IP Library Granted Patent US 9,934,984
Granted Patent B2
US 9,934,984 · App. 14/849,077 · Granted Apr 3, 2018

Hydrofluorocarbon gas-assisted plasma etch for interconnect fabrication

Inventors: Robert L. Bruce (White Plains, NY); Eric A. Joseph (White Plains, NY); Joe Lee (Albany, NY); Takefumi Suzuki (Harrison, NY)
Assignees: International Business Machines Corporation; Zeon Corporation
H01L21/31116H01L21/76802H01L21/76877H01L23/528H01L23/5329
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Quick Facts
Patent No.
US 9,934,984
App. No.
14/849,077
Granted
Apr 3, 2018
Kind
B2
Abstract

In one embodiment, a method for hydrofluorocarbon gas-assisted plasma etch for interconnect fabrication includes providing a layer of a dielectric material and etching a trench in the layer of the dielectric material, by applying a mixture of an aggressive dielectric etch gas and a polymerizing etch gas to the layer of the dielectric material. In another embodiment, an integrated circuit includes a plurality of semiconductor devices and a plurality of conductive lines connecting the plurality of semiconductor devices. A pitch of the plurality of conductive lines is approximately twenty-eight nanometers.

Claims (29)

1. A method, comprising:

providing a capping layer to separate a front end from a back end of an integrated circuit being fabricated;

providing a layer of a dielectric material directly on the capping layer, wherein the layer of the dielectric material forms a part of the back end;

etching a trench in the layer of the dielectric material, by applying a mixture of a dielectric etch gas and a polymerizing etch gas to the layer of the dielectric material, wherein a ratio of the dielectric etch gas to the polymerizing etch gas in the mixture is sufficient to line sidewalls of the trench with a passivation layer as the trench is etched, wherein the etching stops at the capping layer, and wherein the dielectric etch gas comprises a fluorocarbon gas, and the polymerizing etch gas comprises a hydrofluorocarbon gas compound;

removing the passivation layer from the sidewalls of the trench; and

depositing a conductive metal in the trench, subsequent to removing the passivation layer, to form a conductive line that directly contacts the dielectric layer.

2. The method of claim 1 , wherein the mixture comprises approximately twenty to forty parts dielectric etch gas to one part polymerizing etch gas.

3. The method of claim 1 , wherein the dielectric etch gas comprises carbon tetrafluoride.

4. The method of claim 1 , wherein the dielectric etch gas comprises sulfur hexafluoride.

5. The method of claim 1 , wherein the dielectric etch gas comprises nitrogen trifluoride.

6. The method of claim 1 , wherein the polymerizing etch gas comprises perfluorocyclobutane.

7. The method of claim 1 , wherein the polymerizing etch gas comprises heptafluorocyclopentene.

8. The method of claim 1 , wherein the passivation layer protects the sidewalls from lateral etching by the dielectric etch gas.

9. The method of claim 1 , wherein the capping layer completely separates the front end from the back end.

10. A method, comprising:

providing a capping layer to separate a front end from a back end of an integrated circuit being fabricated;

providing a layer of a dielectric material directly over the capping layer, wherein the layer of the dielectric material forms a part of the back end;

providing a mask layer directly over the layer of the dielectric material;

patterning the mask layer to expose portions of the layer of the dielectric material;

etching the portions of the layer of the dielectric material to form a plurality of trenches, wherein the etching is performed using a mixture of a dielectric etch gas and a polymerizing etch gas, wherein the etching stops at the capping layer, and wherein a ratio of the dielectric etch gas to the polymerizing etch gas in the mixture is sufficient to line sidewalls of the plurality of trenches with passivation layers as the plurality of trenches is etched, and wherein the dielectric etch gas comprises a fluorocarbon gas, and the polymerizing etch gas comprises a hydrofluorocarbon gas compound;

removing the passivation layers from the sidewalls of the plurality of trenches; and

filling the plurality of trenches with a conductive metal, subsequent to removing the passivation layers, to form a plurality of conductive lines that directly contact the dielectric layer.

11. The method of claim 10 , wherein the mixture comprises approximately twenty to forty parts dielectric etch gas to one part polymerizing etch gas.

12. The method of claim 10 , wherein the dielectric etch gas comprises carbon tetrafluoride.

13. The method of claim 10 , wherein the dielectric etch gas comprises nitrogen trifluoride.

14. The method of claim 10 , wherein the dielectric etch gas comprises sulfur hexafluoride (SF 6 ).

15. The method of claim 10 , wherein the polymerizing etch gas comprises heptafluorocyclopentene.

16. The method of claim 10 , wherein the polymerizing etch gas comprises perfluorocyclobutane.

17. The method of claim 10 , wherein the passivation layers protect the sidewalls from lateral etching by the dielectric etch gas.

Assignments (4)
CORRECTIVE ASSIGNMENT TO REMOVE THE FOURTH ASSIGNOR'S DATA PREVIOUSLY RECORDED AT REEL: 036523 FRAME: 0638. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 1, 2016
From: BRUCE, ROBERT T.; JOSEPH, ERIC A.; LEE, JOE
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 037968/0895 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 1, 2016
From: SUZUKI, TAKEFUMI
To: ZEON CORPORATION
Reel/Frame 037968/0934 →
CORRECTIVE ASSIGNMENT TO CORRECT THE OMISSION OF THE 2ND RECEIVING PARTY PREVIOUSLY RECORDED AT REEL: 036523 FRAME: 0638. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Feb 16, 2016
From: SUZUKI, TAKEFUMI; BRUCE, ROBERT T.; JOSEPH, ERIC A.; LEE, JOE
To: ZEON CORPORATION; INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 037847/0102 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 9, 2015
From: BRUCE, ROBERT L.; JOSEPH, ERIC A.; LEE, JOE; SUZUKI, TAKEFUMI
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 036523/0638 →
Continuity (1)
Related Publication 20170069508A1 · Mar 9, 2017