Dental products and procedures
Polymeric shells which fit over natural teeth to change the perceived color of the teeth, and optionally to provide orthodontic support. The shells are prepared by thermoforming selected polymeric sheets which contain optical additives; the optical additives cause the combination of the shell and the teeth to have a desired appearance. The shell preferably has transparency of greater than 75%, particularly greater than 85%.
1. A self-supporting shell which (i) fits over one or more teeth and (ii) has been prepared by thermoforming a sheet over a model of the tooth or teeth, wherein said shell comprises a polymeric composition comprising a polymer and one or more optical additives and,
(A) the one or more optical additives comprises light-scattering particles selected from the group consisting of one or more of titanium dioxide, barium sulfate, calcium carbonate, boron nitride, silica, mica and zinc oxide, and
(B) (i) the shell comprises an outermost layer and one or more additional layers,
(ii) at least one of the additional layers contains a first concentration of the one or more optically active additives, and
(iii) the outermost layer contains a second concentration of the one or more optically active additives, the second concentration being less than the first concentration.
2. A self-supporting shell according to claim 1 wherein the one or more optical additives comprises a fluorescent agent which (i) absorbs light at frequencies below about 400 nm and (ii) emits light having frequencies between about 400 and about 600 nm.
3. A self-supporting shell according to claim 1 wherein the one or more optical additive comprises an additive selected from the group consisting of one or more of ultramarine blue, ultramarine violet, manganese oxides, cobalt-based pigments, resin-soluble dyes, phthalocyanine, Violet 92, Violet 11 C, blue 385, blue 214, blue 30 C5 91, blue 30 C588, FDC blue #1 and blue 214.
4. A self-supporting shell according to claim 1 wherein the sheet contains no fluorescent agent and before it is thermoformed, when it is measured on the LAB scale on a white color tile, and using a light source that includes light with a frequency of about 300-400 nm filtered to D65, has an L value from 75 to 99, an A value of −3to 6, and a B value of −10 to −1.
5. A self-supporting shell according to claim 1 which has a thickness of at least 0.3 mm.
6. A self-supporting shell according to claim 1 wherein
(i) the sheet is a laminate comprising an outermost layer and one or more additional layers,
(ii) the additional layer, or each of the additional layers if there is more than one additional layer, contains the one or more optically active additives, and
(iii) the outermost layer does not contain any optically active additives.
7. A self-supporting shell which (i) fits over one or more teeth, and (ii) has been prepared by thermoforming a sheet over a model of the tooth or teeth wherein said shell comprises a polymer and one or more optical additives, and
(A) the one or more optical additives comprises a fluorescent agent which (i) absorbs light at frequencies below about 400 nm and (ii) emits light having frequencies between about 400 and about 600 nm, and
(B) (i) the shell comprises an outermost layer and one or more additional layers,
(ii) at least one of the additional layers contains a first concentration of the one or more optically active additives, and
(iii) the outermost layer contains a second concentration of the one or more optically active additives, the second concentration being less than the first concentration.
8. A self-supporting shell according to claim 7 wherein the one or more optical additives comprises an additive selected from the group consisting of one or more of ultramarine blue, ultramarine violet, manganese oxides, cobalt-based pigments, resin-soluble dyes, phthalocyanine, Violet 92, Violet 11 C, blue 385, blue 214, blue 30 C5 91, blue 30 C588, FDC blue #1 and blue 214.
9. A self-supporting shell according to claim 7 wherein the sheet, before it is thermoformed, when it is measured on the LAB scale on a white color tile, and using a light source that includes light with a frequency of about 300-400 nm filtered to D65, has an L value from 75 to 110, an A value of −3 to 6, and a B value of −10 to −1.
10. A self-supporting shell according to claim 7 wherein
(i) the sheet is a laminate comprising an outermost layer and one or more additional layers,
(ii) the additional layer, or each of the additional layers if there is more than one additional layer, contains the one or more optically active additives, and
(iii) the outermost layer does not contain any optically active additives.
11. A self-supporting shell which (i) fits over one or more teeth and (ii) has been prepared by thermoforming a sheet over a model of the tooth or teeth wherein said shell comprises a polymer and one or more optical additives, and
(A) the one or more optical additives comprises an additive selected from the group consisting of one or more of ultramarine blue, ultramarine violet, manganese oxides, cobalt-based pigments, resin-soluble dies, phthalocyanine, Violet 92, Violet 11 C, blue 385, blue 214, blue 30 C5 91, blue 30 C588, FDC blue #1 and blue 214, and
(B) (i) the shell comprises an outermost layer and one or more additional layers,
(ii) at least one of the additional layers contains a first concentration of the one or more optically active additives, and
(iii) the outermost layer contains a second concentration of the one or more optically active additives, the second concentration being less than the first concentration.
12. A self-supporting shell according to claim 11 wherein
(i) the sheet is a laminate comprising an outermost layer and one or more additional layers,
(ii) the additional layer, or each of the additional layers if there is more than one additional layer, contains the one or more optically active additives, and
(iii) the outermost layer does not contain any optically active additives.