Polyamide compositions for LED applications

1. A composition having at least one melting temperature (Tm) as measured according to ISO 11357-3, said composition comprising:

at least one polyamide;

at least one metal oxide selected from magnesium oxide, zinc oxide, calcium oxide and mixtures thereof; and

titanium dioxide;

wherein the composition has an intrinsic melt viscosity of below 800.0 Pa·s as measured according to ASTM D3835-08 at a moisture content as measured according to ASTM D6869-03 in the range of 150-500 ppm at a shear rate of 400 s −1 and at a temperature ranging from [(Tm max)+10° C.] to [(Tm max)+20° C.], where (Tm max) is the highest of all melting temperatures (Tm).

2. The composition according to claim 1 , wherein the weight percent of the polyamide in the total weight of the composition is of at least 30 wt. %.

3. The composition according to claim 1 , wherein the composition further comprises a reinforcing filler.

4. The composition according to claim 3 , wherein the reinforcing filler is selected from wollastonite and glass fiber.

5. The composition according to claim 3 , wherein the weight percent of the reinforcing filler in the total weight of the composition is of at least 15 wt. %.

6. The composition according to claim 1 , wherein the weight percent of the titanium dioxide in the total weight of the composition is of at least 6 wt. %.

7. The composition according to claim 1 , wherein the at least one polyamide comprises recurring units deriving from the polycondensation reaction of at least one diamine selected from the group consisting of 1,6-diaminohexane, 1,8-diamino-octane, 1,9-diaminononane, 1,10-diaminodecane, 1,11-diaminoundecane, 1,12-diaminododecane and meta-xylylene diamine and at least one dicarboxylic acid selected from the group consisting of phthalic acids, adipic acid, naphtalenedicarboxylic acids, sebacic acid and azelaic acid.

8. The composition according to claim 1 , wherein the weight percent of the metal oxide in the total weight of the composition is of at most 8 wt. %.

9. The composition according to claim 8 , wherein the weight percent of the metal oxide in the total weight of the composition is of at least 2 wt. %.

10. The composition according to claim 1 , wherein the metal oxide is magnesium oxide.

11. An article comprising at least one component comprising the polyamide composition according to claim 1 .

12. The article of claim 11 wherein said article is a light emission apparatus.

13. The light emission apparatus according to claim 12 , wherein said apparatus is a LED.

14. A method for making a light emission apparatus comprising heating components of the apparatus, at least one component comprising the polyamide composition according to claim 1 .

15. The method of claim 14 , wherein the heating is a result of the performance of a soldering operation, or wherein the apparatus further comprises an epoxy or silicone encapsulant and the heating is conducted to cure the encapsulant.

16. The composition according to claim 1 , wherein the composition has a higher retention of reflectivity after exposure to air at 260° C. for 10 minutes, as compared to compositions not comprising the combination of the at least one polyamide, the at least one metal oxide, titanium dioxide, and the intrinsic melt viscosity.

17. The composition according to claim 1 further comprising at least one end capping agent selected from the group consisting of an acid having only one reactive carboxylic acid group, and amine having only one reactive amine group, and mixtures thereof.

18. The composition according to claim 17 , wherein the end capping agent is selected from the group consisting of acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, caprylic acid, lauric acid, stearic acid, cyclohexanecarboxylic acid, benzoic acid, methylamine, ethylamine, butylamine, octylamine, aniline, toluidine, propylamine, hexylamine, dimethylamine, cyclohexylamine, and mixtures thereof.

19. The composition according to claim 17 comprising 0.1 to 6.5 mol. % of the end capping agent.

20. The composition according to claim 17 comprising 1 to 5.5 mol. % of the end capping agent.

21. A composition having at least one melting temperature (Tm) as measured according to ISO 11357-3, said composition comprising, based on total weight of the composition:

from 40 to 70 wt. % of at least one polyamide,

from 3 to 7 wt. % magnesium oxide,

from 10 to 40 wt. % of a reinforcing filler comprising wollastonite and/or glass fibers, and

from 10 to 30 wt. % titanium dioxide,

wherein the composition has an intrinsic melt viscosity of below 800.0 Pa·s as measured according to ASTM D3835-08 at a moisture content as measured according to ASTM D6869-03 in the range of 150-500 ppm at a shear rate of 400 s −1 and at a temperature ranging from [(Tm max)+10° C.] to [(Tm max)+20° C.], where (Tm max) is the highest of all melting temperatures (Tm).

22. A component for a light emission apparatus comprising a polyamide composition according to claim 21 .

23. The component of claim 22 , wherein the component is selected from a basic housing that acts as a reflector or a heatsink slug that acts as a reflector.

24. The component of claim 23 , wherein the component exhibits a reflectance of at least 81% at a wavelength of 450 nanometers after exposure to air at 260° C. for 10 minutes.

25. The composition according to claim 21 further comprising at least one end capping agent selected from the group consisting of an acid having only one reactive carboxylic acid group, and amine having only one reactive amine group, and mixtures thereof.

26. The composition according to claim 25 , wherein the end capping agent is selected from the group consisting of acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, caprylic acid, lauric acid, stearic acid, cyclohexanecarboxylic acid, benzoic acid, methylamine, ethylamine, butylamine, octylamine, aniline, toluidine, propylamine, hexylamine, dimethylamine, cyclohexylamine, and mixtures thereof.

27. The composition according to claim 25 comprising 0.1 to 6.5 mol. % of the end capping agent.

28. The composition according to claim 25 comprising 1 to 5.5 mol. % of the end capping agent.