Nitrile rubber and method of preparing the same
Disclosed are nitrile rubber and a method of preparing the same. The nitrile rubber contributing to an excellent polymerization rate and vulcanization rate and having advantageous processability during vulcanization, and a method of preparing the same are disclosed.
1. A nitrile rubber consisting of
18 to 29 wt % of at least one α,β-unsaturated nitrile monomer,
82 to 71 wt % of at least one conjugated diene monomer,
0.5 to 5 parts by weight of a fatty acid based on 100 parts by weight of the nitrile rubber;
0.01 to 10 parts by weight of alkyl thiol based on 100 parts by weight of the nitrile rubber; and
0.01 to 1 part by weight of oil-soluble peroxide based on 100 parts by weight of the nitrile rubber
wherein the α,β-unsaturated nitrile monomer is at least one selected from acrylonitrile, methacrylonitrile, fumaronitrile, α-chloronitrile or α-cyanoethyl acrylonitrile,
wherein the conjugated diene monomer is at least one selected from 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 2-ethyl-1,3-butadiene, 1,3-pentadiene, or isoprene,
wherein ΔACN ranges from 2 to 3, and Mooney stress-relaxation rate (MSR) of the nitrile rubber measured with a shearing-disc viscometer according to ISO 289-4:2003 E at 100° C. is in the range of 0.35 to 0.383.
2. The nitrile rubber according to claim 1 , wherein the fatty acid is at least one selected from the group consisting of oleic acid, rosin acid, lauric acid, myristic acid, palmitic acid, stearic acid, naphthalene sulfonic acid, and eicosanoic acid.
3. The nitrile rubber according to claim 1 , wherein the alkyl thiol comprises 12 to 16 carbon atoms, and three or more tertiary carbon atoms comprising sulfur bond to one of the tertiary carbon atoms.
4. The nitrile rubber according to claim 3 , wherein
the alkyl thiol is at least one selected from the group consisting of 2,2,4,6,6-pentamethylheptane-4-thiol and 2,2,4,6,6,8,8-heptamethylnonane-4-thiol.
5. The nitrile rubber according to claim 1 , wherein
the oil-soluble peroxide is at least one selected from the group consisting of benzoyl peroxide, di-t-butylperoxide, azobisisobutyronitrile, tributyl hydroperoxide, dicumyl peroxide, t-butyl perbenzoate, cumene hydroperoxide, t-butyl peroctoate, methyl ethylketone peroxide, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, p-menthane hydroperoxide, and lauryl peroxide.
6. A vulcanizable mixture comprising the nitrile rubber according to claim 1 and at least one crosslinker.
7. A molded product formed from the vulcanizable mixture according to claim 6 .
8. The molded product according to claim 7 , wherein the molded product has a tensile strength of 225 to 246 kgf/cm2 and an elongation ratio of 377 to 387%, and a 300% modulus of 174 to 185, wherein the tensile strength, elongation ratio, and 300% modulus are measured at a vulcanised state according to DIN 53 504.
9. The molded product according to claim 7 , wherein the molded product is seals, caps, hoses or diaphragms, O-ring seals, flat-type seals, corrugated seal rings, seal sleeves, seal caps, dust block caps, plug seals, insulation hoses, oil cooler hoses, inhalation hoses, servo control hoses, or pump diaphragms.