IP Library Granted Patent US 9,778,618
Granted Patent B2
US 9,778,618 · App. 14/689,092 · Granted Oct 3, 2017

Multilayer film and authentication label

Inventors: Michael G Fickes (Kennett Square, PA); Michael L Levin (Newark, DE)
Assignee: DUPONT AUTHENTICATION INC.
G03H1/0011B32B7/06B32B7/12B32B27/08B32B27/14B32B27/302B32B27/304B32B27/36G03H1/0248G03H1/0252G03H1/0256G03H1/0272B32B37/0015B32B37/12B32B38/0036B32B38/10B32B2250/05B32B2270/00B32B2307/40B32B2307/736B32B2439/00B32B2519/00C09J7/0296C09J2203/334C09J2425/006C09J2427/006C09J2433/00C09J2467/006G03H2210/30G03H2240/50G03H2250/10G03H2250/35G03H2250/39G03H2250/40G03H2250/44G09F3/0291G09F3/04
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Quick Facts
Patent No.
US 9,778,618
App. No.
14/689,092
Granted
Oct 3, 2017
Kind
B2
Abstract

In a first aspect, a multilayer film includes a holographic image layer, a first heat-shrinkable layer and a first adhesive layer between the holographic image layer and the first heat-shrinkable layer. In a second aspect, an authentication label includes a holographic image layer, a first heat-shrinkable layer, a first adhesive layer between the holographic image layer and the first heat-shrinkable layer, and a back adhesive layer.

Claims (41)

1. A multilayer film comprising:

a holographic image layer;

a first heat-shrinkable layer;

a first adhesive layer between the holographic image layer and the first heat-shrinkable layer;

a second heat-shrinkable layer adhered to the holographic image layer on a side opposite the first heat-shrinkable layer; and

a third adhesive layer between the holographic image layer and the second heat-shrinkable layer,

and wherein the holographic image layer comprises a volume hologram.

2. The multilayer film of claim 1 , wherein the volume hologram comprises an image recorded in a photopolymer, a silver halide emulsion, a dichromated gelatin, or any combination thereof.

3. The multilayer film of claim 1 , wherein the holographic image layer further comprises a color-tuning layer.

4. The multilayer film of claim 1 , wherein the first heat-shrinkable layer is selected from a polyester film, a polystyrene film, a polylactic acid film, a polyvinyl chloride film, or any combination thereof.

5. The multilayer film of claim 4 , wherein the first heat-shrinkable layer comprises polyethylene terephthalate glycol-modified film as the polyester film.

6. The multilayer film of claim 1 , wherein the first adhesive layer comprises a pressure-sensitive adhesive.

7. The multilayer film of claim 6 , wherein the pressure-sensitive adhesive is selected from an acrylic resin, a rubber-based resin, a silicone resin, or any combination thereof.

8. The multilayer film of claim 1 , wherein the first adhesive layer comprises an ultraviolet-cured adhesive.

9. The multilayer film of claim 1 , further comprising a protective film layer and a second adhesive layer.

10. The multilayer film of claim 9 , wherein the protective film layer comprises polyethylene terephthalate.

11. The multilayer film of claim 9 , wherein the holographic image layer is between the first heat-shrinkable layer and the protective film layer and the second adhesive layer is between the holographic image layer and the protective film layer.

12. The multilayer film of claim 9 , wherein the first heat-shrinkable layer is between the holographic image layer and the protective film layer and the second adhesive layer is between the first heat-shrinkable layer and the protective film layer.

13. The multilayer film of claim 1 further comprising an ink layer.

14. A multilayer film comprising:

a holographic image layer;

a first heat-shrinkable layer;

a first adhesive layer between the holographic image layer and the first heat-shrinkable layer; wherein

on heating, the first heat-shrinkable layer shrivels or shrinks such that at least a part of the holographic image layer is unprotected.

15. The multilayer film of claim 14 , further comprising:

a back adhesive layer, wherein the back adhesive layer is adjacent to a side of the holographic image layer that is opposite the first heat-shrinkable layer and is adhered to a substrate.

16. The multilayer film of claim 14 , wherein the holographic image layer comprises a volume hologram.

17. An authentication label comprising:

a holographic image layer;

a first heat-shrinkable layer;

a first adhesive layer between the holographic image layer and the first heat-shrinkable layer; and

a back adhesive layer, wherein the holographic image layer is between the back adhesive layer and the first adhesive layer, and wherein on heating, the first heat-shrinkable layer shrivels or shrinks such that at least a part of the holographic image layer is unprotected.

18. The authentication label of claim 17 , further comprising a protective film layer and a second adhesive layer, wherein the second adhesive layer is between the protective film and a side of the first heat-shrinkable layer that is opposite the first adhesive layer.

19. The authentication label of claim 17 further comprising a first ink layer between the holographic image layer and the back adhesive layer and a second ink layer on an exterior surface of the first heat-shrinkable layer.

20. The authentication label of claim 19 , wherein the back adhesive layer is adjacent to the side of the holographic image layer that is opposite the first heat-shrinkable layer and is adhered to a substrate.

21. The authentication label of claim 19 , wherein the holographic image layer comprises a volume hologram.

22. The authentication label of claim 21 , wherein the volume hologram comprises an image recorded in a photopolymer, a silver halide emulsion, a dichromated gelatin, or any combination thereof.

23. The authentication label of claim 17 , wherein the holographic image layer further comprises a color-tuning layer.

24. The authentication label of claim 17 , wherein the first heat-shrinkable layer is selected from a polyester film, a polystyrene film, a polylactic acid film, a polyvinyl chloride film, or any combination thereof.

25. The authentication label of claim 24 , wherein the first heat-shrinkable layer comprises a polyethylene terephthalate glycol-modified film as the polyester film.

26. The authentication label of claim 17 , wherein the first adhesive layer comprises a pressure-sensitive adhesive.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded May 1, 2025
From: GLAS TRUST CORPORATION LIMITED, LLC
To: DE LA RUE AUTHENTICATION SOLUTIONS INC.
Reel/Frame 070993/0794 →
IP SECURITY AGREEMENT SUPPLEMENT Recorded Aug 14, 2023
From: DE LA RUE AUTHENTICATION SOLUTIONS INC.
To: GLAS TRUST CORPORATION LIMITED, AS SECURITY AGENT
Reel/Frame 064584/0686 →
CHANGE OF NAME Recorded Jan 12, 2018
From: DUPONT AUTHENTICATION, INC.
To: DE LA RUE AUTHENTICATION SOLUTIONS INC.
Reel/Frame 045066/0192 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 19, 2017
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT AUTHENTICATION, INC.
Reel/Frame 041017/0600 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 27, 2016
From: FICKES, MICHAEL G; LEVIN, MICHAEL L
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 040147/0656 →
Continuity (2)
Provisional Application 61981238 · Apr 18, 2014
Related Publication 20150301499A1 · Oct 22, 2015