Laser controlled ion exchange process and glass articles formed therefrom
A method for forming ion-exchanged regions in a glass article by contacting an ion source with at least one surface of the glass article, forming a first ion-exchanged region in the glass article by heating a first portion of the glass article with a laser, and forming a second ion-exchanged region in the glass article. Characteristics of the first ion-exchanged region may be different from characteristics of the second ion-exchanged region. A depth of the ion-exchanged region may be greater than 1 μm. A glass article including a first ion-exchanged region, and a second ion-exchanged region having different characteristics from the first ion-exchanged region. The thickness of the glass article is less than or equal to about 0.5 mm.
1. A method for forming ion-exchanged regions in a glass article, the method comprising:
contacting an ion exchange source with at least one surface of the glass article;
forming a first ion-exchanged region in the glass article by heating a first portion of the glass article with laser energy, wherein the first ion-exchanged region comprises a first compressive stress; and
forming a second ion-exchanged region in the glass article by heating a second portion of the glass article with laser energy, wherein the second ion-exchanged region comprises a second compressive stress that is different from the first compressive stress,
wherein at least a portion of the first ion-exchanged region is located at an edge face of the glass article, the second ion-exchanged region is located at a major surface of the glass article, and a concentration of ions in the first ion-exchanged region is greater than a concentration of ions in the second ion exchange region.
2. The method of claim 1 , wherein a depth of the first ion-exchanged region is different than a depth of the second ion-exchanged region.
3. The method of claim 1 , wherein a depth of each of the first and second ion-exchanged regions is from about 5 μm to about 60 μm.
4. The method of claim 1 , wherein the glass article does not contain any alkali metal ions.
5. The method of claim 1 , wherein the ion exchange source is selected from the group consisting of KNO 3 , NaNO 3 , and AgNO 3 .
6. The method of claim 1 , wherein the laser energy originates from a laser selected from the group consisting of a CO laser, a CO 2 laser, and an infrared laser.
7. The method of claim 1 , wherein the laser is applied to a surface of the glass article where the ion exchange source is not contacted.
8. The method of claim 1 , wherein multiple ion exchange sources are contacted on the at least one surface of the glass article and laser parameters are adjusted to produce ion-exchanged regions in the glass article for each ion exchange source.
9. The glass article of claim 1 , wherein one of the first and second ion exchange sources is a molten salt bath having a temperature less than a temperature of about 400° C. or less.
10. The glass article of claim 1 , wherein laser parameters are adjusted from the first ion-exchanged region to the second ion-exchanged region.
11. The glass article of claim 1 , wherein at least one of the first and second ion exchange sources are contacted with the glass article in a pattern.
12. A method for forming ion-exchanged regions in a glass article, the method comprising:
contacting an ion exchange source with at least a first surface of the glass article;
forming a first ion-exchanged region in the first surface by heating a first portion of the glass article with laser energy, wherein the first ion-exchanged region comprises a first compressive stress; and
forming a second ion-exchanged region in the glass article by heating a second portion of the glass article with laser energy, wherein the second ion-exchanged region comprises a second compressive stress that is different from the first compressive stress,
wherein:
an ion exchange source is contacted with a second surface of the glass article,
ion-exchanged regions are formed on the second surface of the glass article,
the first surface and the second surface are different surfaces, and
characteristics of at least one ion-exchanged region on the first surface and the ion-exchanged regions on the second surface are different.
13. The method of claim 12 , wherein the second ion-exchanged region is a plurality of ion-exchanged regions formed on the second surface of the glass article, wherein the plurality of ion-exchanged regions are substantially identical to one another.
14. The method of claim 12 , wherein the second ion-exchanged region is formed on the second surface of the glass article, and a depth of the first ion-exchanged region is different than a depth of the second ion-exchanged region on the second surface.
15. The method of claim 12 , wherein the second ion exchanged region is formed on the second surface of the glass article and a concentration of ions in the first ion-exchanged region on the first surface is different than a concentration of ions in the second ion-exchanged region on the second surface.
16. A method for forming ion-exchanged regions in a glass article, the method comprising:
contacting multiple ion exchange sources with at least one surface of the glass article; and
forming ion-exchanged regions in the glass article by heating a portion of the glass article with a laser, wherein laser parameters are adjusted to produce ion-exchanged regions in the glass article for each ion exchange source, the ion-exchanged regions for each ion exchange source having different compressive stresses,
wherein a depth of the ion-exchanged region is greater than 1 μm.
17. The method of claim 16 , wherein the multiple ion exchange sources are selected from the group consisting of KNO 3 , NaNO 3 , and AgNO 3 .
18. The method of claim 16 , wherein a portion of the ion-exchanged regions are formed at an edge face of the glass article.