IP Library Granted Patent US 9,910,372
Granted Patent B2
US 9,910,372 · App. 15/335,972 · Granted Mar 6, 2018

Electrostatic charge image developing toner, electrostatic charge image developer, and toner cartridge

Inventors: Moegi Iguchi (Kanagawa, JP); Sakon Takahashi (Kanagawa, JP); Takeshi Tanabe (Kanagawa, JP); Hiroshi Kamada (Kanagawa, JP); Yasuaki Hashimoto (Kanagawa, JP); Masaaki Usami (Kanagawa, JP); Yuka Zenitani (Kanagawa, JP); Yuta Saeki (Kanagawa, JP); Hiroaki Saijo (Kanagawa, JP)
Assignee: FUJI XEROX CO., LTD.
G03G9/0819G03G9/0808G03G9/0827G03G9/08755G03G9/0918G03G9/1075G03G9/1133G03G15/0865
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Quick Facts
Patent No.
US 9,910,372
App. No.
15/335,972
Granted
Mar 6, 2018
Kind
B2
Abstract

An electrostatic charge image developing toner includes: toner particles; first silica particles having an average circularity of 0.9 to 1.0, a particle size distribution index of 1.05 to 1.25, and a compression aggregation degree of 60% to 95%; and second silica particles having an average circularity of 0.9 to 1.0, a particle size distribution index of 1.05 to 1.25, and a compression aggregation degree of 60% to 95%, wherein, when an average primary particle diameter of the first silica particles is set as Da (nm) and an average primary particle diameter of the second silica particles is set as Db (nm), relationships of the following Expressions (A1) to (A3) are satisfied: Expression (A1): 80≦Da≦120, Expression (A2): 120≦Db≦200, and Expression (A3): 10≦Db−Da≦120.

Claims (47)

1. An electrostatic charge image developing toner comprising:

toner particles;

first silica particles having an average circularity of 0.9 to 1.0, a particle size distribution index of 1.05 to 1.25, and a compression aggregation degree of 60% to 95%; and

second silica particles having an average circularity of 0.9 to 1.0, a particle size distribution index of 1.05 to 1.25, and a compression aggregation degree of 60% to 95%,

wherein, when an average primary particle diameter of the first silica particles is set as Da (nm) and an average primary particle diameter of the second silica particles is set as Db (nm), relationships of the following Expressions (A1) to (A3) are satisfied:

80≦ Da≦ 120,  Expression (A1)

120≦ Db≦ 200, and  Expression (A2)

10≦ Db−Da≦ 120.  Expression (A3)

2. The electrostatic charge image developing toner according to claim 1 ,

wherein, when the compression aggregation degree of the second silica particles is set as Ab (%) and a compression aggregation degree of mixed silica particles obtained by mixing the same amounts of the first silica particles and the second silica particles with each other is set as Aa+b (%), a relationship of the following Expression (B1) is satisfied:

Ab<Aa+b.   Expression (B1)

3. The electrostatic charge image developing toner according to claim 1 ,

wherein, when a specific gravity of the hardened first silica particles is set as Sa (g/cm 3 ) and a specific gravity of the hardened second silica particles is set as Sb (g/cm 3 ), relationships of the following Expressions (C1) to (C3) are satisfied:

0.6≦ Sa≦ 0.9,  Expression (C1)

0.5≦ Sb≦ 0.8, and  Expression (C2)

Sb<Sa.   Expression (C3)

4. The electrostatic charge image developing toner according to claim 1 ,

wherein a total amount of the first silica particles and the second silica particles externally added is 0.5% by weight to 3.0% by weight with respect to the toner particles.

5. The electrostatic charge image developing toner according to claim 1 ,

wherein a ratio of the amount of the first silica particles externally added to the amount of the second silica particles externally added (weight ratio: amount of the first silica particles externally added/amount of the second silica particles externally added) is 25/75 to 75/25.

6. The electrostatic charge image developing toner according to claim 1 ,

wherein both of the first silica particles and the second silica particles are sol-gel silica particles.

7. The electrostatic charge image developing toner according to claim 1 ,

wherein at least any one of the first silica particles and the second silica particles are particles in which surfaces of the silica particles are treated with a hydrophobizing agent.

8. The electrostatic charge image developing toner according to claim 7 ,

wherein the hydrophobizing agent is an organic silicon compound.

9. The electrostatic charge image developing toner according to claim 1 ,

wherein a volume average particle diameter (D50v) of the toner particles is from 4 μm to 8 μm.

10. The electrostatic charge image developing toner according to claim 1 ,

wherein an average circularity of the toner particles is 0.950 to 0.990.

11. The electrostatic charge image developing toner according to claim 1 ,

wherein the toner particles include a polyester resin.

12. The electrostatic charge image developing toner according to claim 11 ,

wherein a compositional monomer of the polyester resin includes neopentyl glycol.

13. The electrostatic charge image developing toner according to claim 11 ,

wherein a glass transition temperature (Tg) of the polyester resin is from 50° C. to 80° C.

14. The electrostatic charge image developing toner according to claim 11 ,

wherein a weight average molecular weight (Mw) of the polyester resin is from 7,000 to 500,000.

15. The electrostatic charge image developing toner according to claim 1 , further comprising:

at least one kind selected from the group consisting of resin particles and metallic soap particles.

16. The electrostatic charge image developing toner according to claim 15 ,

wherein the resin particles are composed of polytetrafluoroethylene and the metallic soap particles are composed of zinc stearate.

17. An electrostatic charge image developer comprising:

the electrostatic charge image developing toner according to claim 1 .

18. A toner cartridge comprising:

a container that contains the electrostatic charge image developing toner according to claim 1 ,

wherein the toner cartridge is detachable from an image forming apparatus.

Assignments (2)
CHANGE OF NAME Recorded Aug 12, 2021
From: FUJI XEROX CO., LTD.
To: FUJIFILM BUSINESS INNOVATION CORP.
Reel/Frame 058287/0056 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 27, 2016
From: IGUCHI, MOEGI; TAKAHASHI, SAKON; TANABE, TAKESHI; KAMADA, HIROSHI; HASHIMOTO, YASUAKI; USAMI, MASAAKI; ZENITANI, YUKA; SAEKI, YUTA; SAIJO, HIROAKI
To: FUJI XEROX CO., LTD.
Reel/Frame 040151/0669 →
Priority Claims (1)
JP 2016-091268 · Apr 28, 2016 · national
Continuity (1)
Related Publication 20170315459A1 · Nov 2, 2017