to 500 MPa, and the component (B) has Young's modulus of 50 MPa or less.
15. The production method according to claim 12 , which comprises mixing a compatibilizing agent together with the component (A) and the component (B).
16. The production method according to claim 15 , wherein the compatibilizing agent has an ethylene main chain framework and a side chain containing an epoxy group.
17. The production method according to claim 12 , comprising adding a crosslinking agent for dynamically crosslinking the rubber of component (B), wherein the crosslinking agent is a phenolic resin.
18. The production method according to claim 12 , wherein the mass ratio (A)/(B) is from 90/10 to 50/50.
19. The production method according to claim 12 , wherein the hard segment is polybutylene terephthalate, and the soft segment is aliphatic polycarbonate.
20. The production method according to claim 12 , wherein the aliphatic polycarbonate diol is produced from carbonate ester and aliphatic glycol having from 2 to 12 carbon atoms.
21. The production method according to claim 12 , wherein the component (B) is at least one rubber selected from butyl rubber, halogenated butyl rubber, nitrile rubber and hydrogenated nitrile rubber.
22. A method for producing a pneumatic tire, which comprises obtaining an air permeation resistant film by the production method according to claim 12 , preparing a cylindrical inner liner comprising the air permeation resistant film, fixing a carcass ply and other rubber members including a tread rubber to an outer peripheral side of the inner liner to prepare a green tire, and vulcanization molding the green tire in a mold.