Organic electroluminescent device having a sealant with magnetic particles, method for preparing the same and display panel
An organic electroluminescent device, a method for preparing an organic electroluminescent device, and a display panel are disclosed. The organic electroluminescent device comprises a conductive layer formed by transparent magnetic conductive particles which are mixed in the sealing layer and stacked on a surface of the first transparent electrode layer. The conductive layer increases the conductive performance while not increasing the thickness of the first transparent electrode layer, thereby avoiding decrease of the light transmittance caused by increase of the thickness of the first transparent electrode layer, and avoiding the problem of voltage drop due to poor conductivity of the first transparent electrode layer, so as to improve the display effect and use stability of the organic electroluminescent device.
1. An organic electroluminescent device, comprising a substrate and a cover plate arranged opposite to each other, a sealing frame located between the substrate and the cover plate for connecting the substrate and the cover plate, a sealing layer filling an area enclosed by the sealing frame and bonded with the substrate and the cover plate, a first transparent electrode layer being provided at a side of the substrate facing the cover plate, wherein the organic electroluminescent device further comprises a conductive layer formed by transparent magnetic conductive particles which are mixed in the sealing layer and stacked on a surface of the first transparent electrode layer.
2. The organic electroluminescent device of claim 1 , wherein the first transparent electrode layer comprises indium zinc oxide.
3. The organic electroluminescent device of claim 1 , wherein a weight concentration of the transparent magnetic conductive particles in the sealing layer is greater than or equal to 5% and less than or equal to 50%.
4. The organic electroluminescent device of claim 3 , wherein a diameter of the transparent magnetic conductive particles in the sealing layer is not greater than 200 nm.
5. The organic electroluminescent device of claim 1 , wherein the transparent magnetic conductive particles are metal oxide nanoparticles or non-metal oxide nanoparticles.
6. The organic electroluminescent device of claim 1 , wherein a second transparent electrode layer is formed on a surface of the cover plate facing the substrate, the sealing layer is provided with a conductor structure formed by transparent magnetic conductive particles mixed in the sealing layer, and the conductor structure joins the second transparent electrode layer with the first transparent electrode layer.
7. The organic electroluminescent device of claim 2 , wherein a second transparent electrode layer is formed on a surface of the cover plate facing the substrate, the sealing layer is provided with a conductor structure formed by transparent magnetic conductive particles mixed in the sealing layer, and the conductor structure joins the second transparent electrode layer with the first transparent electrode layer.
8. The organic electroluminescent device of claim 3 , wherein a second transparent electrode layer is formed on a surface of the cover plate facing the substrate, the sealing layer is provided with a conductor structure formed by transparent magnetic conductive particles mixed in the sealing layer, and the conductor structure joins the second transparent electrode layer with the first transparent electrode layer.
9. The organic electroluminescent device of claim 4 , wherein a second transparent electrode layer is formed on a surface of the cover plate facing the substrate, the sealing layer is provided with a conductor structure formed by transparent magnetic conductive particles mixed in the sealing layer, and the conductor structure joins the second transparent electrode layer with the first transparent electrode layer.
10. The organic electroluminescent device of claim 5 , wherein a second transparent electrode layer is formed on a surface of the cover plate facing the substrate, the sealing layer is provided with a conductor structure formed by transparent magnetic conductive particles mixed in the sealing layer, and the conductor structure joins the second transparent electrode layer with the first transparent electrode layer.
11. An organic electroluminescent device display panel, comprising an organic electroluminescent device of claim 1 .
12. A method for preparing an organic electroluminescent device of claim 1 , comprising:
step S 101 , coating a sealing frame and a sealing material mixed with transparent magnetic conductive particles between a cover plate and a substrate, and adjusting distribution of transparent magnetic conductive particles within the sealing material through magnetic field effect, to form a conductive layer on a surface of a first transparent electrode layer, wherein the first transparent electrode layer is formed at a side of the substrate facing the cover plate, and the conductive layer is formed by transparent magnetic conductive particles stacked on the surface of the first transparent electrode layer;
step S 102 , curing the sealing frame and the sealing material to assemble the substrate and the cover plate.
13. The method of claim 12 , wherein the step S 101 comprises:
coating the sealing frame on the cover plate;
coating the sealing material mixed with transparent magnetic conductive particles within an area enclosed by the sealing frame on the cover plate;
pressing the cover plate and the substrate formed with the first transparent electrode layer together in vacuum; and
placing the pressed cover plate and substrate in a magnetic field, adjusting distribution of transparent magnetic conductive particles within the sealing material through magnetic field effect, to form the conductive layer on the surface of a first transparent electrode layer, wherein the first transparent electrode layer is formed at a side of the substrate facing the cover plate, and the conductive layer is formed by transparent magnetic conductive particles stacked on the surface of the first transparent electrode layer.
14. The method of claim 12 , wherein the sealing material is coated on the cover plate using gluing process, slot coating or ink jet coating.
15. The method of claim 12 , wherein the step S 101 comprises:
coating the sealing material mixed with transparent magnetic conductive particles on the first transparent electrode layer on the substrate;
placing the substrate in a magnetic field, adjusting distribution of transparent magnetic conductive particles within the sealing material through magnetic field effect, to form a conductive layer on a surface of a first transparent electrode layer, wherein the first transparent electrode layer is formed at a side of the substrate facing the cover plate, and the conductive layer is formed by transparent magnetic conductive particles stacked on the surface of the first transparent electrode layer; and
pressing the substrate and the cover plate coated with the sealing frame together in vacuum.
16. The method of claim 14 , wherein the sealing material is coated on the substrate using ink jet coating or slot coating.
17. The method of claim 12 , wherein the step S 102 comprises:
curing the sealing frame and the sealing material by UV radiation or heating to assemble the substrate and the cover plate.
18. The method of claim 12 , wherein prior to the step S 101 , the method further comprises: mixing transparent magnetic conductive particles in the sealing material.
19. The method of claim 12 , wherein coating the sealing material between the cover plate and the substrate comprises:
coating a sealing material which comprises transparent magnetic conductive particles between the cover plate and the substrate; and
coating on the sealing material a sealing material which does not comprises transparent magnetic conductive particles.
20. The method of claim 12 , wherein coating the sealing material between the cover plate and the substrate comprises:
coating a sealing material comprising transparent magnetic conductive particles in a first weight concentration between the cover plate and the substrate; and
coating on the sealing material a sealing material comprising transparent magnetic conductive particles in a second weight concentration larger than the first weight concentration.