Polarizing plate and liquid crystal display comprising the same
The present invention relates to a polarizing plate and a liquid crystal display device. In the present invention, the polarizing plate is lightweight and has a small thickness and excellent properties including durability, water resistance, workability, pressure-sensitive adhesion and light leakage prevention ability; and the liquid crystal display device including the same are provided.
1. A polarizing plate, comprising:
a polarizer;
an adhesive layer directly attached to at least one surface of the polarizer; and
an acrylic pressure-sensitive adhesive layer directly attached to the adhesive layer, wherein the acrylic pressure-sensitive adhesive layer includes a first layer and a second layer, and
wherein the first layer is directly adjacent to the adhesive layer and has a tensile modulus at 25° C. of 300 MPa to 850 MPa, and the second layer has a tensile modulus at 25° C. of 0.01 MPa to 1.0 MPa, and
wherein the first layer comprises a cross-linking structure comprising an acryl polymer cross-linked by a multifunctional cross-linking agent and a cross-linking structure comprising a polymerized multifunctional acrylate.
2. The polarizing plate according to claim 1 , wherein the second layer has a pressure-sensitive adhesive surface for attaching the polarizing plate to a liquid crystal panel.
3. The polarizing plate according to claim 1 , wherein the polarizer is a polyvinyl alcohol-based polarizer.
4. The polarizing plate according to claim 1 , wherein the acrylic pressure-sensitive adhesive layer has a thickness of 10 to 80 μm.
5. The polarizing plate according to claim 1 , wherein the adhesive layer includes at least one selected from the group consisting of a polyvinyl alcohol-based adhesive; an acryl-based adhesive; a vinyl acetate-based adhesive; a urethane-based adhesive; a polyester-based adhesive; a polyolefin-based adhesive; a polyvinylalkylether-based adhesive; a rubber-based adhesive; a vinylchloride-vinylacetate-based adhesive; a styrene-butadiene-styrene adhesive; a hydrogenated styrene-butadiene-styrene-based adhesive; an ethylene-based adhesive; and an acrylic acid ester-based adhesive.
6. The polarizing plate according to claim 1 , wherein the adhesive layer includes a thermocurable adhesive composition, a room temperature curable adhesive composition, a moisture curable adhesive composition, or a photocurable adhesive composition in a cured state.
7. The polarizing plate according to claim 1 , further comprising:
a protective film attached to the surface to which the acrylic pressure-sensitive adhesive layer of the polarizer is not attached.
8. The polarizing plate according to claim 1 , wherein the second layer has a tensile modulus at 25° C. of 0.03 to 0.7 MPa.
9. The polarizing plate according to claim 1 , wherein the polymerized multifunctional acrylate is present in an amount of 20 to 200 parts by weight with respect to 100 parts by weight of the acryl polymer.
10. A liquid crystal display device, comprising:
a liquid crystal panel; and
a polarizing plate according to claim 1 attached to one or both surfaces of the liquid crystal panel.
11. The device according to claim 10 , wherein the liquid crystal panel is a passive matrix panel, an active matrix panel, an in-plane switching panel or a vertical alignment panel.