Nanoparticles, compositions, manufacture and applications
View Patent ↗There are disclosed energetic nanoparticle compositions and materials containing silicon and other energetic elements, and methods of manufacturing the same, including reacting silicon nanoparticles and unsaturated alkene or alkyne to form covalently bonded surface coatings passivated against surface oxidation, for combination with a fuel, explosive or oxidizer.
1. A method for refining silicon comprising:
(a) substantially fully vaporizing a silicon feedstock comprising an impurity selected from the group consisting of aluminum, phosphorous, and boron, in a plasma torch vaporization zone at a vaporization temperature of at least about 2000° C. at a first pressure of at least about 0.5 Bar together with a halogen and/or hydrogen getter component to form a silicon vapor stream and a vaporized getter;
(b) conducting said silicon vapor stream with said vaporized getter into an expansion cooling zone at a second pressure lower than said first pressure, wherein said silicon vapor stream is flash cooled at least about 500° C. at a rate of at least about 1×10 3 ° C. per second, to nucleate and precipitate silicon particles depleted in the impurity, and wherein the impurity remains as a vapor component in an entraining gas stream to form an impurity-enriched gas stream; and
(c) separating the impurity-depleted, precipitated silicon particles from said impurity-enriched gas stream.
2. The method in accordance with claim 1 wherein at least about 95 weight percent of said silicon feedstock is vaporized; wherein said getter component comprises a silicon chloride, a silicon fluoride, or mixtures thereof; wherein said vaporization temperature in said plasma torch vaporization zone is at least about 3000° C.; wherein said first pressure is at least about 2 Bar;
wherein said silicon vapor stream conducted into said expansion cooling zone is cooled to at least 1000° C. at a rate of at least about 1×10 5 ° C. per second; and wherein said second pressure is less than about 0.2 Bar.
3. The method in accordance with claim 1 comprising substantially fully vaporizing said silicon feedstock with a hydrogen getter at a temperature above about 3000° C. to form a silicon-hydrogen gas stream, and rapidly cooling said silicon-hydrogen gas stream to form condensed silicon nanoparticles having hydrogen-terminated surfaces.
4. The method in accordance with claim 1 wherein silicon nanoparticles are condensed in said vapor stream, and wherein said silicon nanoparticles are combined with a paraffin or kerosene hydrocarbon to form a hybrid rocket fuel comprising at least about 1 weight percent of said silicon nanoparticles.
5. A method for producing surface passivated silicon nanoparticles comprising:
(a) substantially fully vaporizing a silicon feedstock comprising an impurity in a plasma torch vaporization zone at a temperature of at least about 2000° C. at a first pressure of at least about 0.5 Bar together with a halogen and/or hydrogen getter component to form a silicon vapor stream and a vaporized getter;
(b) conducting said silicon vapor stream with said vaporized getter into an expansion cooling zone at a second pressure lower than said first pressure, wherein said silicon vapor stream is flash cooled to at least about 500° C. at a rate of at least about 1×10 3 ° C. per second, to nucleate and precipitate silicon nanoparticles depleted in the impurity, and wherein the impurity remains as a vapor component in an entraining gas stream to form an impurity-enriched gas stream;
(c) separating the impurity-depleted, precipitated silicon particles from said impurity-enriched gas stream in a hydrocarbon particle collector liquid, wherein said silicon nanoparticles are reacted with an unsaturated alkene or alkyne to form a covalently-bonded alkane or alkene surface coating to produce silicon nanoparticles that are passivated against surface oxidation; and
(d) combining said passivated silicon nanoparticles with an explosive or oxidizer.
6. The method in accordance with claim 5 wherein an unsaturated alkene or alkyne is introduced into said impurity-enriched gas stream and reacts with said silicon nanoparticles to form a covalently-bonded alkane or alkene surface coating to produce silicon nanoparticles which are passivated against surface oxidation, and combining said passivated silicon nanoparticles with a hydrocarbon, explosive, or oxidizer.
7. The method in accordance with claim 5 wherein said alkene comprises a fluorinated alkene, an alkene amine, or an alkene alcohol.