IP Library Granted Patent US 9,798,043
Granted Patent B2
US 9,798,043 · App. 15/111,581 · Granted Oct 24, 2017

Optical fiber, optical fiber cable and communication equipment

Inventors: Hideki Kihara (Toyama, JP); Akinori Ishikado (Toyama, JP); Yoshihiro Tsukamoto (Toyama, JP)
Assignee: Mitsubishi Chemical Corporation
G02B1/048C03C25/104C08F20/22C08L33/12C08L33/16G02B6/02033G02B6/02042G02B6/02395G02B6/4401
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,798,043
App. No.
15/111,581
Granted
Oct 24, 2017
Kind
B2
Abstract

Provided is an optical fiber which has exceptional heat resistance and is highly safe. This optical fiber has a core, and a sheath of a least one layer around the outside circumference of the core, the sheath including a polymer that contains a repeating unit (A) derived from a fluoroalkyl (meth)acrylate having a specific structure.

Claims (33)

1. An optical fiber, comprising:

a core; and

at least one cladding layer formed on a periphery of the core,

wherein the cladding layer comprises a polymer having a repeating unit (A) derived from 2-(perfluorohexyl)ethyl methacrylate.

2. The optical fiber according to claim 1 , wherein the polymer forming the cladding layer further contains a repeating unit (B) derived from a fluoroalkyl (meth)acrylate represented by formula (3) below:

wherein in formula (3), p is an integer of 1 or 2, q is an integer of 1 to 4, R is a hydrogen atom or a methyl group, and X is a hydrogen atom or fluorine atom.

3. The optical fiber according to claim 1 , wherein the polymer forming the cladding layer further comprises a repeating unit (C) derived from an alkyl (meth)acrylate that does not include a fluorine atom.

4. The optical fiber according to claim 1 , wherein the polymer forming the cladding layer further comprises a repeating unit (D) derived from a hydrophilic monomer.

5. The optical fiber according to claim 2 , wherein the polymer forming the cladding layer comprises the following relative to 100 mass % of the polymer:

15 to 60 mass % of the repeating unit (A) derived from 2-(perfluorohexyl)ethyl methacrylate,

20 to 70 mass % of the repeating unit (B) derived from fluoroalkyl (meth)acrylate represented by formula (3),

10 to 30 mass % of a repeating unit (C) derived from alkyl (meth)acrylate that does not include a fluorine atom, and

0.1-10 mass % of a repeating unit (D) derived from a hydrophilic monomer.

6. The optical fiber according to claim 1 , wherein the polymer to form the cladding layer comprises the following relative to 100 mass % of the polymer:

10 to 50 mass % of the repeating unit (A) derived from 2-(perfluorohexyl)ethyl methacrylate,

40 to 80 mass % of a repeating unit (C) derived from alkyl (meth)acrylate that does not include a fluorine atom, and

0.1 to 10 mass % of a repeating unit (D) derived from a hydrophilic monomer.

7. The optical fiber according to claim 4 , wherein the polymer forming the cladding layer comprises at least 1.5 mass % of the repeating unit (D) derived from a hydrophilic monomer relative to 100 mass % of the polymer.

8. The optical fiber according to claim 1 , wherein the polymer forming the cladding layer has a glass transition temperature (Tg) (° C.) and a refractive index (n) that satisfy formula (4) below:

Tg≧ 375× n− 455  (4).

9. The optical fiber according to claim 1 , comprising only one cladding layer.

10. The optical fiber according to claim 1 , comprising two or more cladding layers.

11. The optical fiber according to claim 1 , comprising one core.

12. The optical fiber according to claim 1 , comprising multiple cores.

13. An optical fiber cable, comprising:

the optical fiber according to claim 1 ; and

a jacket layer formed on a periphery of the optical fiber.

14. The optical fiber cable according to claim 13 , wherein the jacket layer comprises 50 mass % or greater of a polyolefin resin or a chlorinated polyolefin resin.

15. A communication equipment device, comprising the optical fiber according to claim 1 .

16. The optical fiber cable according to claim 4 , wherein a monomer forming the repeating unit (D) is selected from the group consisting of (meth)acrylic acid, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate and glycidyl (meth)acrylate.

17. The optical fiber cable according to claim 10 , wherein the cladding layer comprises:

a first inner layer containing a cladding material comprising the polymer having a repeating unit derived from 2-(perfluorohexyl)ethyl methacrylate, and

a second layer containing a cladding material having a refractive index lower than that of the first layer.

Assignments (2)
MERGER Recorded Jun 28, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043027/0929 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 14, 2016
From: KIHARA, HIDEKI; ISHIKADO, AKINORI; TSUKAMOTO, YOSHIHIRO
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 039158/0233 →
Priority Claims (1)
JP 2014-010042 · Jan 23, 2014 · national
Continuity (1)
Related Publication 20160334548A1 · Nov 17, 2016