Composite electric wire structure and method for manufacturing the same
Provided are a composite electric wire structure wherein a carbon material island structure is formed on a surface of a metal wire and a method for manufacturing the same. The carbon material/metal composite electric wire is capable of solving stability problem and preventing a decrease in electrical properties, mechanical properties, etc. In addition, the composite electric wire structure may be produced in commercially viable large scale.
1. A composite electric wire structure comprising:
a metal wire; and
a carbon material island structure present on a surface of the metal wire,
wherein the carbon material island structure comprises carbon material flakes,
wherein the carbon material flakes are positioned to be dispersed and isolated such that no continuous physical connection between the carbon material flakes is present from one end of the metal wire to an opposite end of the metal wire,
wherein the carbon material flakes have grown on the surface of the metal wire,
wherein the carbon material flakes comprise carbon material flakes that have grown from a metal grain boundary of the metal wire, and
wherein the carbon material primarily comprises graphene.
2. The composite electric wire structure according to claim 1 , wherein the composite electric wire structure further comprises a sheath covering the metal wire and the carbon material island structure, and the sheath contacts with the metal wire at a portion where the carbon material island structure is not present and contacts with a carbon material at a portion where the carbon material island structure is present.
3. The composite electric wire structure according to claim 2 , wherein the sheath comprises an insulating sheath.
4. The composite electric wire structure according to claim 1 , wherein the carbon material flakes are present on 5-90% of the total area of the metal wire.
5. The composite electric wire structure according to claim 1 , wherein the carbon material flakes further comprise carbon material flakes that have grown from grains of the metal wire.
6. The composite electric wire structure according to claim 1 , wherein the carbon material flakes comprise carbon material flakes doped with heterogeneous elements.
7. The composite electric wire structure according to claim 1 , wherein the carbon material flakes further comprise an externally derived carbon in addition to polymer-derived carbon.
8. The composite electric wire structure according to claim 1 , wherein the carbon material flakes have a thickness of 0.3-30 nm.
9. The composite electric wire structure according to claim 1 , wherein the composite electric wire structure is a single strand or an aggregate of a plurality of single strands.
10. The composite electric wire structure according to claim 9 , wherein the single-strand composite electric wire structure has a diameter of 10 nm to 100 cm.
11. The composite electric wire structure according to claim 1 , wherein the composite electric wire structure exhibits 1% or more increase in electrical conductivity as compared to that of a metal wire wherein the carbon material island structure is not formed.
12. The composite electric wire structure according to claim 1 , wherein the composite electric wire structure has an elasticity of 0.1-1000 GPa.
13. The composite electric wire structure according to claim 1 , wherein the composite electric wire structure exhibits 1% or less decrease in at least one of electrical conductivity and elasticity when it is deformed from a linear state.
14. The composite electric wire structure according to claim 1 , wherein the metal is a single crystalline metal or a polycrystalline metal.
15. The composite electric wire structure according to claim 1 , wherein the metal is one or more selected from a group consisting of a transition metal, a non-transition metal, a post-transition metal or an alloy thereof,
wherein
the transition metal is one or more selected from a group consisting of Pt, Ru, Cu, Fe, Ni, Co, Pd, W, Ir, Rh, Sr, Ce, Pr, Nd, Sm and Re,
the non-transition metal is one or more selected from a group consisting of Mg, B, Sn and Al, and
the post-transition metal is one or more selected from a group consisting of Sn, Al and Pb.
16. The composite electric wire structure according to claim 1 , wherein the metal wire is a multi-layered metal wire having a multi-layered structure.
17. The composite electric wire structure according to claim 1 , wherein the metal wire is surface-treated.